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The contact of water with graphene is of fundamental importance and of great interest for numerous promising applications, but how graphene interacts with water remains unclear. Here we used atomic force microscopy to investigate…

Mesoscale and Nanoscale Physics · Physics 2016-04-12 Hsien-Chen Ko , Wei-Hao Hsu , Chih-Wen Yang , Chung-Kai Fang , Yi-Hsien Lu , Ing-Shouh Hwang

Energy and water issues are the two main global challenges faced by human in the past decade. The rapid growth in global energy consumption and greenhouse gas emissions have encouraged the exploration of renewable energy sources as…

Materials Science · Physics 2022-08-02 Arvin Shadravan , Mahmood Amani

Graphene-based laminates, with ultralong and tortuous nanocapillaries formed by simply stacking graphene flakes together, have great promises in filtration and separation. However, the information on liquid water trans-membrane permeation…

Chemical Physics · Physics 2015-02-11 Pengzhan Sun , He Liu , Kunlin Wang , Minlin Zhong , Dehai Wu , Hongwei Zhu

Porous graphene has high mechanical strength and atomic layer thickness, which make it a promising material for material separation and biomolecule sensing. Electrostatic interactions between charges in aqueous solution are a kind of strong…

Chemical Physics · Physics 2016-08-02 Yinghua Qiu , Kun Li , Weiyu Chen , Wei Si , Qiyan Tan , Yunfei Chen

Separation of salt ions from seawater using graphene oxide (GO) membrane is an emerging desalination method. Here, we investigate the dynamic behavior of water, sodium, and chloride ions inside GO membrane using a computational approach.…

Chemical Physics · Physics 2021-08-25 One-Sun Lee

Barrier films preventing permeation of gases and moistures are important for many industries ranging from food to medical and from chemical to electronic. From this perspective, graphene has recently attracted particular interest because…

Materials Science · Physics 2014-11-19 Y. Su , V. G. Kravets , S. L. Wong , J. Waters , A. K. Geim , R. R. Nair

Thousands of tons of isotopic mixtures are processed annually for heavy-water production and tritium decontamination. The existing technologies remain extremely energy intensive and require large capital investments. New approaches are…

Materials Science · Physics 2017-05-18 M. Lozada-Hidalgo , S. Zhang , S. Hu , A. Esfandiar , I. V. Grigorieva , A. K. Geim

Graphynes are 2D porous structures deriving from graphene featuring triangular and regularly distributed subnanometer pores, which may be exploited to host small gaseous species. First principles adsorption energies of molecular hydrogen…

Chemical Physics · Physics 2015-10-06 Massimiliano Bartolomei , Estela Carmona-Novillo , Giacomo Giorgi

The electrochemical hydrogenation of graphene induces a robust and reversible conductor-insulator transition, of strong interest in logic-and-memory applications. However, its mechanism remains unknown. Here we show that it proceeds as a…

Adsorption is one important way applied to water decontamination, where carbon is commonly used as highly effective absorbent. Carbon of different morphologies and structures normally demonstrate distinct capabilities to adsorption-typed…

Materials Science · Physics 2017-05-02 Sun Ling

Hydrogen isotope separation has been effectively achieved using gaseous H2/D2 filtered through graphene/Nafion composite membranes. Nevertheless, deuteron nearly does not exist in the form of gaseous D2 in nature but in liquid water. Thus,…

Molecular adsorption on surfaces plays a central role in catalysis, corrosion, desalination, and many other processes of relevance to industry and the natural world. Few adsorption systems are more ubiquitous or of more widespread…

Creating nanopores in graphene is a powerful tool for engineering its properties. Nanopores in graphene tune their electrical, optical, magnetic, and mechanical properties. However, controlling nanopores formation at the nanoscale level…

Mesoscale and Nanoscale Physics · Physics 2023-05-23 Sidi Abdelmajid Ait Abdelkader , Ismail Benabdallah , Mohammed Amlieh , Abdelouahad El Fatimy

Semi-permeable membranes are important elements in water purification and energy generation applications, for which the atomic thickness and strength of graphene can enhance efficiency and permeation rate while maintaining good selectivity.…

Mesoscale and Nanoscale Physics · Physics 2020-09-09 Robin J. Dolleman , Allard J. Katan , Herre S. J. van der Zant , Peter G. Steeneken

Despite being only one-atom thick, defect-free graphene is considered to be completely impermeable to all gases and liquids. This conclusion is based on theory and supported by experiments that could not detect gas permeation through…

Developing 'smart' membranes that allow precise and reversible control of molecular permeation using external stimuli would be of intense interest for many areas of science: from physics and chemistry to life-sciences. In particular,…

Water desalination through nanopores has been shown to be a promising alternative to the currently water purification processes. In spite the results in this direction obtained by means of computational simulations were animating there are…

Graphene has recently attracted a great deal of interest in both academia and industry because of its unique electronic and optical properties [1,2], as well as its chemical, thermal, and mechanical properties. The superb characteristics of…

Materials Science · Physics 2010-06-29 Mingsheng Xu , Daisuke Fujita , Keisuke Sagisaka , Eiichiro Watanabe , Nobutaka Hanagata

Selective ion transport is a hallmark of biological ion channel behavior but is a major challenge to engineer into artificial membranes. Here, we demonstrate, with all-atom molecular dynamics simulations, that bare graphene nanopores yield…

Mesoscale and Nanoscale Physics · Physics 2017-08-22 Subin Sahu , Michael Zwolak

Water inside the low dimensional carbon structures has been considered seriously owing to fundamental interest in its flow and structures as well as its practical impact. Recently, the anomalous perfect penetration of water through graphene…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Danil W. Boukhvalov , Mikhail I. Katsnelson , Young-Woo Son