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It is shown that the Gibbs paradox is actually paralogism, viz. an erroneous statement sounding credible due to the statistic-mechanical interpretation of entropy as a measure of "any and all" irreversibility. As an alternative, the…

General Physics · Physics 2014-02-10 V. A. Etkin

Quantifying irreversibility of a system using finite information constitutes a major challenge in stochastic thermodynamics. We introduce an observable that measures the time-reversal asymmetry between two states after a given time lag. Our…

Statistical Mechanics · Physics 2023-12-18 Shiling Liang , Simone Pigolotti

Experience collected in mesoscopic dynamic modeling of externally driven systems indicates absence of potentials that could play role of equilibrium or nonequilibrium thermodynamic potentials yet their thermo-dynamics-like modeling is often…

Statistical Mechanics · Physics 2017-02-01 Miroslav Grmela

An irreversible thermodynamical theory of solids is presented where the kinematic quantities are defined in an automatically objective way. Namely, auxiliary elements like reference frame, reference time and reference configuration are…

Classical Physics · Physics 2015-12-22 Tamás Fülöp

To describe the nonequilibrium states of a system we introduce a new thermodynamic parameter - the lifetime of a system. The statistical distributions which can be obtained out of the mesoscopic description characterizing the behaviour of a…

Statistical Mechanics · Physics 2007-05-23 V. V. Ryazanov , S. G. Shpyrko

With the help of a general expression of the entropies in extensive and nonextensive systems, some important relations between thermodynamics and statistical mechanics are revealed through the views of thermodynamics and statistic physics.…

Statistical Mechanics · Physics 2009-11-13 Zhifu Huang , Congjie Ou , A. Le Mehaute , Qiuping A. Wang , Jincan Chen

This article aims at revisiting, with the aid of simple and neat numerical examples, some of the basic features of macroscopic irreversibility, and, thus, of the mechanical foundation of the second principle of thermodynamics as drawn by…

Statistical Mechanics · Physics 2015-11-12 Luca Cerino , Fabio Cecconi , Massimo Cencini , Angelo Vulpiani

Relativistic irreversible thermodynamics is reformulated following the conventional approach proposed by Meixner in the non-relativistic case. Clear separation between mechanical and non-mechanical energy fluxes is made. The resulting…

General Relativity and Quantum Cosmology · Physics 2015-06-25 L. S. Garcia-Colin , A. Sandoval-Villalbazo

Thermodynamic relations are derived from first principles of mechanics for non-equilibrium processes. Since the key role herein is played by the law of increase of entropy, the latter is analyzed at first. It is shown that its derivation…

chao-dyn · Physics 2008-02-03 J. Kumicak , X. de Hemptinne

The emergence of irreversibility in physical processes, despite the fundamentally reversible nature of quantum mechanics, remains an open question in physics. This thesis explores the intricate relationship between quantum mechanics and…

Quantum Physics · Physics 2024-10-25 Alberto Rolandi

The approach to a substantiation of thermodynamics is offered. A conservative system of interacting elements, which is not in equilibrium, is used as a model. This system is then split into small subsystems that are accepted as being in…

Statistical Mechanics · Physics 2007-05-23 V. M. Somsikov

Time-reversal had always been assumed to be a symmetry of physics at the fundamental level. In this paper we will explore the violations of time-reversal symmetry at the fundamental level and the consequences on thermodynamic systems.…

Statistical Mechanics · Physics 2015-06-05 Jose A. Magpantay

Entropy production characterizes irreversibility. This viewpoint allows us to consider the thermodynamic uncertainty relation, which states that a higher precision can be achieved at the cost of higher entropy production, as a relation…

Statistical Mechanics · Physics 2021-12-09 Yoshihiko Hasegawa

Recently a number of approaches has been developed to connect the microscopic dynamics of particle systems to the macroscopic properties of systems in nonequilibrium stationary states, via the theory of dynamical systems. This way a direct…

Statistical Mechanics · Physics 2009-10-31 L. Rondoni , E. G. D. Cohen

Two questions connected to the macroscopic Maxwell equations are addressed: First, which form do they assume in the hydrodynamic regime, for low frequencies, strong dissipation and arbitrary field strengths. Second, what does this tell us…

Statistical Mechanics · Physics 2007-05-23 Mario Liu

We identify and explore the intriguing property of resource resonance arising within resource theories of entanglement, coherence and thermodynamics. While the theories considered are reversible asymptotically, the same is generally not…

Quantum Physics · Physics 2019-03-27 Kamil Korzekwa , Christopher T. Chubb , Marco Tomamichel

When a small dynamical system that is initially in contact with a heat bath is detached from this heat bath and then caused to undergo a quasi-static adiabatic processes, the statistical distribution of the system's energy differs from that…

Statistical Mechanics · Physics 2007-05-23 K. Sato , K. Sekimoto , T. Hondou , F. Takagi

Reciprocal relations correlate fairly accurately a great variety of experimental results. Nevertheless, the concepts of statistical fluctuations, and microscopic reversibility - the bases of the accepted proof of the relations by Onsager -…

Chemical Physics · Physics 2007-05-23 Elias P. Gyftopoulos

Statistical thermodynamics is valuable as a conceptual structure that shapes our thinking about equilibrium thermodynamic states. A cloud of unresolved questions surrounding the foundations of the theory could lead an impartial observer to…

Statistical Mechanics · Physics 2025-10-31 O. B. Ericok , J. K. Mason

The principle of microscopic reversibility says that, in equilibrium, two-time cross-correlations are symmetric under the exchange of observables. Thus, the asymmetry of cross-correlations is a fundamental, measurable, and often-used…

Statistical Mechanics · Physics 2023-08-24 Naruo Ohga , Sosuke Ito , Artemy Kolchinsky