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We study electron transport properties of some molecular wires and a unconventional disordered thin film within the tight-binding framework using Green's function technique. We show that electron transport is significantly affected by…

Mesoscale and Nanoscale Physics · Physics 2009-06-29 Santanu K. Maiti

Electronic conductance through a single molecule is sensitive towards its structural orientation between two electrodes, owing to the distribution of molecular orbitals and their coupling to the electrode levels, that are governed by…

Mesoscale and Nanoscale Physics · Physics 2023-08-11 Koushik R. Das , Sudipta Dutta

We investigate the electron transport properties of a model magnetic molecule formed by two magnetic centers whose exchange coupling can be altered with a longitudinal electric field. In general we find a negative differential conductance…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Sujeet K. Shukla , Stefano Sanvito

The great majority of electronic and optoelectronic devices depends on interfaces between n-type and p-type semiconductors. Finding such matching donor-acceptor systems in molecular crystals remains a challenging endeavor. Structurally…

The vertical configuration is a powerful tool recently developed experimentally to investigate field effects in quasi 2D systems. Prototype graphene-based vertical tunneling transistors can achieve an extraordinary control over current…

Mesoscale and Nanoscale Physics · Physics 2017-05-17 Yun-Peng Wang , J. N. Fry , Hai-Ping Cheng

We theoretically analyze correlation effects on the transport properties of a benzene molecule that are mediated by interactions between the motion of the nuclei and the transmitted charge. We focus on the lowest-lying molecular vibrational…

Mesoscale and Nanoscale Physics · Physics 2013-08-09 Michael Knap , Enrico Arrigoni , Wolfgang von der Linden

We present a theoretical study of electron transport through a molecule connected to two metallic nanocontacts. The system investigated is 1,4 benzene-dithiolate (BDT) chemically bonded to two Au contacts. The surface chemistry is modeled…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Eldon Emberly , George Kirczenow

We consider resonant transmission through a finite-length quantum wire connected to leads via finite transparency junctions. The coherent electron transport is strongly modified by the Coulomb interaction. The low-temperature…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 N. B. Kopnin , Y. M. Galperin , V. M. Vinokur

We investigate electron transport through a mixed-valence molecular complex in which an excess electron can tunnel between hetero-valent transition metal ions, each having a fixed localized spin. We show that in this class of molecules the…

Mesoscale and Nanoscale Physics · Physics 2009-03-11 F. Reckermann , M. Leijnse , M. R. Wegewijs

We examine, using mixed classical-quantum electron-ion dynamics, electron transfer in a donor-acceptor-like molecular junction system based on polyacetylene. We identify two qualitatively-different transfer regimes: hopping and tunnelling.…

Mesoscale and Nanoscale Physics · Physics 2014-04-25 D. Psiachos

We discuss the heat transfer by photons between two metals coupled by a linear element with a reactive impedance. Using a simple circuit approach, we calculate the spectral power transmitted from one resistor to the other and find that it…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 L. Pascal , H. Courtois , F. W. J. Hekking

Charge separation properties, that is the ability of a chromophore, or a chromophore/semiconductor interface, to separate charges upon light absorption, are crucial characteristics for an efficient photovoltaic device. Starting from this…

Chemical Physics · Physics 2019-12-05 Thibaud Etienne , Mariachiara Pastore

Analytic results for the conductance of a molecular wire attached to mesoscopic tubule leads are obtained. They permit to study linear transport in presence of low dimensional leads in the whole range of parameters. In particular contact…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 G. Cuniberti , G. Fagas , K. Richter

We study electronic transport through a magnetic molecule with an intrinsic spin $S$ coupled to two magnetic electrodes, in the incoherent regime. The molecule is modeled as a single resonant level with large Coulomb repulsion (no double…

Mesoscale and Nanoscale Physics · Physics 2010-11-19 Thibaut Jonckheere , Ken-Ichiro Imura , Thierry Martin

Using a pi-orbital tight-binding model, we study the elastic and photoassisted transport properties of metal-molecule-metal junctions based on oligophenylenes of varying lengths. The effect of monochromatic light is modeled with an ac…

Mesoscale and Nanoscale Physics · Physics 2009-05-24 J. K. Viljas , F. Pauly , J. C. Cuevas

We investigate electronic transport through two types of conjugated molecules. Mechanically controlled break-junctions are used to couple thiol endgroups of single molecules to two gold electrodes. Current-voltage characteristics (IVs) of…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 J. Reichert , R. Ochs , D. Beckmann , H. B. Weber , M. Mayor , H. v. Loehneysen

Recent advances in experimental and computational techniques have allowed for an accurate description of the adsorption of ionic liquids on metallic electrodes. It is now well established that they adopt a multi-layered structure, and that…

Materials Science · Physics 2016-03-15 Benjamin Rotenberg , Mathieu Salanne

We investigate the electron transfer from a dissociatively adsorbed H2 molecule to a Au(111) surface using the first-principles methods. A fractional electron transfers from a molecule to a substrate, and potential energy increases during…

Materials Science · Physics 2009-11-13 Shigeyuki Takagi , Jun-ichi Hoshino , Hidekazu Tomono , Kazuo Tsumuraya

Redox molecular junctions are molecular conduction junctions that involve more than one oxidation state of the molecular bridge. This property is derived from the ability of the molecule to transiently localize transmitting electrons,…

Mesoscale and Nanoscale Physics · Physics 2013-06-21 Agostino Migliore , Abraham Nitzan

We study theoretically the electron transport in a 1D conductor adiabatically connected to a superconducting and normal metal leads. In the case of non-interacting we show that ac voltage applied along with dc voltage modifies I-V curve…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 P. P. Aseev , S. N. Artemenko