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Structural and magnetic transitions in a double perovskite hosting 5d1 Re ions are discussed on the basis of recently published high-resolution x-ray diffraction patterns [D. Hirai, et al., Phys. Rev. Res. 2, 022063(R) (2020)]. A reported…

Strongly Correlated Electrons · Physics 2021-06-30 S. W. Lovesey , D. D. Khalyavin

Thickness driven electronic phase transitions are broadly observed in different types of functional perovskite heterostructures. However, uncertainty remains whether these effects are solely due to spatial confinement, broken symmetry or…

ABO3 perovskite multiferroic La0.5Bi0.5Mn0.5Fe0.5O3.09 where the B-site cations is responsible for the magnetic properties and the A-site cation with lone pair electron is responsible for the ferroelectric properties was synthesized at…

Materials Science · Physics 2008-08-25 Asish K. Kundu , R. Ranjith , V. Pralong , N. Nguyen , B. Kundys , V. Caignaert , W. Prellier , B. Raveau

(BiFeO3)(1-x){\Lambda}/(LaFeO3)x{\Lambda} superlattices (SLs) with varying x have been grown by pulsed laser deposition on (111) oriented SrTiO3 substrates. In order to obtain good epitaxy and flat samples a conducting SrRuO3 buffer has…

Materials Science · Physics 2019-01-08 J. Belhadi , S. Yousfi , H. Bouyanfif , M. El Marssi

A-site ordered perovskites, CaCu$_3$B$_4$O$_{12}$, which are derivatives of conventional ABO$_3$ perovskites, exhibit varying electronic and magnetic properties. With the objective of examining the role of Cu in this work, we have studied…

Strongly Correlated Electrons · Physics 2022-10-12 Jatin Kumar Bidika , Amit Chauhan , B. R. K. Nanda

The crystal structure of BiFeO3/BaxSr1-xTiO3 (BFO/BST) heterostructures with x = 0.2, 0.6 and 0.8, grown on single-crystal MgO (001) substrate was investigated by x-ray diffraction and Raman spectroscopy in order to determine the influence…

We employed first-principles density functional theory calculations guided by group-theoretical analysis and demonstrated the control of insulator-metal-insulator transition, polarization and two sublattice magnetization in…

Materials Science · Physics 2022-02-07 Monirul Shaikh , Saurabh Ghosh

The hyperfine interaction between the quadrupole moment of atomic nuclei and the electric field gradient (EFG) provides information on the electronic charge distribution close to a given atomic site. In ferroelectric materials, the loss of…

Materials Science · Physics 2012-07-31 J. N. Gonçalves , A. Stroppa , J. G. Correia , T. Butz , S. Picozzi , A. S. Fenta , V. S. Amaral

Polarization hysteresis loops, x-ray diffraction (XRD) and temperature dependent dielectric constant under different electric fields for <110> oriented 0.7 Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 single crystals were measured. The field-induced phase…

Materials Science · Physics 2007-05-23 Ke-Pi Chen , Xiao-Wen Zhang , Fei Fang , Hao-Su Luo

Ba2CoGe2O7, crystallizing in the noncentrosymmetric but nonpolar structure, belongs to a special class of multiferroic materials, whose properties are predetermined by the rotoinversion symmetry. Unlike inversion, the rotoinversion symmetry…

Materials Science · Physics 2015-06-23 I. V. Solovyev

We report a x-ray resonant diffraction study of the perovskite Pr0.6Ca0.4MnO3. At the Mn K-edge, this technique is sensitive to details of the electronic structure of the Mn atoms. We discuss the resonant x-ray spectra measured above and…

Strongly Correlated Electrons · Physics 2009-11-10 S. Grenier , J. P. Hill , Doon Gibbs , K. J. Thomas , M. v. Zimmermann , C. S. Nelson , V. Kiryukhin , Y. Tokura , D. Casa , T. Gog , C. Venkataraman

Magnetic interfaces and the phenomena arising from them drive both the design of modern spintronics and fundamental research. Recently, it was revealed that through designing magnetic frustration in configurationally complex entropy…

Halide perovskite semiconductors respond to electric fields in a way that varies across time and length scales. We discuss the microscopic processes that give rise to the macroscopic polarization of these materials, ranging from the optical…

Materials Science · Physics 2018-12-04 Jacob N. Wilson , Jarvist M. Frost , Suzanne K. Wallace , Aron Walsh

In strongly correlated electronic systems, several novel physical properties are induced by the orbital degree of freedom. In particular, orbital degeneracy near the Fermi level leads to spontaneous symmetry breaking, such as the nematic…

Strongly Correlated Electrons · Physics 2021-02-02 Ling-Fang Lin , Nitin Kaushal , Yang Zhang , Adriana Moreo , Elbio Dagotto

The crystal structure of KAgF3 was studied by powder neutron diffraction. KAgF3 exhibits at all temperatures an orthorhombic symmetry in space group Pnma that allows for several distortions with respect to the ideal cubic perovskite…

Detailed structural measurements were conducted on a new perovskite, ScMnO3, and on orthorhombic LuMnO3. Complementary density functional theory (DFT) calculations were carried out, and predict that ScMnO3 possesses E-phase magnetic order…

Strongly Correlated Electrons · Physics 2015-06-19 T. Yu , T. A. Tyson , H. Y. Chen , A. M. M. Abeykoon , Y. -S. Chen , K. H. Ahn

The 3$d$-5$d$ based double perovskites are of current interest as they provide model system to study the interplay between electronic correlation ($U$) and spin-orbit coupling (SOC). Here we report detailed structural, magnetic and…

Strongly Correlated Electrons · Physics 2017-10-30 K C Kharkwal , A K Pramanik

Single phase polycrystalline sample of perovskite Sr2TiMnO6 (STMO) has been successfully synthesized via solid state reaction route. Its detailed structural and physical properties have been studied using x-ray diffraction, transmission…

Materials Science · Physics 2016-09-06 Shivani Sharma , R. Rawat , N. P. Lalla

The potential of hybrid improper ferroelectrics (HIFs) in electronic and spintronic devices hinges on their ability to switch polarization. Although the coupling between octahedral rotation and tilt is well established, the factors that…

Materials Science · Physics 2026-01-19 Ayana Ghosh , Palanichamy Gayathri , Sathiyamoorthy Buvaneswaran , Saurabh Ghosh

The nature of the "forbidden" local- and long-range polar order in nominally nonpolar paraelectric phases of ferroelectric materials has been an open question since the discovery of ferroelectricity in oxide perovskites (ABO3). A currently…