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Identical classical particles are distinguishable. This distinguishability affects the number of ways W a macrostate can be realized on the micro-level, and from the relation S = k ln W leads to a non-extensive expression for the entropy.…

Statistical Mechanics · Physics 2015-05-20 Marijn A. M. Versteegh , Dennis Dieks

The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the…

Chemical Physics · Physics 2009-12-03 Chi-Ho Cheng

The Gibbs paradox has frequently been interpreted as a sign that particles of the same kind are fundamentally indistinguishable; and that quantum mechanics, with its identical fermions and bosons, is indispensable for making sense of this.…

Quantum Physics · Physics 2010-03-02 Dennis Dieks

Gibbs paradox in the context of statistical mechanics addresses the issue of additivity of entropy of mixing gases. The usual discussion attributes the paradoxical situation to classical distinguishability of identical particles and credits…

Quantum Physics · Physics 2018-11-12 C. S. Unnikrishnan

This letter presents a new, solely thermodynamical argument for considering the states of the quantum isolated horizon of a black hole as distinguishable. We claim that only if the states are distinguishable, the thermodynamic entropy is an…

General Relativity and Quantum Cosmology · Physics 2016-11-26 Andreas G. A. Pithis

The division by N! in the expression of statistical entropy is usually justified to students by the statement that classical particles should be counted as indistinguishable. Sometimes, quantum indistinguishability is invoked to explain it.…

Statistical Mechanics · Physics 2023-05-24 Sergio Di Matteo

The suggestion that particles of the same kind may be indistinguishable in a fundamental sense, even so that challenges to traditional notions of individuality and identity may arise, has first come up in the context of classical…

Quantum Physics · Physics 2015-06-19 Dennis Dieks

The Gibbs Mixing Paradox is a conceptual touchstone for understanding mixtures in statistical mechanics. While debates over the theoretical subtleties of particle distinguishability continue to this day, we seek to extend the discussion in…

Statistical Mechanics · Physics 2018-07-31 Cato Sandford , Daniel Seeto , Alexander Y. Grosberg

We consider the canonical ensemble of $N$ particles admitting a strange Hamiltonian description. Each of the particles obeys a set of Newtonian equation of motion, which can also be described by the standard canonical Hamiltonian mechanics.…

Statistical Mechanics · Physics 2013-06-11 Liu Zhao

Consistent statistical physical description is given for systems where the elementary excitations are composite objects. Explicit calculational scheme is constructed for the energy density and the total number of thermodynamical degrees of…

High Energy Physics - Phenomenology · Physics 2011-03-01 A. Jakovac

The concept of classical indistinguishability is analyzed and defended against a number of well-known criticisms, with particular attention to the Gibbs' paradox. Granted that it is as much at home in classical as in quantum statistical…

Quantum Physics · Physics 2007-05-23 Simon Saunders

In the framework of the Gibbs statistical theory, the question of the size of the particles forming the statistical system is investigated. This task is relevant for a wide variety of applications. The distribution for particle sizes and…

Statistical Mechanics · Physics 2017-11-23 V. V. Ryazanov

Indistinguishability of particles is normally considered to be an inherently quantum property which cannot be possessed by a classical theory. However, Saunders has argued that this is incorrect, and that classically indistinguishable…

Statistical Mechanics · Physics 2007-05-23 Daniel Gottesman

The Gibbs Paradox is essentially a set of open questions as to how sameness of gases or fluids (or masses, more generally) are to be treated in thermodynamics and statistical mechanics. They have a variety of answers, some restricted to…

History and Philosophy of Physics · Physics 2018-08-07 Simon Saunders

It is shown that quantum systems of identical particles can be treated as if they were different when they are in well differentiated states. This simplifying assumption allows the consideration of quantum systems isolated from the rest of…

Quantum Physics · Physics 2009-03-12 Alberto C. de la Torre , Hector O. Martin

Colloidal clusters consist of small numbers of colloidal particles bound by weak, short-range attractions. The equilibrium probability of observing a cluster in a particular geometry is well-described by a statistical mechanical model…

Soft Condensed Matter · Physics 2018-10-03 Ellen D. Klein , Rebecca W. Perry , Vinothan N. Manoharan

Statistics of distinguishable particles has become relevant in systems of colloidal particles and in the context of applications of statistical mechanics to complex networks. When studying these type of systems with the standard textbook…

Statistical Mechanics · Physics 2016-08-24 A. Fernandez-Peralta , Raul Toral

Defining the entropy of classical particles raises a number of paradoxes and ambiguities, some of which have been known for over a century. Several, such as Gibbs' paradox, involve the fact that classical particles are distinguishable, and…

Soft Condensed Matter · Physics 2016-12-28 Michael E. Cates , Vinothan N. Manoharan

This is a systematic review of the concept of indistinguishability in both classical and quantum mechanics, with particular attention to Gibbs' paradox. Section 1 is on the Gibbs paradox; section 2 is a defense of the concept of classical…

History and Philosophy of Physics · Physics 2016-09-20 Simon Saunders

We follow the time sequence of binary elastic collisions in a small collection of hard-core particles. Intervals between the collisions are characterized by the numbers of collisions of different pairs in a given time. It was shown…

Chaotic Dynamics · Physics 2012-02-21 Alexander Jonathan Vidgop , Itzhak Fouxon
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