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We present a coupled continuum formulation for the electrostatic, chemical, thermal and mechanical processes in battery materials. Our treatment applies on the macroscopic scale, at which electrodes can be modelled as porous materials made…

Chemical Physics · Physics 2017-07-25 Zhenlin Wang , Jason B. Siegel , Krishna Garikipati

We study Coulomb drag between an active layer with a clean electron liquid and a passive layer with a pinned electron lattice in the regime of fast intralayer equilibration. Such a two-fluid system offers an experimentally realizable way to…

Strongly Correlated Electrons · Physics 2019-12-17 Tobias Holder

A general physics-based model is developed for heterogeneous electrocatalysis in porous electrodes and used to predict and interpret the impedance of solid oxide fuel cells. This model describes the coupled processes of oxygen gas…

Chemical Physics · Physics 2014-12-05 Y. Fu , S. Poizeau , A. Bertei , C. Qi , A. Mohanram , J. D. Pietras , M. Z. Bazant

Ab initio wavefunction based methods are applied to the study of electron correlation effects on the band structure of oxide systems. We choose MgO as a prototype closed-shell ionic oxide. Our analysis is based on a local Hamiltonian…

Materials Science · Physics 2007-08-13 L. Hozoi , U. Birkenheuer , P. Fulde , A. Mitrushchenkov , H. Stoll

Polycrystalline samples of Z-type hexaferrites, having nominal compositions $\mathrm{Ba_3Co_{2+x}Fe_{24-2x}M_xO_{41}}$ where M = $\mathrm{Ir^{4+}, Hf^{4+}, Mo^{4+}}$ and x=0 and 0.05, were processed via ceramic processing protocols in…

In a fusion reactor internally coated with liquid metal, it will be important to diagnose the thickness of the liquid at various locations in the vessel, as a function of time, and possibly respond to counteract undesired bulging or…

Plasma Physics · Physics 2016-09-21 S. M. H. Mirhoseini , F. A. Volpe

Quantitative description of reaction mechanisms in aqueous phase electrochemistry requires experimental characterization of local water structure at the electrode/aqueous interface and its evolution with changing potential. Gaining such…

Chemical Physics · Physics 2017-11-07 Yujin Tong , François Lapointe , Matin Thämer , Martin Wolf , R. Kramer Campen

Two roads are presently being followed in order to establish the existence of a liquid-gas phase transition in finite nuclear systems from nuclear reactions at high energy. The clean experiment of observing the thermodynamic properties of a…

Nuclear Experiment · Physics 2009-11-10 W. Trautmann

A ring crystal of ions trapped in a linear multipole trap is studied as a basis for an optical frequency standard. The equilibrium conditions and cooling possibilities are discussed through an analytical model and molecular dynamics…

Molecular dynamics simulations at a constant electric potential are an essential tool to study electrochemical processes, providing microscopic information on the structural, thermodynamic, and dynamical properties. Despite the numerous…

Parameters of a high frequency capacitive discharge in argon in axially symmetric chambers of different geometries are studied in experiments and by means of two-dimensional kinetic modeling by the Particle-in-Cell method. It is…

Plasma Physics · Physics 2015-05-19 I. V. Schweigert , D. A. Ariskin , T. V. Chernoiziumskaya , A. S. Smirnov

The enhancement of a cryogenic radio frequency 22 pole trap instrument by the addition of ring electrodes is presented in detail. The ring electrodes tightly surround the poles and only a fraction of the applied electric potential…

Chemical Physics · Physics 2023-06-08 Pavol Jusko , Miguel Jiménez-Redondo , Paola Caselli

Irradiation- and collision-induced fragmentation studies provide information about geometry, electronic properties and interactions between structural units of various molecular systems. Such knowledge brings insights into…

Chemical Physics · Physics 2021-07-28 Pablo de Vera , Alexey Verkhovtsev , Gennady Sushko , Andrey V. Solov'yov

Detailed comparisons between theory and experiment for quantum electrodynamics (QED) effects in He-like ions have been performed in the literature to search for hints of new physics. Different frequentist statistical analyses of the…

One path to realizing systems of trapped atomic ions suitable for large-scale quantum computing and simulation is to create a two-dimensional array of ion traps. Interactions between nearest-neighbouring ions could then be turned on and off…

Photoelectron angular distributions (PADs) obtained from ionization of potassium atoms using moderately intense femtosecond IR fields ($\sim$10$^{12}$Wcm$^{-2}$) of various polarization states are shown to provide a route to "complete"…

Atomic Physics · Physics 2015-01-15 Paul Hockett , Matthias Wollenhaupt , Christian Lux , Thomas Baumert

Diffusiophoretic motion induced by gradients of dissolved species has enabled the manipulation of colloids over large distances, spanning hundreds of microns. Nonetheless, studies have primarily focused on simple geometries that feature 1D…

Soft Condensed Matter · Physics 2024-04-12 Carlos A. Silvera Batista , Kun Wang , Hannah Blake , Vivian Nwosu-Madueke , Sophie Marbach

We have studied the electrical conductance of two-dimensional (2D) random percolating networks of zero-width metallic nanowires (a mixture of rings and sticks). We toke into account the nanowire resistance per unit length and the junction…

Disordered Systems and Neural Networks · Physics 2023-03-08 Yuri Yu. Tarasevich , Andrei V. Eserkepov

Using molecular dynamics simulations, we reveal emergent properties of hydrated electrode interfaces that while molecular in origin are integral to the behavior of the system across long times scales and large length scales. Specifically,…

Materials Science · Physics 2015-05-20 David T. Limmer , Adam P. Willard

Pt/Ti metallisation bilayers are used as bottom electrodes for ferroelectric thin films. During deposition of the ferroelectric films, these electrodes are exposed to elevated temperatures causing modifications of the Pt/Ti bottom…

Materials Science · Physics 2015-02-12 U. Scheithauer , W. Hösler , R. Bruchhaus
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