Related papers: The Virial Correction to the Ideal Gas Law: A Prim…
The virial expansion of ideal quantum gases reveals some interesting and amusing properties when considered as a function of dimensionality $d$. In particular, the convergence radius $\rho_c(d)$ of the expansion is particulary large at {\em…
The purpose of this note is to see to what extent ideal gas laws can be obtained from simple Newtonian mechanics, specifically elastic collisions. We present simple one-dimensional situations that seem to validate the laws. The first…
The adiabatic compression (or expansion) of an ideal gas has been analysed. Using the kinetic theory of gases the usual relation between temperature and volume is obtained, while textbooks follow a thermodynamic approach. In this way we…
We present the full thermodynamics of a fluid confined by an arbitrary external potential based on the virial expansion of the grand potential. The fluid may be classical or quantum and it is assumed that interatomic interactions are…
The equation of state for an ideal gas is simple, which is $P=nk_{\rm B}T$. In the case of imperfect gases where mutual interactions among the constituents are important, pressure $P$ can be expressed as the series expansion of density $n$…
We report a formula for the dry adiabatic lapse rate that depends on the compressibility factor and the adiabatic curves. Then, to take into account the non-ideal behavior of the gases, we consider molecules that can move, rotate, and…
In this paper we find a connection between the macroscopic classical laws of gases and the quantum mechanical description of molecules, composing an ideal gas. In such a gas, the motion of each individual molecule can be considered…
We study the virial expansion of mixtures of countably many different types of particles. The main tool is the Lagrange-Good inversion formula, which has other applications such as counting coloured trees or studying probability generating…
In this work we study the thermodynamic properties of the pion gas starting from the realistic elastic scattering phase-shifts obtained from Chiral Perturbation Theory and using the virial expansion. In particular we study the state…
The ideal gas law of physics and chemistry says that PV = nRT. This law is a statement of the relationship between four variables (P, V, n, and T) that reflect properties of a quantity of gas in a container. The law enables us to make…
Using schematic model potentials, we calculate exactly the virial coefficients of a classical gas up to sixth order and use them to assess the convergence properties of the virial expansion of basic thermodynamic quantities such as…
The equations of state for an ideal generalized gas, like an ideal quantum gas, are expressed in terms of power laws of the temperature. The reduction of an ideal generalized gas to an ideal classical case occurs when the characteristic…
We focus on the study of the processes undergone by a perfect gas when the external pressure is suddenly modified. The analysis shows that, from the second law perspective, there is a non-evident asymmetry between the processes of…
he necessary and sufficient conditions for a unit time-like vector field to be the unit velocity of a classical ideal gas are obtained. In a recent paper [Coll, Ferrando and S\'aez, Phys. Rev D {\bf 99} (2019)] we have offered a purely…
The thermodynamics of an ideal gas enclosed in a box of volume a1 x a2 x a3 at temperature T is considered. The canonical partition function of the system is expressed in terms of complete elliptic integrals of the first kind, whose…
The Euler equations of ideal gas dynamics posess a remarkable nonlinear involutional symmetry which allows one to factor out an arbitrary uniform expansion or contraction of the system. The nature of this symmetry (called by cosmologists…
Virial expansion is a traditional approach in statistical mechanics that expresses thermodynamic quantities, such as pressure $p$, as power series of density or chemical potential. Its radius of convergence can serve as a potential…
The virial theorem is considered for a system of randomly moving particles that are tightly bound to each other by the gravitational and electromagnetic fields, acceleration field and pressure field. The kinetic energy of the particles of…
This article mainly consists in the quantum mechanical study of an adiabatically compressed particle, in an infinitely high well, which we conjecture, can be considered as the basis of an ideal gas. Thus we prove that, all the compression…
We derive a version of the virial theorem that is applicable to diatomic planetary atmospheres that are in approximate thermal equilibrium at moderate temperatures and pressures and are sufficiently thin such that the gravitational…