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Related papers: Molecular kinetics of solid and liquid CHCl$_3$

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Understanding the quantum dynamics of strongly coupled molecule-cavity systems remains a significant challenge in molecular polaritonics. This work develops a comprehensive self-consistent model simulating electromagnetic interactions of…

Chemical Physics · Physics 2025-01-29 Maxim Sukharev , Joseph E. Subotnik , Abraham Nitzan

Molecular machines described in this paper are meant to be such molecular systems that make use of conformational mobility (i.e. hindered rotation around chemical bonds and molecular construction deformations with formation and breakage of…

Chemical Physics · Physics 2007-05-23 Ye. V. Tourleigh , K. V. Shaitan

The effects of particle roughness and short-ranged non-central forces on colloidal gels are studied using computer simulations in which particles experience a sinusoidal variation in energy as they rotate. The number of minima $n$ and…

Soft Condensed Matter · Physics 2019-09-05 Hong T. Nguyen , Alan L. Graham , Peter H. Koenig , Lev D. Gelb

We show that quantum rotational wavepacket dynamics in molecules can be described by a new system-environment model, which consists of a rotational subsystem coupled to a magnetically tunable spin bath formed by the nuclear spins within the…

Quantum Physics · Physics 2025-02-25 Timur V. Tscherbul , Lincoln D. Carr

We analyze two simple model planar molecules: an ionic molecule with D3 symmetry and a covalent molecule with D6 symmetry. Both symmetries allow the existence of chiral molecular orbitals and normal modes that are coupled to each other in a…

Mesoscale and Nanoscale Physics · Physics 2025-11-05 Ivan Pasqua , Gregorio Staffieri , Michele Fabrizio

We present a simple quantum mechanical model describing excited rotational states of molecules in superfluid helium nanodroplets, as recently studied in non-adiabatic molecular alignment experiments [Cherepanov et al., Phys. Rev. A 104,…

Methylammonium lead iodide (CH3NH3PbI3) based solar cells have shown impressive power conversion efficiencies of above 20%. However, the microscopic mechanism of the high photovoltaic performance is yet to be fully understood. Particularly,…

Materials Science · Physics 2016-01-20 T. Chen , B. J. Foley , B. Ipek , M. Tyagi , J. R. D. Copley , C. M. Brown , J. J. Choi , S. -H. Lee

Many atomic liquids can form transient covalent bonds reminiscent of those in the corresponding solid states. These directional interactions dictate many important properties of the liquid state, necessitating a quantitative, atomic-scale…

Chemical Physics · Physics 2020-03-30 Richard C. Remsing , Michael L. Klein

We have investigated thermodynamic and dynamic properties as well as the dielectric constant of water-metha\-nol model mixtures in the entire range of composition by using constant pressure molecular dynamics simulations at ambient…

Soft Condensed Matter · Physics 2015-12-25 E. Galicia-Andrés , H. Dominguez , L. Pusztai , O. Pizio

We present static and dynamic properties of molecular correlation functions S_{lmn,l'm'n'}(q,t) in a simulated supercooled liquid of water molecules, as a preliminary effort in the direction of solving the molecular mode coupling theory…

Statistical Mechanics · Physics 2007-05-23 L. Fabbian , A. Latz , R. Schilling , F. Sciortino , P. Tartaglia , C. Theis

Extremely fast rotating molecules carrying significantly more energy in their rotation than in any other degree of freedom are known as "super rotors". It has been speculated that super rotors may exhibit a number of unique properties.…

Optics · Physics 2013-06-11 Aleksey Korobenko , Alexander A. Milner , Valery Milner

We have performed molecular dynamics simulations for a model two-dimensional soft-core mixture in a supercooled state. The mixture exhibits a slow structural relaxation in a quiescent state, however, the relaxation is much enhanced in…

Soft Condensed Matter · Physics 2009-11-10 Ryoichi Yamamoto , Kunimasa Miyazaki , David R. Reichman

We report molecular-dynamics simulation results performed for a model of molecular liquid orthoterphenyl in supercooled states, which we then compare with both experimental data and mode-coupling-theory (MCT) predictions, aiming at a better…

Soft Condensed Matter · Physics 2009-11-10 S. -H. Chong , F. Sciortino

We report extensive simulations of liquid supercooled states for a simple three-sites molecular model, introduced by Lewis and Wahnstr"om [L. J. Lewis and G. Wahnstr"om, Phys. Rev. E 50, 3865 (1994)] to mimic the behavior of…

Soft Condensed Matter · Physics 2009-10-31 A. Rinaldi , F. Sciortino , P. Tartaglia

Transport properties of concentrated electrolytes have been analyzed using classical molecular dynamics simulations with the algorithms and parameters typical of simulations describing complex electrokinetic phenomena. The electrical…

Materials Science · Physics 2015-03-17 Carles Calero , Jordi Faraudo , Marcel Aguilella-Arzo

Three solid solutions of [CH$_3$NH$_3$]Co$_x$Ni$_{1-x}$(HCOO)$_3$, with $x$ = 0.25 (1), 0.50 (2) and 0.75 (3), were synthesized and their nuclear structures and magnetic properties were characterized using single crystal neutron diffraction…

Strongly Correlated Electrons · Physics 2024-08-06 Madeleine Geers , Oscar Fabelo , Matthew J. Cliffe , Laura Cañadillas-Delgado

It is shown that the drastic distinction in the rotational structure of molecules in the He4 and He3 liquids observed in [1] is due to the difference in the spectral density of excitations regardless of the hydrodynamic properties. The…

Statistical Mechanics · Physics 2009-10-31 V. S. Babichenko , Yu. Kagan

Molecular dynamics simulation is used to model the self-assembly of polyhedral shells containing 180 trapezoidal particles that correspond to the T=3 virus capsid. Three kinds of particle, differing only slightly in shape, are used to…

Biomolecules · Quantitative Biology 2020-04-01 D. C. Rapaport

Non-monotonous changes in velocity autocorrelations across the transformation from molecular to atomic fluid in hydrogen under pressure are studied by ab initio molecular dynamics simulations at the temperature 2500 K. We report diffusion…

Soft Condensed Matter · Physics 2020-05-27 G. Ruocco , T. Bryk , C. Pierleoni , A. P. Seitsonen

Methanol-water liquid mixtures have been investigated by high-energy synchrotron X-ray and neutron diffraction at low temperatures. We are thus able to report the first complete sets of both X-ray and neutron weighted total scattering…