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Related papers: Optimal protocols and the Jarzynski equality

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Many techniques originally developed in the context of deterministic control theory have been recently applied to the quest for optimal protocols in stochastic processes. Given a system subject to environmental fluctuations, one may ask…

Statistical Mechanics · Physics 2025-01-15 Dario Lucente , Alessandro Manacorda , Andrea Plati , Alessandro Sarracino , Marco Baldovin

We consider the quantum mechanical generalization of Crooks Fluctuation Theorem and Jarzynski Equality for an open quantum system. The explicit expression for microscopic work for an arbitrary prescribed protocol is obtained, and the…

Statistical Mechanics · Physics 2008-12-31 H. T. Quan , H. Dong

We consider damped stochastic systems in a controlled (time-varying) quadratic potential and study their transition between specified Gibbs-equilibria states in finite time. By the second law of thermodynamics, the minimum amount of work…

Statistical Mechanics · Physics 2018-03-23 Yongxin Chen , Tryphon Georgiou , Allen Tannenbaum

Thermodynamics is the phenomenological theory of heat and work. Here we analyze to what extent quantum thermodynamic relations are immune to the underlying mathematical formulation of quantum mechanics. As a main result, we show that the…

Quantum Physics · Physics 2016-04-21 Bartłomiej Gardas , Sebastian Deffner , Avadh Saxena

We reconsider a well-known relationship between the fluctuation theorem and the second law of thermodynamics by evaluating a probability measure-valued process. In order to establish a bridge between microscopic and macroscopic behaviors,…

Statistical Mechanics · Physics 2015-03-19 Yuki Sughiyama , Masayuki Ohzeki

We give a field-theoretic proof of the nonequilibrium work relations for a space dependent field with stochastic dynamics. The path integral representation and its symmetries allow us to derive Jarzynski's equality. In addition, we derive a…

Statistical Mechanics · Physics 2008-02-01 Kirone Mallick , Moshe Moshe , Henri Orland

The free energy of glasses cannot be estimated using thermodynamic integration, as glasses are intrinsically not in equilibrium. We present numerical simulations showing that, in contrast, plausible free-energy estimates of a Kob-Andersen…

Statistical Mechanics · Physics 2021-07-07 H. A. Vinutha , Daan Frenkel

We prove the Jarzynski relation for general stochastic processes including non-Markovian systems with memory. The only requirement for our proof is the existence of a stationary state, therefore excluding non-ergodic systems. We then show…

Statistical Mechanics · Physics 2007-09-27 Thomas Speck , Udo Seifert

We study nonequilibrium work relations for a space-dependent field with stochastic dynamics (Model A). Jarzynski's equality is obtained through symmetries of the dynamical action in the path integral representation. We derive a set of exact…

Statistical Mechanics · Physics 2011-02-18 Kirone Mallick , Moshe Moshe , Henri Orland

Quantifying energy flows at nanometer scales promises to guide future research in a variety of disciplines, from microscopic control and manipulation, to autonomously operating molecular machines. A general understanding of the…

Statistical Mechanics · Physics 2018-11-26 Steven J. Large , Raphaël Chetrite , David A. Sivak

Based only on classical Hamiltonian dynamics, we prove the maximum work principle in a system where macroscopic dynamical degrees of freedom are intrinsically coupled to microscopic degrees of freedom. Unlike recent identities between…

Statistical Mechanics · Physics 2015-05-26 Christian Maes , Hal Tasaki

How much free energy is irreversibly lost during a thermodynamic process? For deterministic protocols, lower bounds on energy dissipation arise from the thermodynamic friction associated with pushing a system out of equilibrium in finite…

Statistical Mechanics · Physics 2021-03-26 Samuel J. Bryant , Benjamin B. Machta

A recent result, relating the (irreversible) work performed on a system during a non-quasistatic process, to the Helmholtz free energy difference between two equilibrium states of the system, is discussed. A proof of this result is given…

Statistical Mechanics · Physics 2007-05-23 C. Jarzynski

Nonequilibrium processes of small systems such as molecular machines are ubiquitous in biology, chemistry and physics, but are often challenging to comprehend. In the past two decades, several exact thermodynamic relations of nonequilibrium…

Statistical Mechanics · Physics 2018-02-26 Thai M. Hoang , Rui Pan , Jonghoon Ahn , Jaehoon Bang , H. T. Quan , Tongcang Li

Here we investigate the impact of temporal entanglement on a system's ability to perform thermodynamical work. We show that while the quantum version of the Jarzynski equality remains satisfied even in the presence of temporal entanglement,…

Quantum Physics · Physics 2012-04-26 Vlatko Vedral

The distribution of work done on a quantum system by instantaneously changing the Hamiltonian is shown to satisfy the Jarzynski identity.

Statistical Mechanics · Physics 2007-05-23 Shaul Mukamel

We define common thermodynamic concepts purely within the framework of general Markov chains and derive Jarzynski's equality and Crooks' fluctuation theorem in this setup. In particular, we regard the discrete time case that leads to an…

Statistical Mechanics · Physics 2022-12-14 Pedro Hack , Sebastian Gottwald , Daniel A. Braun

The eigenvalue of the hermitic Hamiltonian is real undoubtedly. Actually, The reality can also be guaranteed by the $PT$-symmetry. The hermiticity and the $PT$-symmetric quantum theory both have requirements regarding the boundary…

Quantum Physics · Physics 2018-03-16 Hao Jiang , Xiang-Jun Kong , Hui-Ping Huang

In multi-period stochastic optimization problems, the future optimal decision is a random variable whose distribution depends on the parameters of the optimization problem. We analyze how the expected value of this random variable changes…

Optimization and Control · Mathematics 2020-01-28 Bar Light

Physical systems driven away from equilibrium by an external controller dissipate heat to the environment; the excess entropy production in the thermal reservoir can be interpreted as a "cost" to transform the system in a finite time. The…

Statistical Mechanics · Physics 2024-12-31 Jérémie Klinger , Grant M. Rotskoff