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Quantum embedding methods enable the study of large, strongly correlated quantum systems by (usually self-consistent) decomposition into computationally manageable subproblems, in the spirit of divide-and-conquer methods. Among these,…

Strongly Correlated Electrons · Physics 2025-03-14 Alicia Negre , Fabian Faulstich , Raehyun Kim , Thomas Ayral , Lin Lin , Eric Cancès

This thesis describes the development of the density matrix embedding theory (DMET) and its applications to lattice strongly correlated electron problems, including a review of DMET theory and algorithms (Ch 2), investigation of finite size…

Strongly Correlated Electrons · Physics 2018-03-29 Bo-Xiao Zheng

Density matrix embedding theory (DMET) provides a theoretical framework to treat finite fragments in the presence of a surrounding molecular or bulk environment, even when there is significant correlation or entanglement between the two. In…

Chemical Physics · Physics 2016-11-29 Sebastian Wouters , Carlos A. Jiménez-Hoyos , Qiming Sun , Garnet Kin-Lic Chan

Density matrix embedding theory (DMET) describes finite fragments in the presence of a surrounding environment. In contrast to most embedding methods, DMET explicitly allows for quantum entanglement between both. In this chapter, we discuss…

Strongly Correlated Electrons · Physics 2018-02-19 Sebastian Wouters , Carlos A. Jiménez-Hoyos , Garnet K. -L. Chan

Density matrix embedding theory (DMET) is a powerful quantum embedding method for solving strongly correlated quantum systems. Theoretically, the performance of a quantum embedding method should be limited by the computational cost of the…

Computational Physics · Physics 2020-08-19 Xiaojie Wu , Michael Lindsey , Tiangang Zhou , Yu Tong , Lin Lin

We introduce DMET, a new quantum embedding theory for predicting ground-state properties of infinite systems. Like dynamical mean-field theory (DMFT), DMET maps the the bulk interacting system to a simpler impurity model and is exact in the…

Strongly Correlated Electrons · Physics 2015-03-20 Gerald Knizia , Garnet Kin-Lic Chan

This article provides the first mathematical analysis of the Density Matrix Embedding Theory (DMET) method. We prove that, under certain assumptions, (i) the exact ground-state density matrix is a fixed-point of the DMET map for…

Mathematical Physics · Physics 2023-10-03 Eric Cancès , Fabian M. Faulstich , Alfred Kirsch , Eloïse Letournel , Antoine Levitt

The idea of using fragment embedding to circumvent the high computational scaling of accurate electronic structure methods while retaining high accuracy has been a long-standing goal for quantum chemists. Traditional fragment embedding…

Chemical Physics · Physics 2022-10-11 Hong-Zhou Ye , Matthew Welborn , Nathan D. Ricke , Troy Van Voorhis

We examine the performance of the density matrix embedding theory (DMET) recently proposed in [G. Knizia and G. K.-L. Chan, Phys. Rev. Lett. 109, 186404 (2012)]. The core of this method is to find a proper one-body potential that generates…

Strongly Correlated Electrons · Physics 2020-12-07 Masataka Kawano , Chisa Hotta

Density matrix embedding theory (DMET) [Phys. Rev. Lett.2012, 109, 186404] has been demonstrated as an efficient wave-function-based embedding method to treat extended systems. Despite its success in many quantum lattice models, the…

Chemical Physics · Physics 2018-03-01 Hung Q. Pham , Varinia Bernales , Laura Gagliardi

Density matrix embedding theory (DMET) is a fully quantum-mechanical embedding method which shows great promise as a method of defeating the inherent exponential cost scaling of multiconfigurational wave function-based calculations by…

Chemical Physics · Physics 2019-02-07 Matthew R. Hermes , Laura Gagliardi

We describe an efficient quantum embedding framework for realistic ab initio density matrix embedding (DMET) calculations in solids. We discuss in detail the choice of orbitals and mapping to a lattice, treatment of the virtual space and…

Strongly Correlated Electrons · Physics 2020-01-15 Zhi-Hao Cui , Tianyu Zhu , Garnet Kin-Lic Chan

Density matrix embedding theory (DMET) is a quantum embedding theory for strongly correlated systems. From a computational perspective, one bottleneck in DMET is the optimization of the correlation potential to achieve self-consistency,…

Chemical Physics · Physics 2019-09-04 Xiaojie Wu , Zhi-Hao Cui , Yu Tong , Michael Lindsey , Garnet Kin-Lic Chan , Lin Lin

Quantum embedding approaches involve the self-consistent optimization of a local fragment of a strongly correlated system, entangled with the wider environment. The `energy-weighted' density matrix embedding theory (EwDMET) was established…

Strongly Correlated Electrons · Physics 2021-02-23 P. V. Sriluckshmy , Max Nusspickel , Edoardo Fertitta , George H. Booth

Density matrix embedding theory (DMET) formally requires the matching of density matrix blocks obtained from high-level and low-level theories, but this is sometimes not achievable in practical calculations. In such a case, the global band…

Computational Physics · Physics 2022-01-14 Fabian M. Faulstich , Raehyun Kim , Zhi-Hao Cui , Zaiwen Wen , Garnet Kin-Lic Chan , Lin Lin

Entanglement related properties work as nice fingerprint of the quantum many-body wave function. However, those of fermionic models are hard to evaluate in standard numerical methods because they suffer from finite size effects. We show…

Strongly Correlated Electrons · Physics 2020-11-04 Xavier Plat , Chisa Hotta

The equivalence in one-electron quantum bath between the practical implementation of density matrix embedding theory (DMET) and the more recent Householder-transformed density matrix functional embedding theory has been shown previously in…

Chemical Physics · Physics 2023-07-24 Sajanthan Sekaran , Oussama Bindech , Emmanuel Fromager

Density matrix embedding theory (DMET) provides a framework to describe ground-state expectation values in strongly correlated systems, but its extension to dynamical quantities is still an open problem. We show one route to obtaining…

Strongly Correlated Electrons · Physics 2025-11-13 Shuoxue Li , Chenghan Li , Huanchen Zhai , Garnet Kin-Lic Chan

Density matrix embedding theory (DMET) [Phys. Rev. Lett., 109, 186404 (2012)], introduced a new approach to quantum cluster embedding methods, whereby the mapping of strongly correlated bulk problems to an impurity with finite set of bath…

Strongly Correlated Electrons · Physics 2015-06-24 George H. Booth , Garnet Kin-Lic Chan

Quantum embedding based on the (one-electron reduced) density matrix is revisited by means of the unitary Householder transformation. While being exact and equivalent to (but formally simpler than) density matrix embedding theory (DMET) in…

Strongly Correlated Electrons · Physics 2021-07-12 Sajanthan Sekaran , Masahisa Tsuchiizu , Matthieu Saubanère , Emmanuel Fromager
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