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Computational chemistry at the atomic level has largely branched into two major fields, one based on quantum mechanics and the other on molecular mechanics using classical force fields. Because of high computational costs, quantum…

Chemical Physics · Physics 2018-10-23 Pedro E M Lopes

Inspired by one--dimensional light--particle systems, the dynamics of a non-Hamiltonian system with long--range forces is investigated. While the molecular dynamics does not reach an equilibrium state, it may be approximated in the…

Statistical Mechanics · Physics 2019-01-23 Romain Bachelard , Nicola Piovella , Shamik Gupta

We propose a mean-field optimal control problem for the parameter identification of a given pattern. The cost functional is based on the Wasserstein distance between the probability measures of the modeled and the desired patterns. The…

Optimization and Control · Mathematics 2021-04-08 Martin Burger , Lisa Maria Kreusser , Claudia Totzeck

We present a detailed derivation and testing of our approach to rescale the dynamics of mesoscale simulations of coarse-grained polymer melts (I. Y. Lyubimov et al. J. Chem. Phys. \textbf{132}, 11876, 2010). Starting from the…

Soft Condensed Matter · Physics 2015-05-27 I. Y. Lyubimov , M. G. Guenza

Diffusive molecular dynamics is a novel model for materials with atomistic resolution that can reach diffusive time scales. The main ideas of diffusive molecular dynamics are to first minimize an approximate variational Gaussian free energy…

Numerical Analysis · Mathematics 2015-06-09 Gideon Simpson , Mitchell Luskin , David J. Srolovitz

We construct explicit examples of spontaneous energy generation and non-uniqueness for the compressible Euler system, with and without pressure, by taking limits of Hamiltonian dynamics as the number of molecules increases to infinity. The…

Mathematical Physics · Physics 2016-09-29 Stamatis Dostoglou , Jianfei Xue

A new algorithm for efficient and fully time-reversible integration of first-principles molecular dynamics based on orbital-free density functional theory (OFDFT) is presented. The algorithm adapts to this nontrivial case the recently…

Statistical Mechanics · Physics 2022-12-21 Alessandro Coretti , Taylor J. Baird , Rodolphe Vuilleumier , Sara Bonella

We analyze the time reversible Born-Oppenheimer molecular dynamics (TRBOMD) scheme, which preserves the time reversibility of the Born-Oppenheimer molecular dynamics even with non-convergent self-consistent field iteration. In the linear…

Numerical Analysis · Mathematics 2015-06-16 Lin Lin , Jianfeng Lu , Sihong Shao

In the previous paper (hep-th/9712161) it was shown that the nonlinear Born-Infeld field equations supplemented by the "dynamical condition" (certain boundary condition for the field along the particle's trajectory) define perfectly…

High Energy Physics - Theory · Physics 2008-11-26 Dariusz Chruscinski

We report the first wholly non-empirical generalized gradient approximation, non-interacting free energy functional for orbital-free density functional theory and use that new functional to provide forces for finite-temperature molecular…

Materials Science · Physics 2013-11-26 Valentin V. Karasiev , Debajit Chakraborty , Olga A. Shukruto , S. B. Trickey

This note provides an introduction to molecular dynamics, the computational implementation of the theory of statistical physics. The discussion is focused on the properties of Langevin dynamics, a degenerate stochastic differential equation…

Analysis of PDEs · Mathematics 2021-12-16 Gabriel Stoltz

Accelerated molecular dynamics (MD) simulations are implemented to model the sliding process of AFM experiments at speeds close to those found in experiment. In this study the hyperdynamics method, originally devised to extend MD time…

Materials Science · Physics 2015-05-14 Woo Kyun Kim , Michael L. Falk

This paper proposes the first free-stream boundary condition in a purely Lagrangian framework for weakly-compressible smoothed particle hydrodynamics (WCSPH). The boundary condition is implemented based on several numerical techniques,…

Fluid Dynamics · Physics 2023-07-04 Shuoguo Zhang , Wenbin Zhang , Chi Zhang , Xiangyu Hu

We introduce a scheme for molecular simulations, the Deep Potential Molecular Dynamics (DeePMD) method, based on a many-body potential and interatomic forces generated by a carefully crafted deep neural network trained with ab initio data.…

Computational Physics · Physics 2018-04-11 Linfeng Zhang , Jiequn Han , Han Wang , Roberto Car , Weinan E

We introduce a novel and powerful method for exploring the properties of the multidimensional free energy surfaces of complex many-body systems by means of a coarse-grained non-Markovian dynamics in the space defined by a few collective…

Statistical Mechanics · Physics 2009-11-07 A. Laio , M. Parrinello

Molecular dynamics simulations are used to study structure formation in simple model polymer chains that are subject to excluded volume and torsional interactions. The changing conformations exhibited by chains of different lengths under…

Soft Condensed Matter · Physics 2009-11-07 D. C. Rapaport

The method of molecular dynamics is used to study behavior of a ultracold non-ideal ion-electron Be plasma in a uniform magnetic field. Our simulations yield an estimate for the rate of electron-ion collisions which is…

Plasma Physics · Physics 2018-01-17 I. L. Isaev , A. P. Gavriliuk

In this work, we consider optimal control problems for mechanical systems on vector spaces with fixed initial and free final state and a quadratic Lagrange term. Specifically, the dynamics is described by a second order ODE containing an…

A number of optimization algorithms have been inspired by the physics of Newtonian motion. Here, we ask the question: do algorithms themselves obey some ``natural laws of motion,'' and can they be derived by an application of these laws? We…

Optimization and Control · Mathematics 2026-04-21 I. M. Ross

We present a phase-space electronic Hamiltonian $\hat{H}_{PS}$ (parameterized by both nuclear position $\mathbf{X}$ and momentum $\mathbf{P}$) that boosts each electron into the moving frame of the nuclei that are closest in real space --…

Chemical Physics · Physics 2024-12-31 Zhen Tao , Tian Qiu , Xuezhi Bian , Joseph E. Subotnik