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Samarium hydrides, belonging to the broad class of lanthanide polyhydrides, have yet to be experimentally tested at high pressure. In this study, we use random structure searches to explore multiple possible stoichiometries and propose…

Strongly Correlated Electrons · Physics 2023-08-23 Zelong Zhao , Siyu Chen , Bartomeu Monserrat , Evgeny Plekhanov , Cedric Weber

Hydrogen in metals is a significant research area with far-reaching implications, encompassing diverse fields such as hydrogen storage, metal-insulator transitions, and the recently emerging phenomenon of room-temperature ($\textit{$T_C$}$)…

Superconductivity · Physics 2023-11-30 Heejung Kim , Ina Park , J. H. Shim , D. Y. Kim

H2O is an important constituent in planetary bodies, controlling habitability and, in geologically-active bodies, plate tectonics. At pressures within the interior of many planets, the H-bonds in H2O collapse into stronger, ionic bonds.…

Motivated by advances in hydrogen-rich superconductors in the past decades, we conducted variable-composition structural searches in Mo-H binary system at high pressure. A new composition-pressure phase diagram of thermodynamically stable…

Superconductivity · Physics 2024-01-31 Aiqin Yang , Xiangru Tao , Yundi Quan , Peng Zhang

Old and novel layered structures are attracting increasing attention for their physical, electronic, and frictional properties. SiS$_2$, isoelectronic to SiO$_2$, CO$_2$ and CS$_2$, is a material whose phases known experimentally up to 6…

Chemical Physics · Physics 2016-09-13 Dušan Plašienka , Roman Martoňák , Erio Tosatti

An open question is whether the liquid and glassy phases of water are thermodynamically distinct or continuous. Here we address this question using molecular dynamics simulations in comparison with neutron scattering experiments to study…

Condensed Matter · Physics 2007-05-23 Francis W. Starr , Marie-Claire Bellissent-Funel , H. Eugene Stanley

Methane clathrate hydrates, particularly those with an sI structure, are significant due to their potential as energy resources and their impact on gas pipelines. In this study, a two-dimensional (2D) lattice-gas model is employed to…

Disordered Systems and Neural Networks · Physics 2025-02-10 Julian Juan , Maria E. Pronsato , Antonio J. Ramirez-Pastor , Pablo Longone

Water exhibits rich polymorphism, where more than 20 crystalline phases have been experimentally reported. Five of them are metastable and form at low temperatures by either heating amorphous ice or degassing clathrate hydrates. However,…

The high-pressure phases of solid hydrogen are of fundamental interest and relevant to the interior of giant planets; however, knowledge of these phases is far from complete. Particle swarm optimization (PSO) techniques were applied to a…

Materials Science · Physics 2012-05-09 Hanyu Liu , Hui Wang , Yanming Ma

Reaching superconductivity at ambient conditions is one of the biggest scientific dreams. The discoveries in the last few years at high pressures place hydrogen-based compounds as the best candidates for making it true. As the recent…

Superconductivity · Physics 2022-04-20 Ion Errea

A hexagonal structure of solid molecular hydrogen with $P6_122$ symmetry is calculated to be more stable below about 200 GPa than the monoclinic $C2/c$ structure identified previously as the best candidate for phase III. We find that the…

Materials Science · Physics 2016-11-01 Bartomeu Monserrat , Richard J. Needs , Eugene Gregoryanz , Chris J. Pickard

Dissociation of gas hydrates below 240 K leads to the formation of a metastable form of water ice, so called cubic ice (Ic). Through its defective nature and small particle size the surface film composed of such material is incapable of…

Materials Science · Physics 2015-10-28 Andrzej Falenty , Thomas C. Hansen , Werner F. Kuhs

We present extensive molecular dynamics (MD) simulations investigating numerous candidate crystal structures for hydrogen in conditions around the present experimental frontier (400GPa). Spontaneous phase transitions in the simulations…

Materials Science · Physics 2015-11-18 Ioan B. Magdau , Graeme J. Ackland

A key challenge in materials discovery is to find high-temperature superconductors. Hydrogen and hydride materials have long been considered promising materials displaying conventional phonon-mediated superconductivity. However, the high…

Synchrotron X-ray diffraction and Raman spectroscopy have been used to study chemical reactions of molecular hydrogen (H2) with sulfur (S) at high pressures. We find theoretically predicted Cccm and Im-3m H3S to be the reaction products at…

Superconductivity · Physics 2017-04-19 Alexander F. Goncharov , Sergey S. Lobanov , Vitali B. Prakapenka , Eran Greenberg

We have studied solid hydrogen up to pressures of 300 GPa and temperatures of 350 K using density functional theory methods and have found "mixed structures" that are more stable than those predicted earlier. Mixed structures consist of…

Materials Science · Physics 2012-06-20 Chris J. Pickard , Miguel Martinez-Canales , Richard J. Needs

We present results predicting experimentally measurable structural quantities from molecular dynamics studies of hydrogen. In doing this, we propose a paradigm shift for experimentalists -- that the predictions from such calculations should…

Materials Science · Physics 2020-03-25 Graeme J. Ackland , John S. Loveday

The measurement of superconductivity at above 200K in compressed samples of hydrogen sulfide and lanthanum hydride at 250K is reinvigorating the search for conventional high temperature superconductors. At the same time it exposes a…

Superconductivity · Physics 2019-10-02 Chris J. Pickard , Ion Errea , Mikhail I. Eremets

The recent discovery of H3S and LaH10 superconductors with record high superconducting transition temperatures, Tc, at high pressure, has fueled the search for room-temperature superconductivity in the compressed superhydrides. Here we…

Knowing the phase transformations in dense water ice is key to unraveling the peculiar geophysical properties of Uranus and Neptune, whose stratified interior models predict a thick ice layer beneath a convective ionic fluid layer. In the…