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Numerical reproduction of measurements, experimental evidence for skin super-solidity and hydrogen-bond memory clarified that Mpemba paradox integrates the heat emission-conduction-dissipation dynamics in the source-path-drain cycle system.

Soft Condensed Matter · Physics 2015-01-29 Chang Q Sun

An ancient and counterintuitive phenomenon know as the Mpemba effect (water can cool faster when initially heated up) showcases the critical role of initial conditions in relaxation processes. How to realize and utilize this effect for…

We demonstrate that the Mpemba paradox arises intrinsically from the release rate of energy initially stored in the covalent H-O part of the O:H-O bond in water albeit experimental conditions. Generally, heating raises the energy of a…

Chemical Physics · Physics 2015-01-29 Xi Zhang , Yongli Huang , Zengsheng Ma , Chang Q Sun

The Mpemba effect is a counter-intuitive relaxation phenomenon, where a system prepared at a hot temperature cools down faster than an identical system initiated at a cold temperature when both are quenched to an even colder bath. Such…

Statistical Mechanics · Physics 2019-07-03 Israel Klich , Oren Raz , Ori Hirschberg , Marija Vucelja

We look into the Mpemba effect---the initially hotter sample cools sooner---in a molecular gas with nonlinear viscous drag. Specifically, the gas particles interact among them via elastic collisions and also with a background fluid at…

Statistical Mechanics · Physics 2020-07-24 Andrés Santos , Antonio Prados

Mpemba effect refers to the counterintuitive phenomenon of a hotter system equilibrating faster than a colder system when both are quenched to the same low temperature. For a Brownian particle trapped in a piece-wise linear single well…

Statistical Mechanics · Physics 2023-05-12 Apurba Biswas , R. Rajesh

The highly complicated nature of far from equilibrium systems can lead to a complete breakdown of the physical intuition developed in equilibrium. A famous example of this is the Mpemba effect, which states that non-equilibrium states may…

Statistical Mechanics · Physics 2024-07-03 Colin Rylands , Katja Klobas , Filiberto Ares , Pasquale Calabrese , Sara Murciano , Bruno Bertini

The Mpemba effect has initially been noticed in macroscopic systems -- namely that hot water can freeze faster than cold water -- but recently its extension to open quantum systems has attracted significant attention. This phenomenon can be…

Mesoscale and Nanoscale Physics · Physics 2025-04-08 Juliane Graf , Janine Splettstoesser , Juliette Monsel

The "Mpemba effect" is the name given to the assertion that hot water freezes quicker than cold water1 or, in a modern and more general form, that the system that is initially more distant from its equilibrium state comes to this state…

Chemical Physics · Physics 2025-08-08 Andrei A. Klimov , Alexei V. Finkelstein

Loosely speaking, the Mpemba effect appears when hotter systems cool sooner or, in a more abstract way, when systems further from equilibrium relax faster. In this paper, we investigate the Mpemba effect in a molecular gas with nonlinear…

Soft Condensed Matter · Physics 2022-05-31 Alberto Megías , Andrés Santos , Antonio Prados

When a hot system cools down faster than an equivalent cold one, it exhibits the Mpemba Effect. This counterintuitive phenomenon was observed in several systems including water, magnetic alloys and polymers. In most experiments the system…

Statistical Mechanics · Physics 2023-07-07 Gianluca Teza , Ran Yaacoby , Oren Raz

The Mpemba effect refers to systems whose thermal relaxation time is a non-monotonic function of the initial temperature. Thus, a system that is initially hot cools to a bath temperature more quickly than the same system, initially warm. In…

Statistical Mechanics · Physics 2021-03-31 Raphaël Chétrite , Avinash Kumar , John Bechhoefer

The quantum Mpemba effect is a phenomenon characterized by an exponential relaxation from a non-equililbrium state to a steady state. This effect was predicted with an analysis of the Liouvillian superoperator and experimentally…

The Mpemba effect is a fingerprint of the anomalous relaxation phenomenon wherein an initially hotter system equilibrates faster than an initially colder system when both are quenched to the same low temperature. Experiments on a single…

Statistical Mechanics · Physics 2023-08-16 Apurba Biswas , R. Rajesh , Arnab Pal

The Mpemba effect occurs when a system prepared at a hot temperature cools down faster to the bath temperature than an identical system starting at a warm temperature. We derive the condition for the Mpemba effect in the small-diffusion…

Statistical Mechanics · Physics 2023-05-31 Matthew R. Walker , Marija Vucelja

The so-called Mpemba effect, i.e. the observation that the warmer of two otherwise identical systems cools faster when both are refrigerated in the same thermal reservoir, is a hotly debated topic in condensed mater physics and statistical…

Materials Science · Physics 2019-09-11 A. Gijón , A. Lasanta , E. R. Hernández

The Mpemba effect, in which a hotter system cools faster than a colder one, remains one of the most intriguing anomalies in thermodynamics. Here, we investigate its microscopic origin within the framework of quantum resource theories and…

Quantum Physics · Physics 2026-04-17 Doruk Can Alyürük , Mahir H. Yeşiller , Vlatko Vedral , Onur Pusuluk

Under certain conditions, it takes a shorter time to cool a hot system than to cool the same system initiated at a lower temperature. This phenomenon - the "Mpemba Effect" - is well known in water, and has recently been observed in other…

Statistical Mechanics · Physics 2017-09-28 Zhiyue Lu , Oren Raz

We demonstrate the quantum Mpemba effect in a quantum dot coupled to two reservoirs, described by the Anderson model. We show that the system temperatures starting from two different initial values (hot and cold), cross each other at finite…

Statistical Mechanics · Physics 2023-08-25 Amit Kumar Chatterjee , Satoshi Takada , Hisao Hayakawa

Under certain conditions, two samples of fluid at different initial temperatures present a counterintuitive behavior known as the Mpemba effect: it is the hotter system that cools sooner. Here, we show that the Mpemba effect is present in…

Soft Condensed Matter · Physics 2017-10-06 Antonio Lasanta , Francisco Vega Reyes , Antonio Prados , Andrés Santos
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