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Related papers: Rotational spectroscopy of interstellar PAHs

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This work presents theoretical calculations of infrared spectra of nitrogen (N)-containing polycyclic aromatic hydrocarbon (PAH) molecules with incorporation of N, NH and NH$_2$ using density functional theory (DFT). The properties of their…

Astrophysics of Galaxies · Physics 2021-12-30 Akant Vats , Amit Pathak , Takashi Onaka , Mridusmita Buragohain , Itsuki Sakon , Izumi Endo

Aims. We aim to elucidate the spectral changes in the 3 micron region that result from chemical changes in the molecular periphery of polycyclic aromatic hydrocarbons (PAHs) with extra hydrogens (H-PAHs) and methyl groups (Me-PAHs).…

Astrophysics of Galaxies · Physics 2018-04-04 E. Maltseva , C. J. Mackie , A. Candian , A. Petrignani , X. Huang , T. J. Lee , A. G. G. M. Tielens , J. Oomens , WJ Buma

We report the results of a search for emission features from interstellar deuterated polycyclic aromatic hydrocarbons (PAHs) in the 4um region with the Infrared Camera (IRC) onboard AKARI. No significant excess emission is seen in 4.3-4.7um…

Astrophysics of Galaxies · Physics 2015-06-17 Takashi Onaka , Tamami I. Mori , Itsuki Sakon , Ryou Ohsawa , Hidehiro Kaneda , Yoko Okada , Masahiro Tanaka

Polycyclic Aromatic Hydrocarbons (PAHs) constitute a significant fraction of the Universe's carbon budget, playing a key role in the cosmic carbon cycle and dominating the mid-infrared spectra of astrophysical environments in which they…

Solar and Stellar Astrophysics · Physics 2026-03-18 Charlotte Smith-Perez , Aidan Hembruff , Els Peeters , Alexander G. G. M. Tielens , Alessandra Ricca

A distinct set of broad emission features at 3.3, 6.2, 7.7, 8.6, 11.3, and 12.7 $\mu$m, is often detected in protoplanetary disks (PPDs). These features are commonly attributed to polycyclic aromatic hydrocarbons (PAHs). We model these…

Solar and Stellar Astrophysics · Physics 2017-02-08 Ji Yeon Seok , Aigen Li

In the interstellar medium (ISM), polycylic aromatic hydrocarbons (PAHs) are believed to be an important carbon reservoir, accounting for up to a quarter of all interstellar carbon in our galaxy. This makes the investigation of their…

Astrophysics of Galaxies · Physics 2025-06-23 Karina Sogomonyan , Malek Ben Khalifa , Phoebe Pierré , Jérôme Loreau

Polycyclic aromatic hydrocarbons (PAHs) have been proposed as potential carriers of the unidentified infrared bands (UIRs) and the diffuse interstellar bands (DIBs). PAHs are not likely to form by gas-phase or solid-state interstellar…

The Interest in polycyclic aromatic hydrocarbons (PAHs) spans numerous fields and infrared spectroscopy is usually the method of choice to disentangle their molecular structure. In order to compute vibrational frequencies, numerous…

Chemical Physics · Physics 2021-05-18 Gaétan Laurens , Malalatiana Rabary , Julien Lam , Daniel Peláez , Abdul-Rahman Allouche

We present 10-15 micron spectra of a sample of H II regions, YSOs and evolved stars that show strong unidentified infrared emission features, obtained with the ISO/SWS spectrograph on-board ISO. These spectra reveal a plethora of emission…

It has been shown that the diversity of the aromatic emission features can be rationalized into different classes of objects, in which differences between circumstellar and interstellar matter are emphasised. We probe the links between the…

Astrophysics · Physics 2009-11-13 C. Joblin , R. Szczerba , O. Berne , C. Szyszka

Airborne and space-based low-resolution spectroscopy in the 1980s discovered tantalizing quantitative relationships between the gas phase C/O abundance ratio in planetary nebulae (PNe) and the fractions of total far-infrared luminosity…

Astrophysics · Physics 2009-11-13 Martin Cohen , Michael J. Barlow

Spitzer and AKARI observations have found that polycyclic aromatic hydrocarbons (PAHs) are present in nearby elliptical galaxies, but their spatial distributions are still unknown. In order to investigate their distributions, we performed…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-19 Hidehiro Kaneda , Takashi Onaka , Itsuki Sakon , Tetsu Kitayama , Yoko Okada , Toyoaki Suzuki , Daisuke Ishihara , Mitsuyoshi Yamagishi

We present a new methodology for simulating mid-infrared emission from polycyclic aromatic hydrocarbons (PAHs) in galaxy evolution simulations. To do this, we combine theoretical models of PAH emission features as they respond to varying…

Mixtures of polycylic aromatic hydrocarbons (PAHs) have been produced by means of laser pyrolysis. The main fraction of the extracted PAHs were primarily medium-sized, up to a maximum size of 38 carbon atoms per molecule. The use of…

Instrumentation and Methods for Astrophysics · Physics 2011-01-24 M. Steglich , C. Jäger , G. Rouillé , F. Huisken , H. Mutschke , Th. Henning

The high interstellar abundances of polycyclic aromatic hydrocarbons (PAHs) and their size distribution are the result of complex chemical processes implying dust, UV radiation, and the main gaseous components (H, C+, and O). These…

Astrophysics of Galaxies · Physics 2021-07-07 A. Omont , H. F. Bettinger

We present results of mid-infrared spectroscopic mapping observations of six star-forming regions in the Small Magellanic Cloud from the Spitzer Spectroscopic Survey of the SMC (S4MC). We detect the mid-IR emission from polycyclic aromatic…

We extend the prediction of vibrational spectra to large sized polycyclic aromatic hydrocarbon (PAH) molecules comprising up to \sim 1500 carbon atoms by evaluating the efficiency of several computational chemistry methodologies. We employ…

PAHs have been detected toward molecular clouds and some young stars with disks, but have not yet been associated with embedded young stars. We present a sensitive mid-IR spectroscopic survey of PAH features toward a sample of low-mass…

The PHANGS survey uses ALMA, HST, VLT, and JWST to obtain an unprecedented high-resolution view of nearby galaxies, covering millions of spatially independent regions. The high dimensionality of such a diverse multi-wavelength dataset makes…