Related papers: The Deuterium Fractionation Timescale in Dense Clo…
Despite the detection of numerous interstellar complex organic molecules (iCOMs) for decades, it is still a matter of debate whether they are synthesized in the gas-phase or on the icy surface of interstellar grains. In the past, molecular…
The formation of singly and doubly deuterated isotopomers of formaldehyde and of singly, doubly, and multiply deuterated isotopomers of methanol on interstellar grain surfaces has been studied with a semi-empirical modified rate approach…
Context. The increased sensitivity and high spectral resolution of millimeter telescopes allow the detection of an increasing number of isotopically substituted molecules in the interstellar medium. The 14N/ 15N ratio is difficult to…
Context: Chemical models of dense cloud cores often utilize the so-called pseudo-time-dependent approximation, in which the physical conditions are held fixed and uniform as the chemistry occurs. In this approximation, the initial…
The study of deuteration in pre-stellar cores is important to understand the physical and chemical initial conditions in the process of star formation. In particular, observations toward pre-stellar cores of methanol and deuterated…
IRAS 16293-2422 is a well studied low-mass protostar characterized by a strong level of deuterium fractionation. In the line of sight of the protostellar envelope, an additional absorption layer, rich in singly and doubly deuterated water…
We investigate the chemical evolution of a forming molecular cloud behind an interstellar shock wave. We conduct three-dimensional magnetohydrodynamics simulations of the converging flow of atomic gas, including a simple chemical network…
We present an extended version of the 2-phase gas-grain code NAUTILUS to the 3-phase modelling of gas and grain chemistry of cold cores. In this model, both the mantle and the surface are considered as chemically active. We also take into…
We present sensitive observations of NH2D at 110.153599 GHz toward 50 Galactic massive star-forming regions with IRAM 30-m telescope. The NH2D transition is detected toward 36 objects, yielding a detection rate of 72%. Column densities of…
Aims. We aim to present simulated chemical abundance profiles for a variety of important species, with special attention given to spin-state chemistry, in order to provide reference results against which present and future models can be…
We investigate the chemical and observational implications of repetitive transient dense core formation in molecular clouds. We allow a transient density fluctuation to form and disperse over a period of 1 Myr, tracing its chemical…
The molecular evolution that occurs in collapsing prestellar cores is investigated. To model the dynamics, we adopt the Larson-Penston (L-P) solution and analogues with slower rates of collapse. For the chemistry, we utilize the new…
(Abridged) The aim of this study is to investigate the chemical evolution from the prestellar phase to the formation of the disk, and to determine the impact that the chemical composition of the cold and dense core has on the final…
Detections of deuterium in high redshift Lyman limit absorption systems along the line of sight to QSOs promise to reveal the primordial deuterium abundance. At present, the deuterium abundances (D/H) derived from the very few systems…
The flood of new data on deep surveys, and above all the CFRS (Canada-France-Redshift-Survey), has had a great impact on studies of galactic evolution. On the basis of cosmological models consistent with the improved values of the Hubble…
The predictions of Galactic chemical evolution models for D and $^3$He are described in connection with those on the other Galactic quantities for which observational constraints are available. Models in agreement with the largest set of…
We present a survey of the ortho-H2D+(1_{1,0}-1_{1,1}) line toward a sample of 10 starless cores and 6 protostellar cores, carried out at the Caltech Submillimeter Observatory. The high diagnostic power of this line is revealed for the…
In star-forming regions, molecular cloud history and dynamics set the trend in the chemical composition. Ice formation, in particular, is affected by the evolution of physical conditions, which can lead to different ice compositions within…
We combine dynamical and non-equilibrium chemical modeling of evolving prestellar molecular cloud cores, and explore the evolution of molecular abundances in the contracting core. We model both magnetic cores, with varying degrees of…
We present a study of the elemental depletion in the interstellar medium. We combined the results of a Galatic model describing the gas physical conditions during the formation of dense cores with a full-gas-grain chemical model. During the…