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We investigate the characteristic length scales associated with the glass transition phenomenon. By studying an atomic glass-forming liquid in negatively curved space, for which the local order is well identified and the amount of…

Statistical Mechanics · Physics 2010-02-10 François Sausset , Gilles Tarjus

Despite the use of glasses for thousands of years, the nature of the glass transition is still mysterious. On approaching the glass transition, the growth of dynamic heterogeneity has long been thought to play a key role in explaining the…

Soft Condensed Matter · Physics 2018-03-23 Lijin Wang , Ning Xu , W. H. Wang , Pengfei Guan

We show that in the equilibrium phase of glass-forming hard-sphere fluids in three dimensions, the static length scales tentatively associated with the dynamical slowdown and the dynamical length characterizing spatial heterogeneities in…

Disordered Systems and Neural Networks · Physics 2013-04-16 Patrick Charbonneau , Gilles Tarjus

The growing sluggishness of glass-forming liquids is thought to be accompanied by growing structural order. The nature of such order, however, remains hotly debated. A decade ago, point-to-set (PTS) correlation lengths were proposed as…

Statistical Mechanics · Physics 2016-09-26 Sho Yaida , Ludovic Berthier , Patrick Charbonneau , Gilles Tarjus

We analyze static point-to-set correlations in glass-forming liquids. The generic idea is to freeze the position of a set of particles in an equilibrium configuration and to perform sampling in the presence of this additional constraint.…

Statistical Mechanics · Physics 2012-01-05 Ludovic Berthier , Walter Kob

We numerically study dynamics and correlation length scales of a colloidal liquid in both quiescent and sheared conditions to further understand the origin of slow dynamics and dynamic heterogeneity in glass-forming systems. The simulation…

Soft Condensed Matter · Physics 2015-06-05 Wen-Sheng Xu , Zhao-Yan Sun , Li-Jia An

We discuss a novel approach, the point-to-set correlation functions, that allows to determine relevant static and dynamic length scales in glass-forming liquids. We find that static length scales increase monotonically when the temperature…

Disordered Systems and Neural Networks · Physics 2013-07-04 Walter Kob , Sandalo Roldan-Vargas , Ludovic Berthier

A few years ago it was showed that some systems that have very similar local structure, as quantified by the pair correlation function, exhibit vastly different slowing down upon supercooling [L. Berthier and G. Tarjus, Phys. Rev. Lett.…

Soft Condensed Matter · Physics 2015-06-17 Elijah Flenner , Hannah Staley , Grzegorz Szamel

There is growing evidence that slow dynamics and dynamic heterogeneity possess structural signatures in glass-forming liquids. However, even in the weakly frustrated glass-forming liquids, whether or not the dynamic heterogeneity has a…

Soft Condensed Matter · Physics 2015-06-11 Wen-Sheng Xu , Zhao-Yan Sun , Li-Jia An

One of the central problems of the liquid-glass transition is whether there is a structural signature that can qualitatively distinguish different dynamic behaviors at different degrees of supercooling. Here, we propose a novel structural…

Soft Condensed Matter · Physics 2015-09-24 Yan-Wei Li , You-Liang Zhu , Zhao-Yan Sun

The most puzzling aspect of the glass transition observed in laboratory is an apparent decoupling of dynamics from structure. In this paper we recount the implication of various theories of glass transition for the static correlation length…

Disordered Systems and Neural Networks · Physics 2017-02-08 S. Davatolhagh

The dramatic dynamic slowing down associated with the glass transition is considered by many to be related to the existence of a static length scale that grows when temperature decreases. Defining, identifying and measuring such a length is…

Statistical Mechanics · Physics 2014-05-29 Giulio Biroli , Smarajit Karmakar , Itamar Procaccia

The existence of heterogeneity in the dynamics of supercooled liquids is believed to be one of the hallmarks of the glass transition. Intense research has been carried out in the past to understand the origin of this heterogeneity in…

Soft Condensed Matter · Physics 2020-07-01 Indrajit Tah , Smarajit Karmakar

Understanding glass formation is a challenge because the existence of a true glass state, distinct from liquid and solid, remains elusive: Glasses are liquids that have become too viscous to flow. An old idea, as yet unproven…

Supercooled liquids exhibit spatial heterogeneity in the dynamics of their fluctuating atomic arrangements. The length and time scales of the heterogeneous dynamics are central to the glass transition and influence nucleation and growth of…

Materials Science · Physics 2018-05-09 Pei Zhang , Jason J. Maldonis , Ze Liu , Jan Schroers , Paul M. Voyles

We report an extensive and systematic investigation of the multi-point and multi-time correlation functions to reveal the spatio-temporal structures of dynamic heterogeneities in glass-forming liquids. Molecular dynamics simulations are…

Soft Condensed Matter · Physics 2013-01-04 Kang Kim , Shinji Saito

Using extensive molecular dynamics simulations, we have performed finite-size scaling (FSS) in the aging regime of a model glass-forming liquid to investigate how the length scales associated with amorphous order (static length) and dynamic…

Soft Condensed Matter · Physics 2025-12-22 Santu Nath , Smarajit Karmakar

The term "fragility" describes the rate at which viscosity grows when a supercooled liquid approaches its putative glass transition temperature. The field of glassy materials is actively searching for a structural origin that governs this…

Soft Condensed Matter · Physics 2021-08-06 Indrajit Tah , Smarajit Karmakar

The origin of the dramatic changes in the behavior of liquids as they approach their vitreous state - increases of many orders of magnitude in transport properties and dynamic time scales - is a major unsolved problem in condensed matter.…

Soft Condensed Matter · Physics 2015-06-23 R. Casalini , D. Fragiadakis , C. M. Roland

It has been demonstrated recently that supercooled liquids sharing simple structural features (e.g. pair distribution functions) may exhibit strikingly distinct dynamical behavior. Here we show that a more subtle structural feature…

Statistical Mechanics · Physics 2012-06-04 Glen M. Hocky , Thomas E. Markland , David R. Reichman
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