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Quantum control strategies that provide shortcuts to adiabaticity are increasingly considered in various contexts including atomic cooling. Recent studies have emphasized practical issues in order to reduce the gap between the idealized…

Quantum Gases · Physics 2012-11-02 S. Choi , R. Onofrio , B. Sundaram

Mixed quantum-classical mechanics descriptions are critical to modeling coupled electron-nuclear dynamics, i.e. non-adiabatic molecular dynamics, relevant to photochemical and photophysical processes. We argue that, for polyatomic…

Chemical Physics · Physics 2018-08-21 Roman Baskov , Alexander White , Dmitry Mozyrsky

One key challenge in the study of nonadiabatic dynamics in open quantum systems is to balance computational efficiency and accuracy. Although Ehrenfest dynamics (ED) is computationally efficient and well-suited for large complex systems, ED…

Quantum Physics · Physics 2024-12-02 Jingqi Chen , Joonho Lee , Wenjie Dou

We consider an Ehrenfest approximation for a particle in a double-well potential in the presence of an external environment schematized as a finite resource heat bath. This allows us to explore how the limitations in the applicability of…

Quantum Physics · Physics 2015-10-09 Stephen Choi , Roberto Onofrio , Bala Sundaram

Due to a continuum of electronic states present in periodic systems, the description of molecular dynamics on surfaces poses a serious computational challenge. One of the most used families of approaches in these settings are friction…

Chemical Physics · Physics 2021-12-08 Ignacio Loaiza , Artur F. Izmaylov

Mixed quantum-classical methods, such as surface hopping and Ehrenfest dynamics, have proven useful for describing molecular processes involving multiple electronic states. These methods require propagating many independent trajectories,…

Chemical Physics · Physics 2025-08-15 Alan Scheidegger , Jiří J. L. Vaníček

An economic modeling approach for cavity quantum electrodynamics is provided by mean-field dynamics, wherein the optical field is described classically while a self-consistent interaction with quantum emitters is incorporated through the…

Chemical Physics · Physics 2025-12-10 Ming-Hsiu Hsieh , Alex Krotz , Roel Tempelaar

Treated traditionally by the Ehrenfest approximation, dynamics of a one-dimensional molecular crystal model with off-diagonal exciton-phonon coupling is investigated in this work using the Dirac-Frenkel time-dependent variational principle…

Chemical Physics · Physics 2017-04-25 Zhongkai Huang , Lu Wang , Changqin Wu , Lipeng Chen , Frank Grossmann , Yang Zhao

Ehrenfest Dynamics combined with real-time time-dependent density functional theory has proven to be a reliable tool to study non-adiabatic molecular dynamics with a reasonable computational cost. Among other possibilities, it allows for…

Materials Science · Physics 2023-01-05 Ronaldo Rodrigues Pela , Claudia Draxl

In order to find out whether there exists a thermodynamic description of the glass phase, the Ehrenfest relations along the glass transition line are reconsidered. It is explained that the one involving the compressibility is always…

Statistical Mechanics · Physics 2009-10-30 Th. M. Nieuwenhuizen

A method is proposed to drive an ultrafast non-adiabatic dynamics of an ultracold gas trapped in a box potential. The resulting state is free from spurious excitations associated with the breakdown of adiabaticity, and preserves the quantum…

Quantum Gases · Physics 2014-12-02 A. del Campo , M. G. Boshier

Relativistic kinematics is usually considered only as a manifestation of pseudo-Euclidean (Lorentzian) geometry of space-time. However, as it is explicitly stated in General Relativity, the geometry itself depends on dynamics, specifically,…

Classical Physics · Physics 2020-04-17 Moses Fayngold

The dynamics of an electronic system interacting with an electromagnetic field is investigated within mixed quantum-classical theory. Beyond the classical path approximation (where we ignore all feedback from the electronic system on the…

Chemical Physics · Physics 2019-02-11 Hsing-Ta Chen , Tao E. Li , Maxim Sukharev , Abraham Nitzan , Joseph E. Subotnik

Shortcuts to adiabatic expansion of the effectively one-dimensional Bose-Einstein condensate (BEC) loaded in the harmonic-oscillator (HO) trap is investigated by combining techniques of the variational approximation and inverse engineering.…

Quantum Physics · Physics 2020-05-26 Tang-You Huang , Boris A. Malomed , Xi Chen

We show that standard Ehrenfest dynamics does not conserve linear and angular momentum when using a basis of truncated adiabatic states. However, we also show that previously proposed effective Ehrenfest equations of…

Chemical Physics · Physics 2023-12-15 Zhen Tao , Xuezhi Bian , Yanze Wu , Jonathan Rawlinson , Robert G. Littlejohn , Joseph E. Subotnik

In this thesis, it is presented a set of results in adiabatic dynamics (closed and open system) and transitionless quantum driving that promote some advances in our understanding on quantum control and Hamiltonian inverse engineering. In…

Quantum Physics · Physics 2021-07-27 Alan C. Santos

We investigate an undamped random phase-space dynamics in deterministic external force fields (conservative and magnetic ones). By employing the hydrodynamical formalism for those stochastic processes we analyze microscopic kinetic-type…

Statistical Mechanics · Physics 2009-11-07 R. Czopnik , P. Garbaczewski

A model for the slow dynamics of the supercooled liquid is formulated in terms of the standard equations of fluctuating nonlinear hydrodynamics (FNH) with the inclusion of an extra diffusive mode for the collective density fluctuations. If…

Statistical Mechanics · Physics 2016-03-23 Neeta Bidhoodi , Shankar P. Das

The approach of shortcuts to adiabaticity enables the effective execution of adiabatic dynamics in quantum information processing with enhanced speed. Owing to the inherent trade-off between dynamical speed and the cost associated with the…

Ehrenfest dynamics is a useful approximation for ab initio mixed quantum-classical molecular dynamics that can treat electronically nonadiabatic effects. Although a severe approximation to the exact solution of the molecular time-dependent…

Chemical Physics · Physics 2021-09-24 Seonghoon Choi , Jiří Vaníček
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