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We calculate the uniaxial and dilatation acoustic deformation potentials, $\Xi^{\text{L}}_{u}$ and $\Xi^{\text{L}}_{d}$, of the conduction band L valleys of PbTe from first principles, using the local density approximation (LDA) and hybrid…

Materials Science · Physics 2018-11-19 Aoife R. Murphy , Felipe Murphy-Armando , Stephen Fahy , Ivana Savic

Due to the strongly nonlocal nature of $f_{xc}({\bf r},{\bf r}',\omega)$ the {\em scalar} exchange and correlation (xc) kernel of the time-dependent density-functional theory (TDDFT), the formula for Q the friction coefficient of an…

Materials Science · Physics 2009-11-13 V. U. Nazarov , J. M. Pitarke , Y. Takada , G. Vignale , Y. -C. Chang

First-principles phonon calculations along with Kohn-Sham density functional theory (DFT) is an essential tool to study the lattice dynamics, thermodynamical properties and phase-transitions of materials. The two full-Heusler compounds…

Strongly Correlated Electrons · Physics 2018-06-18 Shivprasad S. Shastri , Sudhir K. Pandey

Due to their current and future technological applications, including realisation of water filters and desalination membranes, water adsorption on graphitic sp$^{2}$-bonded carbon is of overwhelming interest. However, these systems are…

Materials Science · Physics 2025-01-14 Jan Gerit Brandenburg , Andrea Zen , Dario Alfè , Angelos Michaelides

The magnetic ground state of FeRh is highly sensitive towards the lattice constant. This, in addition to partially filled d-shells of Fe and Rh, posed a significant challenge for Density Functional Theory (DFT) calculations in the past.…

Materials Science · Physics 2024-01-24 Shishir Kumar Pandey , Saikat Debnath , Zhanghao Zhouyina , Qiangqiang Gu

We combine density functional theory (DFT) within the local density approximation (LDA), the quasiharmonic approximation (QHA), and a model of vibrational density of states (VDoS) to calculate elastic moduli and sound velocities of alpha-…

Materials Science · Physics 2012-05-22 M. Núñez Valdez , Z. Wu , Y. G. Yu , R. M. Wentzcovitch

A density functional theory is developed for fermions in one dimension, interacting via a delta-function. Such systems provide a natural testing ground for questions of principle, as the local density approximation should work well for…

Other Condensed Matter · Physics 2007-05-23 R. J. Magyar , K. Burke

Earlier tests show that the Tao-Perdew-Staroverov-Scuseria (TPSS) nonempirical meta-generalized gradient approximation (meta-GGA) for the exchange-correlation energy yields more accurate surface energies than the local spin density (LSD)…

Materials Science · Physics 2009-11-13 Jianmin Tao , John P. Perdew , Luis Miguel Almeida , Carlos Fiolhais , Stephan Kümmel

This study investigates the predictive capabilities of common DFT methods (GGA, GGA+$U$, and GGA+$U$+$V$) for determining the transition temperature of antiferromagnetic insulators. We utilize a dataset of 29 compounds and derive Heisenberg…

Computational Physics · Physics 2024-03-19 Zahra Mosleh , Mojtaba Alaei

The correct treatment of d electrons is of prime importance in order to predict the electronic properties of the prototype chalcopyrite semiconductors. The effect of d states is linked with the anion displacement parameter u, which in turn…

F.E. Harris has been a significant partner in our work on orbital-free density functional approximations for use in ab initio molecular dynamics. Here we mention briefly the essential progress on single-point functionals since our original…

Chemical Physics · Physics 2016-01-12 Valentin V. Karasiev , S. B. Trickey

Increasing interest in sustainable synthesis of ammonia, nitrates, and urea has led to an increase in studies of catalytic conversion between nitrogen-containing compounds using heterogeneous catalysts. Density functional theory (DFT) is…

Materials Science · Physics 2024-06-21 Honghui Kim , Neung-Kyung Yu , Nianhan Tian , Andrew J. Medford

Effects of explicit temperature dependence in the exchange-correlation (XC) free-energy functional upon calculated properties of matter in the warm dense regime are investigated. The comparison is between the KSDT finite-temperature local…

Materials Science · Physics 2016-06-29 Valentin V. Karasiev , Lázaro Calderín , S. B. Trickey

The response of a one-dimensional fermion system is investigated using Density Functional Theory (DFT) within the Local Density Approximation (LDA), and compared with exact results. It is shown that DFT-LDA reproduces surprisingly well some…

Strongly Correlated Electrons · Physics 2008-10-30 Stefan Schenk , Michael Dzierzawa , Peter Schwab , Ulrich Eckern

Within density-functional theory, the local-density approximation (LDA) correlation functional is typically built by fitting the difference between the near-exact and Hartree-Fock (HF) energies of the uniform electron gas (UEG), together…

Chemical Physics · Physics 2017-05-01 Fergus J. M. Rogers , Caleb J. Ball , Pierre-François Loos

The development of semilocal models for the kinetic energy density (KED) is an important topic in density functional theory (DFT). This is especially true for subsystem DFT, where these models are necessary to construct the required…

Other Condensed Matter · Physics 2017-02-15 S. Śmiga , E. Fabiano , L. A. Constantin , F. Della Sala

For closed-shell systems, the local density approximation (LDA) and the LYP, BLYP, and B3LYP functionals are shown to be compatible with reference-state one-particle density-matrix theory, where this recently introduced formalism is based…

Chemical Physics · Physics 2009-11-10 James P. Finley

We discuss self-consistently obtained ground-state electronic properties of monolayers of graphene and a number of beyond graphene compounds, including films of transition-metal dichalcogenides (TMDs), using the recently proposed strongly…

Materials Science · Physics 2017-04-27 I. G. Buda , C. Lane , B. Barbiellini , A. Ruzsinszky , J. Sun , A. Bansil

The stability of the nonmodulated martensitic phase, the austenitic Fermi surface and the phonon dispersion relations for ferromagnetic Ni$_2$MnGa are studied using density functional theory. Exchange-correlation effects are considered with…

We combine density functional theory (DFT) within the local density approximation (LDA), the quasiharmonic approximation (QHA), and a model vibrational density of states (VDoS) to calculate elastic moduli and sound velocities of…

Materials Science · Physics 2015-06-05 M. Núñez Valdez , Z. Wu , Y. G. Yu , J. Revenaugh , R. M. Wentzcovitch
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