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Fourier transform deep level transient spectroscopy has been performed between 80 K and 550 K in five n-type ZnO samples grown by different techniques. The capture cross section and ionization energy of four electron traps have been deduced…

Materials Science · Physics 2015-06-18 Gauthier Chicot , Pierre Muret , Julien Pernot , J. L. Santailler , Guy Feuillet

Dislocation core chemistry in oxides critically influences mechanical behavior and functionality; yet the evolution of core chemistry during the dislocation motion in them has not been directly observed. Here, using SrTiO3 as a model…

Materials Science · Physics 2026-05-04 Min-Chul Kang , Chunxu Yan , Alexander Frisch , Xufei Fang , Liming Xiong , Lin Zhou

We study the effect of oxygen vacancies on the electronic structure of the model strongly correlated metal SrVO$_3$. By means of angle-resolved photoemission (ARPES) synchrotron experiments, we investigate the systematic effect of the UV…

SrTiO3 (STO) displays a broad spectrum of physical properties, including superconductivity, ferroelectricity, and photoconductivity, making it a standout semiconductor material. Despite extensive researches, the oxygen partial…

Materials Science · Physics 2026-04-27 Zenghua Cai , Chunlan Ma

The oxide interface SrTiO3/LaAlO3 supports a 2D electron liquid displaying superconductivity and magnetism, while allowing for a continuous control of the electron density using a gate. Our recent measurements have shown a similar…

Strongly Correlated Electrons · Physics 2017-02-22 Eran Maniv , Yoram Dagan , Moshe Goldstein

Cu$_2$O has appealing properties as an electrode for photo-electrochemical water splitting, yet its practical performance is severely limited by inefficient charge extraction at the interface. Using hybrid DFT calculations, we investigate…

Materials Science · Physics 2021-03-09 Chiara Ricca , Lisa Grad , Matthias Hengsberger , Jürg Osterwalder , Ulrich Aschauer

The iron(III) center in ferroelectric PbTiO3 together with an oxygen vacancy forms a charged defect associate, oriented along the crystallographic c-axis. Its microscopic structure has been analyzed in detail comparing results from a…

In this study, we report on investigations of the electronic structure of SrTiO$_3$ annealed at temperature ranging between 550 and 840$^\circ$C in an ultrahigh vacuum. Annealing induced oxygen vacancies (O$_{vac}$) impart considerable…

Materials Science · Physics 2014-08-18 Prabir Pal , Pramod Kumar , Aswin V. , Anjana Dogra , Amish G. Joshi

Quasi-two-dimensional electron systems (q-2DES) are formed in various hetero-structures, including oxide interfaces. Oxygen vacancies (OVs) in oxides like $\mathrm{SrTiO_3}$ are known to produce electronic carriers. A novel way to produce…

Mesoscale and Nanoscale Physics · Physics 2022-07-27 Shyam Sundar Yadav , Shelender Kumar , Pankaj Kumar , Ananth Venkatesan

We perform an electronic structure study for cerium oxide homogeneously-doped with cobalt impurities, focusing on the role played by oxygen vacancies and structural relaxation. By means of full-potential ab-initio methods, we explore the…

Strongly Correlated Electrons · Physics 2010-06-18 V. Ferrari , A. M. Llois , V. Vildosola

Transition metal oxides have been extensively studied and utilized as efficient catalysts. However, the strongly correlated behavior which often results in intriguing emergent phenomena in these materials has been mostly overlooked in…

{\it Ab initio} calculations within density functional theory with generalized gradient approximation have been performed to study the effects of oxygen vacancies on the electronic structure and magnetism in undoped V$_2$O$_{5-x}$ ($0 < x <…

Materials Science · Physics 2008-02-12 Zhi Ren Xiao , Guang Yu Guo , Po Han Lee , Hua Shu Hsu , Jung Chun Andrew Huang

We report controlled formation of sub-100 nm-thin electron channels in SrTiO$_3$ by doping with oxygen vacancies induced by Ar$^+$-ion irradiation. The conducting channels exhibit a consistent high electron mobility (~15,000…

Mesoscale and Nanoscale Physics · Physics 2015-11-03 Jung-Won Chang , Joon Sung Lee , Tae Ho Lee , Jinhee Kim , Yong-Joo Doh

The 2DEG at the LaAlO3/SrTiO3 interface promises to add a new dimension to emerging electronic devices due to its high tunability. Defects in the form of Oxygen vacancies in titanate surfaces and interfaces, on the other hand, play a key…

Superconductivity · Physics 2014-05-14 N. Mohanta , A. Taraphder

We have investigated the role of transition metal impurities and oxygen vacancies in the formation of ferromagnetism in Co-doped TiO2 using LSDA+U approach which takes into account strong on-cite Coulomb correlations for electronic…

Strongly Correlated Electrons · Physics 2007-05-23 V. I. Anisimov , M. A. Korotin , I. A. Nekrasov , A. S. Mylnikova , A. V. Lukoyanov , J. -L. Wang , Z. Zeng

Strontium titanate (SrTiO3) is widely used as a promising photocatalyst due to its unique band edge alignment with respect to the oxidation and reduction potential corresponding to oxygen evolution reaction (OER) and hydrogen evolution…

The presence of oxygen vacancy, as well as ordering of vacancies plays an important role in determining the electronic, ionic and thermal transport properties of many transition metal oxide materials. Controlling the concentration of oxygen…

Mesoscale and Nanoscale Physics · Physics 2018-12-05 Xue Rui , Robert Klie

Using first-principles density functional theory calculations, we find a strong position and thickness dependence of the formation energy of oxygen vacancies in LaAlO3|SrTiO3 (LAO|STO) multilayers and interpret this with an analytical…

Materials Science · Physics 2010-11-01 Zhicheng Zhong , P. X. Xu , Paul J. Kelly

The relative significance of quantum conductivity correction and magnetic nature of electrons in understanding the intriguing low-temperature resistivity minimum and negative magnetoresistance of the two-dimensional electron gas at…

Strongly Correlated Electrons · Physics 2021-08-11 Xiaorong Zhou , Zhiqi Liu

The electronic structure of SrTiO3 and SrHfO3 (001) surfaces with oxygen vacancies is studied by means of first-principles calculations. We reveal how oxygen vacancies within the first atomic layer of the SrTiO3 surface (i) induce a large…

Strongly Correlated Electrons · Physics 2016-01-13 A. C. Garcia-Castro , M. G. Vergniory , E. Bousquet , A. H. Romero