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We study the relationship between local structural ordering and dynamical heterogeneities in a model glass-forming liquid, the Wahnstrom mixture. A novel cluster-based approach is used to detect local energy minimum polyhedral clusters and…

Soft Condensed Matter · Physics 2013-02-26 Alex Malins , Jens Eggers , C. Patrick Royall , Stephen R. Williams , Hajime Tanaka

The effects of randomly pinning particles in a model glass-forming fluid are studied, with a focus on the dynamically heterogeneous relaxation in the presence of pinning. We show how four-point dynamical correlations can be analysed in real…

Statistical Mechanics · Physics 2013-10-30 Robert L. Jack , Christopher J. Fullerton

We study the role of elasticity-induced facilitation on the dynamics of glass-forming liquids by a coarse-grained two-dimensional model in which local relaxation events, taking place by thermal activation, can trigger new relaxations by…

Disordered Systems and Neural Networks · Physics 2023-04-05 Misaki Ozawa , Giulio Biroli

The origins of rapid dynamical slow down in glass forming liquids in the growth of static length scales, possibly associated with identifiable structural ordering, is a much debated issue. Growth of medium range crystalline order (MRCO) has…

Soft Condensed Matter · Physics 2018-08-29 Indrajit Tah , Shiladitya Sengupta , Srikanth Sastry , Chandan Dasgupta , Smarajit Karmakar

We compare dynamical heterogeneities in equilibrated supercooled liquids and in the nonequilibrium glassy state within the framework of the random first order transition theory. Fluctuating mobility generation and transport in the glass are…

Statistical Mechanics · Physics 2014-01-21 Apiwat Wisitsorasak , Peter G. Wolynes

Using molecular dynamics simulations, we study the slow dynamics of supercooled liquids confined in a random matrix of immobile obstacles. We study the dynamical crossover from glass-like to Lorentz-gas-like behavior in terms of the density…

Soft Condensed Matter · Physics 2011-05-30 Kang Kim , Kunimasa Miyazaki , Shinji Saito

Glass-like materials are nonequilibrium systems where the relaxation time may exceed reasonable time scales of observations. In the present paper a dynamic percolation model is introduced in order to explain the principal properties of…

Condensed Matter · Physics 2007-05-23 A. Vazquez , O. Sotolongo-Costa

A link between structural ordering and slow dynamics has recently attracted much attention from the context of the origin of glassy slow dynamics. Candidates for such structural order are icosahedral, exotic amorphous, and crystal-like.…

Soft Condensed Matter · Physics 2013-01-31 Mathieu Leocmach , Hajime Tanaka

When a liquid is cooled below its melting temperature, if crystallization is avoided, it forms a glass. This phenomenon, called glass transition, is characterized by a marked increase of viscosity, about 14 orders of magnitude, in a narrow…

Disordered Systems and Neural Networks · Physics 2008-08-23 Simone Capaccioli , Giancarlo Ruocco , Francesco Zamponi

We define a correlation function that quantifies the spatial correlation of single-particle displacements in liquids and amorphous materials. We show for an equilibrium liquid that this function is related to fluctuations in a bulk…

Soft Condensed Matter · Physics 2009-10-31 Claudio Donati , Sharon C. Glotzer , Peter H. Poole

The relationship between spatially heterogeneous dynamics (SHD) and jamming is studied in a glass-forming binary Lennard-Jones system via molecular dynamics simulations. It has been suggested that the probability distribution of…

Disordered Systems and Neural Networks · Physics 2007-05-23 Naida Lacevic , Sharon C. Glotzer

The dramatic slowdown of glass-forming liquids has been variously linked to increasing dynamic and static correlation lengths. Yet, empirical evidence is insufficient to decide among competing theories. The random first order theory (RFOT)…

Disordered Systems and Neural Networks · Physics 2010-02-25 C. Cammarota , A. Cavagna , G. Gradenigo , T. S. Grigera , P. Verrocchio

Disordered systems like liquids, gels, glasses, or granular materials are not only ubiquitous in daily life and in industrial applications but they are also crucial for the mechanical stability of cells or the transport of chemical and…

Disordered Systems and Neural Networks · Physics 2019-04-30 Zhen Zhang , Walter Kob

Dynamic heterogeneity is expected to be a key concept for understanding the origin of slow dynamics near the glass transition. In previous studies, quantitative evaluations of dynamic heterogeneity have been attempted using two different…

Disordered Systems and Neural Networks · Physics 2022-04-11 Kohsei Kanayama , Taiki Hoshino , Ryoichi Yamamoto

We investigate dynamical heterogeneities in the collective relaxation of a concentrated microgel system, for which the packing fraction can be conveniently varied by changing the temperature. The packing fraction dependent mechanical…

Soft Condensed Matter · Physics 2011-05-31 David A. Sessoms , Irmgard Bischofberger , Luca Cipelletti , Véronique Trappe

Glass-forming liquids exhibit a dramatic dynamical slowdown as the temperature is lowered. This can be attributed to relaxation proceeding via large structural rearrangements whose characteristic size increases as the system cools. These…

Statistical Mechanics · Physics 2015-03-31 Allan Adams , Tarek Anous , Jaehoon Lee , Sho Yaida

An aqueous suspension of the synthetic clay Laponite undergoes a transition from a liquid-like ergodic state to a glass-like nonergodic arrested state. In an observation that closely resembles the dynamical slowdown observed in supercooled…

Soft Condensed Matter · Physics 2016-10-18 Paramesh Gadige , Debasish Saha , Sanjay Kumar Behera , Ranjini Bandyopadhyay

We study the dynamics of water confined between hydrophobic flat surfaces at low temperature. At different pressures, we observe different behaviors that we understand in terms of the hydrogen bonds dynamics. At high pressure, the formation…

Soft Condensed Matter · Physics 2015-05-13 Giancarlo Franzese , Francisco de los Santos

The existence of a static lengthscale that grows in accordance with the dramatic slowing down observed at the glass transition is a subject of intense interest. A recent publication compared two proposals for this length scale, one based on…

Statistical Mechanics · Physics 2017-06-27 Ricardo Gutiérrez , Smarajit Karmakar , Yoav G. Pollack , Itamar Procaccia

We prove the emergence of spatially correlated dynamics in slowly compacting dense granular media by analyzing analytically and numerically multi-point correlation functions in a simple particle model characterized by slow non-equilibrium…

Statistical Mechanics · Physics 2009-11-10 Alexandre Lefèvre , Ludovic Berthier , Robin Stinchcombe
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