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This work provides an alternative derivation of third order response functions in four wave mixing spectroscopy of multichromophoric macromolecular systems considering only single exciton states. For the case of harmonic oscillator bath…

Quantum Physics · Physics 2026-01-05 Seogjoo J. Jang

We explore the feasibility of coherent control of excitonic dynamics in light harvesting complexes, analyzing the limits imposed by the open nature of these quantum systems. We establish feasible targets for phase and phase/amplitude…

The generalized quantum master equation (GQME) approach provides a rigorous framework for deriving the exact equation of motion for any subset of electronic reduced density matrix elements (e.g., the diagonal elements). In the context of…

Quantum Physics · Physics 2023-02-03 Ningyi Lyu , Ellen Mulvihill , Micheline B. Soley , Eitan Geva , Victor S. Batista

The generalized quantum master equation provides a powerful framework for non-Markovian dynamics of open quantum systems. However, the accurate and efficient evaluation of the memory kernel remains a challenge. In this work, we introduce a…

Chemical Physics · Physics 2026-05-26 Rui-Hao Bi , Wei Liu , Wenjie Dou

A well-known approach to describe the dynamics of an open quantum system is to compute the master equation evolving the reduced density matrix of the system. This approach plays an important role in describing excitation transfer through…

Quantum Physics · Physics 2022-10-25 Kimara Naicker , Ilya Sinayskiy , Francesco Petruccione

New exact completely closed homogeneous Generalized Master Equations (GMEs), governing the evolution in time of equilibrium two-time correlation functions for dynamic variables of a subsystem of s particles (s<N) selected from N>>1…

Statistical Mechanics · Physics 2020-12-30 Victor F. Los

The Lindblad (GKLS) master equation, which represents the mathematical form for the general evolution of a density matrix, is a versatile and widely-used tool in open quantum systems. In contrast with the typical approach of imposing…

Quantum Physics · Physics 2026-04-17 Eugenia Pyurbeeva , Ronnie Kosloff

When deriving a master equation for a multipartite weakly-interacting open quantum systems, dissipation is often addressed \textit{locally} on each component, i.e. ignoring the coherent couplings, which are later added `by hand'. Although…

Magnetoelectroluminescence (MEL) of organic semiconductor has been experimentally tuned by adopting blended emitting layer consisting of both hole and electron transporting materials. A theoretical model considering intermolecular quantum…

Materials Science · Physics 2015-05-14 B. F. Ding , Y. Yao , X. Y. Sun , Z. Y. Sun , X. D. Gao , Z. T. Xie , Z. J. Wang , X. M. Ding , Y. Z. Wu , X. F. Jin , C. Q. Wu , X. Y. Hou

A detailed analysis of the quantum diffusive Stochastic Master Equation (SME) for qubit/cavity systems with dispersive coupling is provided. This analysis incorporates classical input signals and output signals (measurement outcomes through…

Quantum Physics · Physics 2026-04-01 Pierre Rouchon

Polaron-transformed quantum master equation (PQME) offers a unified framework to describe the dynamics of quantum systems in both limits of weak and strong couplings to environmental degrees of freedom. Thus, PQME serves as an efficient…

Quantum Physics · Physics 2026-01-01 Seogjoo J. Jang

We develop a framework that provides a few-mode master equation description of the interaction between a single quantum emitter and an arbitrary electromagnetic environment. The field quantization requires only the fitting of the spectral…

We present a model for exciton-plasmon coupling based on an energy exchange mechanism between quantum emitters (QE) and localized surface plasmons in metal-dielectric structures. Plasmonic correlations between QEs give rise to a collective…

Mesoscale and Nanoscale Physics · Physics 2020-11-12 Tigran V. Shahbazyan

The striking efficiency of energy transfer in natural photosynthetic systems and the recent evidence of long-lived quantum coherence in biological light harvesting complexes has triggered much excitement, due to the evocative possibility…

Mesoscale and Nanoscale Physics · Physics 2015-10-13 Yonatan Dubi

We present here a brief overview of our work in developing a convolutionless quantum master equation approach suitable for mesoscopic sized systems. Our final equation can be used in the regimes where the golden rule approach is not…

Materials Science · Physics 2007-05-23 Eric R. Bittner , Andrey Pereverzev

A remarkable amount of theoretical research has been carried out to elucidate the physical origins of the recently observed long-lived quantum coherence in the electronic energy transfer process in biological photosynthetic systems.…

Quantum Physics · Physics 2015-03-19 Sangwoo Shim , Patrick Rebentrost , Stéphanie Valleau , Alan Aspuru-Guzik

We study the evolution of the absorption spectrum of a modulation doped GaAs/AlGaAs semiconductor quantum well with decreasing the carrier density. We find that there is a critical density which marks the transition from a Fermi edge…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 G. Yusa , H. Shtrikman , I. Bar-Joseph

A vibronic exciton model is developed to investigate the origin of long lived coherences in light-harvesting complexes. Using experimentally determined parameters and uncorrelated site energy fluctuations, the model predicts oscillations in…

Biological Physics · Physics 2012-06-07 Niklas Christensson , Harald F. Kauffmann , Tonu Pullerits , Tomas Mancal

The time-convolutionless master equation for the electronic populations is derived for a generic electron-phonon Hamiltonian. The equation can be used in the regimes where the golden rule approach is not applicable. The equation is applied…

Materials Science · Physics 2009-11-11 Andrey Pereverzev , Eric R. Bittner

Despite its widespread significance, the temporal coupled-mode theory (CMT) lacks a foundational validation based on electromagnetic principles and stands as a phenomenological theory relying on fitted coupling coefficients. We employ an ab…

Optics · Physics 2024-06-11 Tong Wu , Philippe Lalanne