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The understanding of geochemical interactions between H2 and geofluids is of great importance for underground H2 storage but requires further study. We report the first investigation on the three-phase fluid mixture containing H2, H2O, and…

Chemical Physics · Physics 2023-07-31 Yafan Yang , Jingyu Wan , Jingfa Li , Guangsi Zhao , Xiangyu Shang

A calculation of the rotational S$_0$(0) frequencies in high pressure solid para-hydrogen is performed. Convergence of the perturbative series at high density is demonstrated by the calculation of second and third order terms. The results…

Statistical Mechanics · Physics 2009-11-10 Francesco Grazzi , Massimo Moraldi , Lorenzo Ulivi

The D2O ice VI to ice XV hydrogen ordering phase transition at ambient pressure is investigated in detail with neutron diffraction. The lattice constants are found to be sensitive indicators for hydrogen ordering. The a and b lattice…

Ternary or more complex hydrogen-rich hydrides are the main hope of reaching room-temperature superconductivity at high pressures. Their chemical space is vast and its exploration is challenging. Here we report the investigation of the…

Superconductivity · Physics 2023-12-13 Grigoriy Shutov , Dmitrii Semenok , Ivan A. Kruglov , Artem R. Oganov

We show that collision-induced absorption allows molecular hydrogen to act as an incondensible greenhouse gas, and that bars or tens of bars of primordial H2-He mixtures can maintain surface temperatures above the freezing point of water…

Earth and Planetary Astrophysics · Physics 2015-05-28 Raymond Pierrehumbert , Eric Gaidos

The current Venus climate is largely regulated by globally-covered concentrated sulfuric acid clouds from binary condensation of sulfuric acid (H2SO4) and water (H2O). To understand this complicated H2SO4-H2O gas-cloud system, previous…

Earth and Planetary Astrophysics · Physics 2022-07-22 Longkang Dai , Xi Zhang , Wencheng D. Shao , Carver J. Bierson , Jun Cui

There is evidence to suggest that clathrate hydrates have a significant effect on the surface geology of icy bodies in the Solar System. However the aqueous environments believed to be present on these bodies are likely to be saline rather…

Earth and Planetary Astrophysics · Physics 2017-04-12 E. Safi , Stephen P. Thompson , Aneurin Evans , Sarah J. Day , C. A. Murray , J. E. Parker , A. R. Baker , J. M. Oliveira , J. Th. van Loon

It is generally assumed that solid hydrogen will transform into a metallic alkali-like crystal at sufficiently high pressure. However, some theoretical models have also suggested that compressed hydrogen may form an unusual two-component…

Materials Science · Physics 2009-11-10 Stanimir A. Bonev , Eric Schwegler , Tadashi Ogitsu , Giulia Galli

For the gradual introduction of hydrogen in the energy market, the study of the properties of mixtures of hydrogen with typical components of natural gas (NG) and liquefied petroleum gas (LPG) is of great importance. This work aims to…

Recent x-ray Compton scattering experiments in ice have provided useful information about the quantum nature of the interaction between H$_2$O monomers. The hydrogen bond is characterized by a certain amount of charge transfer which could…

Materials Science · Physics 2007-10-11 B. Barbiellini , A. Shukla

Hydrocarbons are observed in the gas or solid phases of solar system objects, including comets, Trans-Neptunian Objects, planets and their moons. In the presence of water ice in these environments, hydrocarbons-bearing clathrate hydrates…

Earth and Planetary Astrophysics · Physics 2021-04-28 Emmanuel Dartois

The transition of a warm dense fluid hydrogen from insulator to a conducting state at pressures of the order of 20-300 GPa and temperatures of 1000-5000 K has been the subject of active scientific research over the past few decades. The use…

Other Condensed Matter · Physics 2022-04-14 Ilya Fedorov , Vladimir Stegailov

The properties of hydrogen at high pressure have wide implications in astrophysics and high-pressure physics. Its phase change in the liquid is variously described as a metallization, H2-dissociation, density discontinuity or plasma phase…

Materials Science · Physics 2020-03-17 Hua Y. Geng , Q. Wu , Miriam Marqués , Graeme J. Ackland

Surfaces (interfaces) dictate many physical and chemical properties of solid materials and adsorbates considerably affect these properties. Nitrogen molecules, which are the most abundant constituent in ambient air, are considered to be…

Recent cutting-edge experiments have provided {\it in situ} structure characterization and measurements of the pressure ($P$), density ($\bar{\rho}$) and temperature ($T$) of shock compressed silicon in the 100 GPa range of pressures and…

Materials Science · Physics 2024-12-12 M. W. C. Dharma-wardana , Dennis D. Klug , Hannah Poole , G. Gregori

The ever-expanding catalog of detected super-Earths calls for theoretical studies of their properties in the case of a substantial water layer. This work considers such water planets with a range of masses and water mass fractions (2 to 5…

Earth and Planetary Astrophysics · Physics 2015-05-18 Roger Fu , Richard J. OConnell , Dimitar D. Sasselov

In a combination of neutron and synchrotron diffraction the lattice constants and expansivities of hydrogenated and deuterated CH4-, CO2-, Xe- (structure type I) and N2-hydrate (structure type II) from 10 K up to the stability limit under…

Materials Science · Physics 2016-02-17 Thomas C. Hansen , Andrzej Falenty , M. Mangir Murshed , Werner F. Kuhs

Fluid polyamorphism, the existence of multiple amorphous fluid states in a single-component system, has been observed or predicted in a variety of substances. A remarkable example of this phenomenon is the fluid-fluid phase transition in…

Soft Condensed Matter · Physics 2022-09-21 Nathaniel R. Fried , Thomas J. Longo , Mikhail A. Anisimov

The uniquely characteristic macrostructures of binary hydrogen-clathrate compounds $M$H$_\textrm{n}$ formed at high pressure, a cage of hydrogens surrounding a central-atom host, is theoretically predicted in various studies to include…

Superconductivity · Physics 2020-06-22 Dale R. Harshman , Anthony T. Fiory

In this work, we examine metal electrode-ionomer electrolyte systems at high voltage / negative surface charge and at high pH to assess factors that influence hydrogen production efficiency. We simulate the hydrogen evolution electrode…

Chemical Physics · Physics 2019-09-04 Reese E. Jones , William C. Tucker , Matthew J. L. Mills , Sanjeev Mukerjee