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In the study of model electronic device systems where electrons are typically under confinement, a key obstacle is the need to iteratively solve the coupled Schr\"{o}dinger-Poisson (SP) equation. It is possible to bypass this obstacle by…

Mesoscale and Nanoscale Physics · Physics 2014-12-16 Vikram Jadhao , Kaushik Mitra , Francisco J. Solis , Monica Olvera de la Cruz

The electronic Schr\"odinger equation describes the motion of $N$ electrons under Coulomb interaction forces in a field of clamped nuclei. It is proved that its solutions for eigenvalues below the essential spectrum lie in the spectral…

Analysis of PDEs · Mathematics 2026-04-10 Harry Yserentant

The dynamics of electrons in the presence of a positive ion is considered for conditions of weak electron-electron couping but strong electron-ion coupling. The equilibrium electron density and electric field time correlation functions are…

Statistical Mechanics · Physics 2007-05-23 James W. Dufty , Ilya V. Pogorelov , Bernard Talin , Annette Calisti

The essence of atomic structure theory, quantum chemistry, and computational materials science is solving the multi-electron stationary Schr\"odinger equation. The Quantum Monte Carlo-based neural network wave function method has surpassed…

Atomic Physics · Physics 2023-12-27 JinDe Liu , Chenglong Qin , Xi He , Gang Jiang

The interaction between freely propagating electrons and light waves is typically described using an approximation in which we assume that the electron velocity remains approximately the same during the interaction. In this article we…

Quantum Physics · Physics 2025-03-06 Marek Kuchař , Kamila Moriová , Martin Kozák

Schr{\"o}dinger-Pauli (SP) theory is a description of electrons in the presence of a static electromagnetic field in which the interaction of the magnetic field with both the orbital and spin moments is explicitly considered. The theory is…

Quantum Physics · Physics 2019-09-24 Viraht Sahni

For a given many-electron molecule, it is possible to define a corresponding one-electron Schr\"odinger equation, using potentials derived from simple atomic densities, whose solution predicts fairly accurate molecular orbitals for single-…

Chemical Physics · Physics 2022-05-16 Fariba Nazari , Jerry L. Whitten

We examine the spatial distribution of electrons generated by a fixed energy point source in uniform, parallel electric and magnetic fields. This problem is simple enough to permit analytic quantum and semiclassical solution, and it harbors…

Quantum Physics · Physics 2007-05-23 Christian Bracher , Tobias Kramer , John B. Delos

Solving the electronic Schr\"odinger equation for changing nuclear coordinates provides access to the Born-Oppenheimer potential energy surface. This surface is the key starting point for almost all theoretical studies of chemical processes…

Chemical Physics · Physics 2022-01-14 Markus Reiher

Starting from the Schr\"odinger-equation of a composite system, we derive unified dynamics of a classical harmonic system coupled to an arbitrary quantized system. The classical subsystem is described by random phase-space coordinates…

Quantum Physics · Physics 2007-05-23 Lajos Diosi

The full-dimensional time-dependent Schrodinger equation for the electronic dynamics of single-electron systems in intense external fields is solved directly using a discrete method. Our approach combines the finite-difference and Lagrange…

Atomic Physics · Physics 2009-11-10 Liang-You Peng , J F McCann , Daniel Dundas , K T Taylor , I D Williams

We show that the exact solution of the Schr\"odinger equation for two electrons confined to two distinct concentric rings or spheres can be found in closed form for particular sets of the ring or sphere radii. In the case of two concentric…

Chemical Physics · Physics 2015-06-12 Pierre-François Loos , Peter M. W. Gill

The non-equilibrium dynamics of electrons is of a great experimental and theoretical value providing important microscopic parameters of the Coulomb and electron-phonon interactions in metals and other cold plasmas. Because of the…

Superconductivity · Physics 2008-11-19 V. V. Kabanov , A. S. Alexandrov

A theory of electronic friction is developed using the exact factorization of the electron-nuclear wavefunction. No assumption is made regarding the electronic bath, which can be made of independent or interacting electrons, and the nuclei…

Quantum Physics · Physics 2022-06-01 Rocco Martinazzo , Irene Burghardt

The Schr\"odinger-Pauli theory of electrons in the presence of a static electromagnetic field can be described from the perspective of the individual electron via its equation of motion or `Quantal Newtonian' first law. The law is in terms…

Quantum Physics · Physics 2019-09-24 Marlina Slamet , Viraht Sahni

The importance of multi-electron dynamics during the tunnel ionization of a correlated quantum system is investigated. By comparison of the solution of the time-dependent Schr\"odinger equation (TDSE) with the time-dependent configuration…

Atomic Physics · Physics 2016-05-23 Maximilian Hollstein , Daniela Pfannkuche

The Schr\"odinger equation is solved for the wave function of an electron moving in a superposition of external constant and uniform electric and magnetic fields at an arbitrary angle between the field directions. The changing of the…

Quantum Physics · Physics 2017-02-10 S. O. Lebedynskyi , V. I. Miroshnichenko , R. I. Kholodov , V. A. Baturin

We study the equation of motion for the Noether current in an electron gas within the framework of the Schwinger-Keldysh Closed-Time-Path formalism. The equation is shown to be highly non-linear and irreversible even for a non-interacting,…

High Energy Physics - Theory · Physics 2015-09-18 Sašo Grozdanov , Janos Polonyi

Born-Oppenheimer dynamics is shown to provide an accurate approximation of time-independent Schr\"odinger observables for a molecular system with an electron spectral gap, in the limit of large ratio of nuclei and electron masses, without…

Mathematical Physics · Physics 2011-09-21 Christian Bayer , Håkon Hoel , Petr Plecháč , Anders Szepessy , Raúl Tempone

An embedding method for solving the time-dependent Schr\"odinger equation is developed using the Dirac-Frenkel variational principle. Embedding allows the time-evolution of the wavefunction to be calculated explicitly in a limited region of…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 J. E. Inglesfield