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We present a theory that efficiently describes the quantum dynamics of an electronic excitation that is coupled to a continuous, highly structured phonon environment. Based on a stochastic approach to non-Markovian open quantum systems, we…

Quantum Physics · Physics 2009-11-05 Jan Roden , Alexander Eisfeld , Wolfgang Wolff , Walter T. Strunz

We investigate the role of quantum coherence in modulating the energy transfer rate between two independent energy donors and a single acceptor participating in an excitonic energy transfer process. The energy transfer rate depends…

Chemical Physics · Physics 2015-07-13 Sreenath K. Manikandan , Anil Shaji

As a quantum resource, quantum coherence plays an important role in modern physics. Many coherence measures and their relations with entanglement have been proposed, and the dynamics of entanglement has been experimentally studied. However,…

Quantum Physics · Physics 2023-07-18 Yi Zheng , Cheng-Jie Zhang , Zheng-Hao Liu , Jian-Wei Shao , Jin-Shi Xu , Chuan-Feng Li , Guang-Can Guo

We present a fully quantum-mechanical model of the electronic dynamics of primary photoexcitations in a polymeric semiconductor heterojunction, which includes both polymer stacking and phonon relaxation. By examining the phonon-induced…

Materials Science · Physics 2014-03-05 Eric R. Bittner , Carlos Silva

The quantum dynamics of transport networks in the presence of noisy environments have recently received renewed attention with the discovery of long-lived coherences in different photosynthetic complexes. This experimental evidence has…

Biological Physics · Physics 2015-06-04 A. W. Chin , S. F. Huelga , M. B. Plenio

The role of quantum coherence and the environment in the dynamics of excitation energy transfer is not fully understood. In this work, we introduce the concept of dynamical contributions of various physical processes to the energy transfer…

Quantum Physics · Physics 2009-07-18 Patrick Rebentrost , Masoud Mohseni , Alán Aspuru-Guzik

Quantum coherence, the ability of a quantum system to be in a superposition of orthogonal quantum states, is a distinct feature of the quantum mechanics, thus marking a deviation from classical physics. Coherence finds its applications in…

Quantum Physics · Physics 2023-01-18 Najmeh Etehadi Abari , Andrey Rakhubovsky , Radim Filip

Transport phenomena on a quantum scale appear in a variety of systems, ranging from photosynthetic complexes to engineered quantum devices. It has been predicted that the efficiency of quantum transport can be enhanced through dynamic…

This paper presents the inversion symmetry breaking observed in ion-pair formation from molecular hydrogen on electron impact. We explain these observations using quantum interference of two dissociation paths coherently accessed by…

Chemical Physics · Physics 2024-04-17 Akshay Kumar , Suvasis Swain , Vaibhav S. Prabhudesai

Quantum work capacitances and maximal asymptotic work/energy ratios are figures of merit characterizing the robustness against noise of work extraction processes in quantum batteries formed by collections of quantum systems. In this paper…

Quantum Physics · Physics 2025-01-31 Salvatore Tirone , Raffaele Salvia , Stefano Chessa , Vittorio Giovannetti

Quantum coherence is a central ingredient in quantum physics with several theoretical and technological ramifications. In this work we consider a figure of merit encoding the information on how the coherence generated on average by a…

In natural light harvesting systems, the sequential quantum events of photon absorption by specialized biological antenna complexes, charge separation, exciton formation and energy transfer to localized reaction centers culminates in the…

Quantum Physics · Physics 2014-11-25 A. Thilagam

We develop a theoretical framework for the analysis of the quantum coherence of light emitted by two independent single-photon sources in an arbitrary environment. The theory provides design rules for the control of the degree of quantum…

Quantum Physics · Physics 2016-03-30 Antoine Canaguier-Durand , Rémi Carminati

Until recently it was believed that photosynthesis, a fundamental process for life on earth, could be fully understood with semi-classical models. However, puzzling quantum phenomena have been observed in several photosynthetic…

Giant strides in ultrashort laser pulse technology have enabled real-time observation of dynamical processes in complex molecular systems. Specifically, the discovery of oscillatory transients in the two-dimensional electronic spectra of…

Chemical Physics · Physics 2021-03-08 Akihito Ishizaki , Graham R. Fleming

Quantum coherence, the physical property underlying fundamental phenomena such as multi-particle interference and entanglement, has emerged as a valuable resource upon which modern technologies are founded. In general, the most prominent…

Quantum coherence is highly involved in photochemical functioning of complex molecular systems. Co-existence and intermixing of electronic and/or vibrational coherences, while never unambiguously identified experimentally, has been proposed…

In this paper we investigate the coherence properties of a quantum dot under two-photon resonant excitation in combination with an additional photo-neutralization laser. The photo-neutralization increases the efficiency of the excitation…

Quantum Physics · Physics 2016-09-21 Tobias Huber , Ana Predojević , Glenn S. Solomon , Gregor Weihs

The nature of excited states of open quantum systems produced by incoherent natural thermal light is analyzed based on a description of the generator of the dynamics. Natural thermal light is shown to generate long-lasting coherent dynamics…

Quantum Physics · Physics 2017-09-05 Leonardo A. Pachon , Juan D. Botero , Paul Brumer

Spectroscopic experiments have identified long-lived coherences in several light-harvesting systems, suggesting that coherent effects may be relevant to their performance. However, there is limited experimental evidence of coherence…

Chemical Physics · Physics 2019-10-30 Stefano Tomasi , Sima Baghbanzadeh , Saleh Rahimi-Keshari , Ivan Kassal