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The mathematical model describing the non-stationary natural pH-gradient arising under the action of an electric field in an aqueous solution of ampholytes (amino acids) is constructed and investigated. The model is part of a more general…

Chemical Physics · Physics 2013-11-22 E. V. Shiryaeva , N. M. Zhukova , M. Yu. Zhukov

The mathematical model describing the non-stationary natural pH-gradient arising under the action of an electric field in an aqueous solution of ampholytes (amino acids) is constructed. The model is a part of a more general model of the…

Chemical Physics · Physics 2013-11-26 E. V. Shiryaeva , N. M. Zhukova , M. Yu. Zhukov

A mathematical model describing a steady pH-gradient in the solution of ampholytes in water has been studied with the use of analytical, asymptotic, and numerical methods. We show that at the large values of an electric current a…

Chemical Physics · Physics 2009-02-24 L. V. Sakharova , V. A. Vladimirov , M. Yu. Zhukov

We propose an efficient simulation algorithm based on the dissipative particle dynamics (DPD) method for studying electrohydrodynamic phenomena in electrolyte fluids. The fluid flow is mimicked with DPD particles while the evolution of the…

Computational Physics · Physics 2015-06-23 Stefan Medina , Jiajia Zhou , Zhen-Gang Wang , Friederike Schmid

Diffusiophoresis of charged particles in the presence of electrolytes has been extensively studied in the literature. However, in these setups, particles typically move in a single direction, either up or down the electrolyte gradient.…

Soft Condensed Matter · Physics 2025-06-09 Ethan Coleman , Ankur Gupta

Electrohydrodynamics is crucial in many nanofluidic and biotechnological applications. In such small scales, the complexity due to the coupling of fluid dynamics with the dynamics of ions is increased by the relevance of thermal…

Fluid Dynamics · Physics 2022-01-19 Alberto Gubbiotti , Mauro Chinappi , Carlo Massimo Casciola

Diffusiophoretic motion induced by gradients of dissolved species has enabled the manipulation of colloids over large distances, spanning hundreds of microns. Nonetheless, studies have primarily focused on simple geometries that feature 1D…

Soft Condensed Matter · Physics 2024-04-12 Carlos A. Silvera Batista , Kun Wang , Hannah Blake , Vivian Nwosu-Madueke , Sophie Marbach

We present a minimal model to study liquid phase separation in a fixed pH ensemble. The model describes a mixture composed of macromolecules that exist in three different charge states and have a tendency to phase separate. We introduce the…

Biological Physics · Physics 2020-10-30 Omar Adame-Arana , Christoph A. Weber , Vasily Zaburdaev , Jacques Prost , Frank Jülicher

A model is constructed to describe the arbitrary deformation of a drop or vesicle that contains and is embedded in an electrolyte solution, where the deformation is caused by an applied electric field. The applied field produces an…

Fluid Dynamics · Physics 2022-07-13 Manman Ma , Michael R. Booty , Michael Siegel

We propose a framework to study the spatio-temporal evolution of liquid-liquid phase separation of weak polyelectrolytes in ionic solutions. Unlike strong polyelectrolytes, which carry a fixed charge, the charge state of weak…

Soft Condensed Matter · Physics 2025-03-19 Giulia Laura Celora , Ralf Blossey , Andreas Munch , Barbara Wagner

We suggest to augment standard isoelectronic focusing for separation of proteins in a gradient of pH by a similar focusing in the presence of a strongly charged polyelectrolyte (PE). Proteins which have the same isoelectric point but…

Condensed Matter · Physics 2009-11-07 E. M. Baskin , B. I. Shklovskii , G. V. Zilberstein

We present a novel microfield approach for studying the dependence of the orientational polarization of the water in aqueous electrolyte solutions upon the salt concentration and temperature. The model takes into account the orientation of…

Chemical Physics · Physics 2016-07-15 Nir Gavish , Keith Promislow

The origin of enhanced reactivity in aqueous microdroplets remains debated, with interfacial electric fields (IEFs) often invoked as catalytic drivers. Here, we provide a quantum-mechanical, spatially resolved characterization of the…

Self-propelled particles that are subject to noise are a well-established generic model system for active matter. A homogeneous alignment field can be used to orient the direction of the self-propulsion velocity and to model systems like…

Statistical Mechanics · Physics 2024-03-06 Sameh Othman , Jiarul Midya , Thorsten Auth , Gerhard Gompper

The kinetics of an initially undercooled solid-liquid melt is studied by means of a generalized Phase Field model, which describes the dynamics of an ordering non-conserved field phi (e.g. solid-liquid order parameter) coupled to a…

Condensed Matter · Physics 2009-10-30 Umberto Marini Bettolo Marconi , Andrea Crisanti , Giulia Iori

Advanced in situ techniques based on electrons and X-rays are increasingly used to gain insights into fundamental materials dynamics in liquid media. Yet, ionizing radiation changes the solution chemistry. In this work, we show that…

This paper proposes a method for studying the early stages of the cavitation development in arbitrary, non-stationary conditions. This method is based on the comparison of the results of calculations in the framework of a theoretical model…

Fluid Dynamics · Physics 2014-04-02 M. N. Shneider , M. Pekker

A heterogeneous medium of constituents with vastly different mechanical properties, whose inhomogeneities are in close proximity to each other, is considered. The gradient of the solution to the corresponding problem exhibits singular…

Analysis of PDEs · Mathematics 2014-01-28 Yuliya Gorb

We study a stochastic model for the self-controlled particle-deposition process induced by optical near-fields. This process was experimentally realized by Yukutake et al. on an electrode of a novel photovoltaic device as Ag deposition…

Mesoscale and Nanoscale Physics · Physics 2015-07-29 Kan Takahashi , Makoto Katori , Makoto Naruse , Motoichi Ohtsu

Concentration gradients play a critical role in embryogenesis, bacterial locomotion, as well as the motility of active particles. Particles develop concentration profiles around them by dissolution, adsorption, or the reactivity of surface…

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