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The phase transition of a fluid adsorbed in a heterogeneous system is studied with two simple lattice gas models within the framework of a mean-field theory. Despite the different origin of the heterogeneity (spatial variation of binding…

Statistical Mechanics · Physics 2007-05-23 E. V. Vakarin , W. Dong , J. P. Badiali

We report on the onset of fluid entrainment when a contact line is forced to advance over a dry solid of arbitrary wettability. We show that entrainment occurs at a critical advancing speed beyond which the balance between capillary,…

Soft Condensed Matter · Physics 2015-06-16 Rodrigo Ledesma-Aguilar , Aurora Hernández-Machado , Ignacio Pagonabarraga

Interfacial phenomena associated with fluid adsorption in two dimensional systems has recently been shown to exhibit hidden symmetries, or covariances, which precisely relate local adsorption properties in different confining geometries. We…

Statistical Mechanics · Physics 2009-11-10 C. Rascon , A. O. Parry

Using mesoscopic interfacial models and microscopic density functional theory we study fluid adsorption at a dry wall decorated with three completely wet stripes of width $L$ separated by distances $D_1$ and $D_2$. The stripes interact with…

Statistical Mechanics · Physics 2019-05-02 Alexandr Malijevský , A. O. Parry , Martin Pospíšil

The moisture absorption in granulated materials used in foundry technologies is analyzed. The absorption process has a diffusive behavior mainly. A simple experimental technique, in which the wet weight increment was recorded as the…

Materials Science · Physics 2007-05-23 Ernesto Villar Cocina , Eduardo Valencia Morales , Romulo Gonzalez Rodriguez

We use density functional theory to investigate adsorption of liquid mixtures on solid surfaces modified with end-grafted chains. The chains are modelled as freely joined spheres. The fluid molecules are spherical. All spherical species…

Soft Condensed Matter · Physics 2016-03-08 M. Borówko , T. Staszewski

Using molecular dynamics simulations, we study the motion of a closely fitting nanometer-size solid sphere in a fluid-filled cylindrical nanochannel at low Reynolds numbers and for a wide range of fluid-solid interactions corresponding to…

Soft Condensed Matter · Physics 2007-05-23 German Drazer , Boris Khusid , Joel Koplik , Andreas Acrivos

The heterogeneous distribution of water-repellent materials at the soil surface causes a phenomenon known as fractional wettability. This condition frequently triggers destabilization of the wetting front during water infiltration,…

We develop a diffuse solid method that is versatile and accurate for modeling wetting and multiphase flows in highly complex geometries. In this scheme, we harness N + 1-component phase field models to investigate interface shapes and flow…

The analytical expressions of liquid-vapor macroscopic contact angles are analyzed for various simple geometries and arrangements of the substrate, in particular when the latter exhibits two or more scales. It concerns the Wenzel state of…

Soft Condensed Matter · Physics 2021-03-17 J. De Coninck , F. Dunlop , T. Huillet

Direct numerical simulations are used to elucidate the interplay of wettability and fluid viscosities on immiscible fluid displacements in a heterogeneous porous medium.We classify the flow regimes based using qualitative and quantitative…

Interfacial fluctuation effects occuring at wedge and cone filling transitions are investigated and shown to exhibit very different characteristics. For both geometries we show how the conditions for observing critical (continuous) filling…

Soft Condensed Matter · Physics 2009-10-31 A. O. Parry , A. J. Wood , C. Rascon

We briefly discuss how the wetting properties of a fluid/solid interface can indirectly influence the diffusion properties of fluid confined between two solid walls. This influence is related to the variability of the hydrodynamic boundary…

Soft Condensed Matter · Physics 2007-05-23 Yannick Alméras , Jean-Louis Barrat , Lydéric Bocquet

We study non-equilibrium analogues of surface phase transitions in a minimal model of active particles in contact with a purely repulsive potential barrier that mimics a thin porous membrane. Under conditions of bulk motility-induced phase…

Statistical Mechanics · Physics 2021-12-15 Francesco Turci , Nigel B. Wilding

The development of substrates with a switchable wettability is on a fast pace. The limit of switching frequencies and contact angle differences between substrate states are steadily pushed further. We investigate the behavior of a droplet…

Fluid Dynamics · Physics 2022-04-01 Leon Topp , Moritz Stieneker , Svetlana Gurevich , Andreas Heuer

Condensation in linear wedges formed by semi-infinite walls is a well-established critical phenomenon characterized by the continuous growth of an adsorbed liquid layer as bulk two-phase coexistence is approached. In this study, we…

Soft Condensed Matter · Physics 2025-05-06 Jiří Janek , Alexandr Malijevský

Wetting phenomena play a key role in flows through porous media. Relative permeability and capillary pressure-saturation functions show a high sensitivity to wettability, which has different definitions at the continuum- and pore-scale. At…

We investigate adsorption of a gas on the flat surface of a solid deformable adsorbent taking into account thermal fluctuations and analyze in detail the effect of thermal fluctuations on the adsorbent deformation in adsorption. The…

Materials Science · Physics 2017-02-13 A. S. Usenko

Using fundamental-measure density functional theory we investigate entropic wetting in an asymmetric binary mixture of hard spheres with positive non-additivity. We consider a general planar hard wall, where preferential adsorption is…

Soft Condensed Matter · Physics 2015-05-28 Paul Hopkins , Matthias Schmidt

Microfluidic devices offer unique opportunities to directly observe multiphase flow in porous media. However, as a direct representation of flow in geological pore networks, conventional microfluidics face several challenges. One is that…

Fluid Dynamics · Physics 2026-03-11 S. J. Cox , A. Davarpanah , W. R. Rossen