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We propose a Jastrow factor for electron-electron correlations that interpolates between the radial symmetry of the Coulomb interaction at short inter-particle distance and the space-group symmetry of the simulation cell at large…

Strongly Correlated Electrons · Physics 2016-08-10 T. M. Whitehead , M. H. Michael , G. J. Conduit

We demonstrate the accuracy of ground-state energies of the transcorrelated Hamiltonian, employing sophisticated Jastrow factors obtained from variational Monte Carlo, together with the coupled cluster and distinguishable cluster methods at…

A form of Jastrow factor is introduced for use in quantum Monte Carlo simulations of finite and periodic systems. Test data are presented for atoms, molecules, and solids, including both all-electron and pseudopotential atoms. We…

Computational Physics · Physics 2008-01-03 N. D. Drummond , M. D. Towler , R. J. Needs

We study many-body correlations in the ground states of a general quantum system of bosons or fermions by including an additional Jastrow function in our ecently proposed variational coupled-cluster method. Our approach combines the…

Strongly Correlated Electrons · Physics 2009-11-13 Y. Xian

We present a novel specialization of the variational Monte Carlo linear method for the optimization of the recently introduced cluster Jastrow antisymmetric geminal power ansatz, achieving a lower-order polynomial cost scaling than would be…

Chemical Physics · Physics 2016-03-23 Eric Neuscamman

We introduce a basis of counting functions that, by cleanly tessellating three dimensional space, allows real space number counting Jastrow factors to be straightforwardly applied to general molecular situations. By exerting direct control…

Strongly Correlated Electrons · Physics 2018-11-09 Brett Van Der Goetz , Leon Otis , Eric Neuscamman

In this article, we report a fully ab initio variational Monte Carlo study of the linear, and periodic chain of Hydrogen atoms, a prototype system providing the simplest example of strong electronic correlation in low dimensions. In…

Strongly Correlated Electrons · Physics 2015-05-30 Lorenzo Stella , Claudio Attaccalite , Sandro Sorella , Angel Rubio

Compact and accurate wave functions can be constructed by quantum Monte Carlo methods. Typically, these wave functions consist of a sum of a small number of Slater determinants multiplied by a Jastrow factor. In this paper we study the…

Condensed Matter · Physics 2009-10-30 Chien-Jung Huang , C. J. Umrigar , M. P. Nightingale

We have developed a flexible framework for constructing Jastrow factors which allows for the introduction of terms involving arbitrary numbers of particles. The use of various three- and four-body Jastrow terms in quantum Monte Carlo…

Computational Physics · Physics 2015-06-05 Pablo Lopez Rios , Priyanka Seth , Neil D Drummond , Richard J Needs

Transcorrelated coupled cluster and distinguishable cluster methods are presented. The Hamiltonian is similarity transformed with a Jastrow factor in the first quantisation, which results in up to three-body integrals. The coupled cluster…

Chemical Physics · Physics 2021-12-22 Thomas Schraivogel , Aron J. Cohen , Ali Alavi , Daniel Kats

Quantum Monte Carlo simulations of interacting electrons in solids often use Slater-Jastrow trial wave functions. The Jastrow function takes into account correlations between pairs of electrons. In simulations of solids, it is common to use…

Materials Science · Physics 2007-05-23 A. Garcia-Lekue , M. Nekovee , J. M. Pitarke , R. Gaudoin

Variational wave functions based on a Margenau-Brink cluster model with short range and state dependent correlations, and angular momentum projection are obtained for some nuclei with $12 \leq A \leq 16$. The calculations have been carried…

Nuclear Theory · Physics 2009-11-10 E. Buendia , F. J. Galvez , A. Sarsa

We propose a new ground state trial wavefunction for a two-dimensional Wigner crystal in a strong perpendicular magnetic field. The wavefunction includes Laughlin-Jastrow correlations between electron pairs, and may be interpreted as a…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Hangmo Yi , H. A. Fertig

A trial wave function for two-dimensional quantum dot helium in an arbitrary perpendicular magnetic field (a system of two interacting electrons in a two-dimensional parabolic confinement potential) is introduced. A key ingredient of this…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Orion Ciftja , M. Golam Faruk

We propose an efficient ${\cal O}(N^2)$-parameter ansatz that consists of a sequence of exponential operators, each of which is a unitary variant of Neuscamman's cluster Jastrow operator. The ansatz can also be derived as a decomposition of…

Chemical Physics · Physics 2020-07-07 Yuta Matsuzawa , Yuki Kurashige

We consider the Jastrow pair-product wavefunction for the strongly correlated Bose systems, in our case liquid helium-4. An ansatz is proposed for the pair factors which consists of a numeric solution to a modified and parametrized pair…

Other Condensed Matter · Physics 2017-04-03 Yaroslav Lutsyshyn

It has been well established that the Jastrow correlation factor can effectively capture the electron correlation effects, and thus, the efficient optimization of the many-body wave function including the Jastrow correlation factor is of…

Atomic Physics · Physics 2023-09-12 Masayuki Ochi

While coupled cluster theory accurately models weakly correlated quantum systems, it often fails in the presence of strong correlations where the standard mean-field picture is qualitatively incorrect. In many cases, these failures can be…

Nuclear Theory · Physics 2020-05-14 Y. Qiu , T. M. Henderson , T. Duguet , G. E. Scuseria

The accurate but expensive product of geminals ansatz may be approximated by a geminal power, but this approach sacrifices size consistency. Here we show both analytically and numerically that a size consistent form very similar to the…

Strongly Correlated Electrons · Physics 2012-11-19 Eric Neuscamman

We investigate the optimization of flexible tailored real-space Jastrow factors for use in the transcorrelated (TC) method in combination with highly accurate quantum chemistry methods such as initiator full configuration interaction…

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