Related papers: Ionic effects in self-propelled Pt-coated Janus sw…
Micrometer scale colloidal particles that propel in a deterministic fashion in response to local environmental cues are useful analogs to self-propelling entities found in nature. Both natural and synthetic active colloidal systems are…
We study experimentally-using Janus colloids-and theoretically-using Active Brownian Particles- the sedimentation of dilute active colloids. We first confirm the existence of an exponential density profile. We show experimentally the…
Partitioning and transport of water and small solutes into and through nanopores is important to a variety of chemical and biological processes and applications. Here we study the partitioning of positive ions of increasing size into the…
Polymer electrolytes typically exhibit diminished ionic conductivity due to the presence of correlation effects between the cations and anions. Microscopically, transient ionic aggregates, e.g. {\it ion-pairs}, {\it ion-triplets} or higher…
Efficient mixing of colloids, particles or molecules is a central issue in many processes. It results from the complex interplay between flow deformations and molecular diffusion, which is generally assumed to control the homogenization…
The development of synthetic microswimmers has advanced our understanding of the fundamental self-propelled mechanisms of living systems. However, there are scarce studies at the microscale within highly structured anisotropic media, such…
Phoretic swimmers are a class of artificial active particles that has received significant attention in recent years. By making use of self-generated gradients (e.g. in temperature, electric potential or some chemical product) phoretic…
Janus particles propel themselves by generating concentration gradients along their active surface. This induces a flow near the surface, known as the diffusio-osmotic slip, which propels the particle even in the absence of externally…
Phoretic self-propulsion is a unique example of force- and torque-free motion on small scales. The classical framework describing the flow field around a particle swimming by self-diffusiophoresis neglects the advection of the solute field…
Ionic transport in nanopores is a fundamentally and technologically important problem in view of its occurrence in biological processes and its impact on novel DNA sequencing applications. Using microscopic calculations, here we show that…
Surface bound catalytic chemical reactions self-propel chemically active Janus particles. In the vicinity of boundaries, these particles exhibit rich behavior, such as the occurrence of wall-bound steady states of "sliding". Most active…
We construct a coarse-grained molecular dynamics model based on poly(ethylene oxide) and lithium bis-(trifluoromethane)sulfonimide salt to examine the combined effects of temperature and salt concentration on the transport properties. Salt…
A trapping mechanism for propelled colloidal particles based on an inhomogeneous drive is presented and studied by means of computer simulations. In experiments this method can be realized using photophoretic Janus particles driven by a…
Micron-sized particles moving through solution in response to self-generated chemical gradients serve as model systems for studying active matter. Their far-reaching potential applications will require the particles to sense and respond to…
We theoretically study the electrolyte Seebeck effect in the vicinity of a heated metal nanostructure, such as the cap of an active Janus colloid in an electrolyte, or gold- coated interfaces in optofluidic devices. The thermocharge…
We numerically simulate the transport of elliptic Janus particles along narrow two-dimensional channels with reflecting walls. The self-propulsion velocity of the particle is oriented along either their major (prolate) or minor axis…
Ionic solids and melts are compounds in which the interactions are dominated by electrostatic effects. However, the polarization of the ions also plays an important role in many respects as has been clarified in recent years thanks to the…
We study the diffusiophoretic self-propulsion of a colloidal catalytic particle due to a surface chemical reaction in a vicinity of a solid wall. Diffusiophoresis is a chemico-mechanical transduction mechanism in which a concentration…
Water-metal interfaces are ubiquitous and play a key role in many chemical processes, from catalysis to corrosion. Whereas water adlayers on atomically flat transition metal surfaces have been investigated in depth, little is known about…
For natural microswimmers, the interplay of swimming activity and external flow can promote robust motion, e.g. propulsion against ("upstream rheotaxis") or perpendicular to the direction of flow. These effects are generally attributed to…