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We consider a multiatomic system where the nuclei are assumed to be point charges at fixed positions. Particles interact via Coulomb potential and electrons have pseudo-relativistic kinetic energy. We prove the van der Waals-London law,…

Mathematical Physics · Physics 2022-11-16 Jean-Marie Barbaroux , Michael Hartig , Dirk Hundertmark , Semjon Vugalter

In this work we improve upon previous results on the expansion of the interaction energy of two atoms. On the one hand we prove the van der Waals-London's law, assuming that only one of the ground state eigenspaces of the atoms is…

Mathematical Physics · Physics 2019-02-19 Ioannis Anapolitanos , Mathieu Lewin , Matthias Roth

van der Waals interactions govern the physics of a plethora of molecular structures. It is well known that the leading term in the distance-based London expansion of the van der Waals energy for atomic and molecular dimers decays as…

Chemical Physics · Physics 2017-11-22 Mireia Via-Nadal , Mauricio Rodríguez-Mayorga , Eduard Matito

We prove van der Waals - London's law of decay of the van der Waals force for a collection of neutral atoms at large separation.

Mathematical Physics · Physics 2013-08-27 Ioannis Anapolitanos , Israel Michael Sigal

We consider the interatomic van der Waals interaction energy between two neutral ground-state atoms moving in the vacuum space with the same uniform acceleration. We assume the acceleration orthogonal to their separation, so that their…

Quantum Physics · Physics 2013-07-25 Antonio Noto , Roberto Passante

The van der Waals interaction between neutral atoms is typically studied using stationary perturbation theory for the short-distance (London) limit, while long-distance (Casimir-Polder) results are usually derived via semiclassical,…

Quantum Physics · Physics 2025-12-30 L. Saba , C. D. Fosco

We extend a method (E. Canc\`es and L.R. Scott, SIAM J. Math. Anal., 50, 2018, 381--410) to compute more terms in the asymptotic expansion of the van der Waals attraction between two hydrogen atoms. These terms are obtained by solving a set…

Mathematical Physics · Physics 2020-07-09 Éric Cancès , Rafaël Coyaud , L. Ridgway Scott

A quantum electrodynamic calculation of the interaction of an excited-state atom with a ground-state atom is performed. For an excited reference state and a lower-lying virtual state, the contribution to the interaction energy naturally…

Quantum Physics · Physics 2017-05-19 U. D. Jentschura , V. Debierre

In the first part of the thesis we consider the constraints of causality and unitarity for particles interacting via strictly finite-range interactions. We generalize Wigner's causality bound to the case of non-vanishing partial-wave…

Nuclear Theory · Physics 2014-09-16 Serdar Elhatisari

Using fourth-order perturbation theory, a general formula for the van der Waals potential of two neutral, unpolarized, ground-state atoms in the presence of an arbitrary arrangement of dispersing and absorbing magnetodielectric bodies is…

Quantum Physics · Physics 2007-05-23 Hassan Safari , Stefan Yoshi Buhmann , Dirk-Gunnar Welsch , Ho Trung Dung

Based on a microscopic model, we use a functional integral approach to evaluate the quantum interaction energy between two neutral atoms. Each atom is coupled to the electromagnetic (EM) field via a dipole term, generated by an electron…

Quantum Physics · Physics 2023-07-19 C. D. Fosco , G. Hansen

We consider a model of quantum-mechanical particles interacting via point interactions of infinite scattering length. In the case of fermions we prove a Lieb-Thirring inequality for the energy, i.e., we show that the energy is bounded from…

Mathematical Physics · Physics 2015-06-03 Rupert L. Frank , Robert Seiringer

Within the frame of macroscopic quantum electrodynamics in causal media, the van der Waals interaction between an atomic system and an arbitrary arrangement of dispersing and absorbing dielectric bodies including metals is studied. It is…

Quantum Physics · Physics 2007-05-23 Stefan Yoshi Buhmann , Ho Trung Dung , Dirk-Gunnar Welsch

Van der Waals interactions between two neutral but polarizable systems at a separation $R$ much larger than the typical size of the systems are at the core of a broad sweep of contemporary problems in settings ranging from atomic, molecular…

High Energy Physics - Phenomenology · Physics 2017-06-14 Nora Brambilla , Vladyslav Shtabovenko , Jaume Tarrús Castellà , Antonio Vairo

The Lieb-Schultz-Mattis (LSM) theorem asserts that microscopic details of the system can impose non-trivial constraints on the system's low-energy properties. While traditionally applied to short-range interaction systems, where locality…

Strongly Correlated Electrons · Physics 2024-07-19 Yi-Neng Zhou , Xingyu Li

Using a recently obtained (general) formula for the interaction energy between an excited and a ground-state atom (Sherkunov Y 2007 Phys. Rev. A 75 012705), we consider the interaction energy between two such atoms near the interface…

Quantum Physics · Physics 2008-04-10 Marin-Slobodan Tomas

We compute the conservative van-der-Waals forces between two atoms, one of which is initially excited, in the limit of identical atoms. Starting with the perturbative calculation of the interaction between two dissimilar atoms, we show that…

Quantum Physics · Physics 2021-12-08 J. Sánchez-Cánovas , M. Donaire

At long distances interactions between neutral ground state atoms can be described by the Van der Waals potential V(r) =-C6/r^6-C8/r^8 - ... . In the ultra-cold regime atom-atom scattering is dominated by s-waves phase shifts given by an…

Other Condensed Matter · Physics 2013-05-29 A. Calle Cordon , E. Ruiz Arriola

We provide a simple proof of the Lieb-Robinson bound and use it to prove the existence of the dynamics for interactions with polynomial decay. We then use our results to demonstrate that there is an upper bound on the rate at which…

Mathematical Physics · Physics 2007-05-23 Bruno Nachtergaele , Yoshiko Ogata , Robert Sims

Recent works have revealed the intricate effect of long-range interactions on information transport in quantum many-body systems: In $D$ spatial dimensions, interactions decaying as a power-law $r^{-\alpha}$ with $\alpha > 2 D+1$ exhibit a…

Mathematical Physics · Physics 2025-09-23 Marius Lemm , Tom Wessel
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