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Recently reported anomalies in the double-photonionization spectra of the aromatic molecules partially deuterated benzene, naphthalene, anthracene, pentacene, azulene, phenanthrene, pyrene and coronene are attributed to Coulomb-pair…

Strongly Correlated Electrons · Physics 2014-03-12 D. L. Huber

We present an analysis of the pairing resonances observed in photo-double-ionization studies of CnHm aromatic molecules with multiple benzene-like rings. The analysis, which is based on the Coulomb pairing model, is applied to naphthalene,…

Chemical Physics · Physics 2015-09-17 D. L. Huber

The low energy resonance in the double photoionization of the aromatic hydrocarbons pyrene (C$_{16}$H$_{10}$) and coronene (C$_{24}$H$_{12}$) is investigated theoretically using an approach based on the one-dimension Hubbard model for…

Atomic Physics · Physics 2022-08-09 Ralf Wehlitz , David L. Huber

Strong electron correlation effects in the photophysics of quasi-one-dimensional $\pi$-conjugated organic systems such as polyenes, polyacetylenes, polydiacetylenes, etc., have been extensively studied. Far less is known on correlation…

Strongly Correlated Electrons · Physics 2014-02-18 K. Aryanpour , A. Roberts , A. Sandhu , R. Rathore , A. Shukla , S. Mazumdar

It is shown that the M$^{2+}$ ion yield in the double photoionization of the aromatic hydrocarbons, pyrene and coronene, can be expressed as a superposition of a contribution from a resonance involving carbon atoms on the perimeter and…

Chemical Physics · Physics 2020-01-23 David L. Huber , Ralf Wehlitz

A well-known property of aromatic molecules is their highly anisotropic response to the presence of an external magnetic field: the component of their magnetic susceptibility parallel to the field is generally much larger than the remaining…

Strongly Correlated Electrons · Physics 2021-05-26 Thaís V. Trevisan , Gustavo M. Monteiro , Amir O. Caldeira

We report studies of the correlated excited states of coronene and substituted coronene within the Pariser-Parr-Pople (PPP) correlated $\pi$-electron model employing symmetry adapted density matrix renormalization group technique. These…

Chemical Physics · Physics 2019-02-15 Suryoday Prodhan , Sumit Mazumdar , S. Ramasesha

The aromaticity in the polyacene analogues of several inorganic ring compounds (BN-acenes, CN-acenes, BO-acenes and Na6-acenes) is reported here for the first time. Conceptual density functional theory based reactivity descriptors and the…

Atomic and Molecular Clusters · Physics 2016-09-28 Pratim Kumar Chattaraj , Debesh Ranjan Roy

The electronic and optical properties of various polycyclic aromatic hydrocarbons (PAHs) with lower symmetry, namely, benzo[ghi]perylene (C$_{22}$H$_{12}$), benzo[a]coronene (C$_{28}$H$_{14}$), naphtho[2,3a]coronene (C$_{32}$H$_{16}$),…

Chemical Physics · Physics 2020-07-07 Pritam Bhattacharyya , Deepak Kumar Rai , Alok Shukla

The electronic and optical properties of polycyclic aromatic hydrocarbons (PAHs) present a strong dependence on their size and geometry. We tackle this issue by analyzing the spectral features of two prototypical classes of PAHs, belonging…

Soft Condensed Matter · Physics 2014-09-09 Caterina Cocchi , Deborah Prezzi , Alice Ruini , Marilia J. Caldas , Elisa Molinari

We present numerical studies of one- and two-photon excited states ordering in a number of polycyclic aromatic hydrocarbon molecules: coronene, hexa-peri-hexabenzocoronene and circumcoronene, all possessing $D_{6h}$ point group symmetry…

Strongly Correlated Electrons · Physics 2014-03-12 K. Aryanpour , A. Shukla , S. Mazumdar

Over twenty years ago one of us suggested the title was affirmative. In 2012 Cooper pairs were identified in several, but not all aromatic compounds tested, benzene being one. This manuscript discusses the formation of three time-reversed…

Superconductivity · Physics 2013-11-20 R. H. Squire , N. H. March , A. Rubio

The rich molecular structures of polycyclic aromatic hydrocarbons -- essentially planar flakes of fused benzene rings -- and their fullerene cousins are revealed through their vibrational and electronic spectra.

Astrophysics of Galaxies · Physics 2019-08-19 A. Candian , J. Zhen , A. G. G. M. Tielens

Ubiquitous unidentified infrared emission bands are seen in many astronomical sources. Although these bands are widely, if not unanimously, attributed to the collective emission from polycyclic aromatic hydrocarbons, no single species from…

We investigate the possibility of electron pairing in small metallic nanoparticles at zero temperature. In these particles both electrons and phonons are mesoscopic, i.e. modified by the nanoparticle's finite size. The electrons, the…

Superconductivity · Physics 2011-08-30 Ze'ev Lindenfeld , Eli Eisenberg , Ron Lifshitz

Spectral and transport properties of small molecule single-crystal organic semiconductors have been theoretically analyzed focusing on oligoacenes, in particular on the series from naphthalene to rubrene and pentacene aiming to show that…

Strongly Correlated Electrons · Physics 2014-03-25 C. A. Perroni , F. Gargiulo , A. Nocera , V. Marigliano Ramaglia , V. Cataudella

Static properties of an anharmonic potential model for planar two-electron quantum dots are investigated using a method which allows for the exact representation of the matrix elements, including the full Coulombic electron - electron…

Mesoscale and Nanoscale Physics · Physics 2015-06-12 Sebastian Schröter , Paul-Antoine Hervieux , Giovanni Manfredi , Johannes Eiglsperger , Javier Madroñero

Aims. In this work we determine the effects of anharmonicity on the mid-infrared spectra of the linear polycyclic aromatic hydrocarbons (PAHs) naphthalene, anthracene, tetracene and pentacene recorded using the free electron laser FELIX.…

Astrophysics of Galaxies · Physics 2019-08-15 A. K. Lemmens , D. B. Rap , J. M. M. Thunnissen , C. J. Mackie , A. Candian , A. G. G. M. Tielens , A. M. Rijs , W. J. Buma

The superconducting pairing of electrons in doped graphene due to in-plane and out-of-plane phonons is considered. It is shown that the structure of the order parameter in the valley space substantially affects conditions of the pairing.…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 Yu. E. Lozovik , S. L. Ogarkov , A. A. Sokolik

Pion exchange in S-wave between hadrons that are themselves in a relative S-wave is shown to shift energies by hundreds of MeV, leading to deeply bound quasi-molecular states. In the case of charmed mesons $D^*,D_1$ a spectroscopy arises…

High Energy Physics - Phenomenology · Physics 2010-05-12 Frank Close , Clark Downum , Christopher E. Thomas
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