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The ionization dynamics of a hydrogen molecule, serving as a fundamental benchmark in quantum chemistry, is investigated within a comprehensive framework combining quantum electrodynamics and the Lindblad master equation. This approach…

Quantum Physics · Physics 2025-11-27 Hui-hui Miao

Mathematical theory of the quantum systems control is based on some ideas of the optimal control theory. These ideas are developed here as applied to these systems. The results obtained meet the deficiencies in the basis and algorithms of…

Quantum Physics · Physics 2008-05-22 V. F. Krotov

In principle, we should not need the time-dependent extension of density-functional theory (TDDFT) for excitations, and in particular not for Molecular Dynamics (MD) studies: the theorem by Hohenberg and Kohn teaches us that for any…

Strongly Correlated Electrons · Physics 2015-05-27 J. L. Alonso , Alberto Castro , Pablo Echenique , Angel Rubio

In quantum systems which satisfy the hypothesis of equal weights for eigenstates [4], the maximum work principle (for extremely slow and relatively fast operation) is derived by using quantum dynamics alone. This may be a crucial step in…

Statistical Mechanics · Physics 2007-05-23 Hal Tasaki

We propose an analysis of the time-optimal control of a dissipative two-level quantum system whose dynamics is governed by the Lindblad equation. This simple system allows one to use tools of geometric control theory and to construct its…

Quantum Physics · Physics 2007-08-29 D. Sugny , C. Kontz , H. R. Jauslin

Controlling the dynamics of quantum systems is a crucial task in quantum science and technology. Obtaining the driving field that transforms the quantum systems to its objective is a typical control task. This task is hard, scaling…

Quantum Physics · Physics 2022-01-10 Aviv Aroch , Shimshon Kallush , Ronnie Kosloff

This paper is concerned with a risk-sensitive optimal control problem for a feedback connection of a quantum plant with a measurement-based classical controller. The plant is a multimode open quantum harmonic oscillator driven by a…

Quantum Physics · Physics 2019-12-30 Igor G. Vladimirov , Matthew R. James , Ian R. Petersen

A generalized formalism of the so-called non-adiabatic quantum molecular dynamics is presented, which applies for atomic many-body systems in external laser fields. The theory treats the nuclear dynamics and electronic transitions…

Atomic Physics · Physics 2007-05-23 Thomas Kunert , Ruediger Schmidt

The extraordinary success in laser cooling, trapping, and coherent manipulation of atoms has energized the efforts in extending this exquisite control to molecules. Not only are molecules ubiquitous in nature, but the control of their…

Atomic Physics · Physics 2022-04-27 D. Mitra , K. H. Leung , T. Zelevinsky

We introduce a method for solving the problem of an externally controlled electron spin in a quantum dot interacting with host nuclei via the hyperfine interaction. Our method accounts for generalized (non-unitary) evolution effected by…

Mesoscale and Nanoscale Physics · Physics 2011-07-21 Edwin Barnes , Sophia E. Economou

The core problem in optimal control theory applied to quantum systems is to determine the temporal shape of an applied field in order to maximize the expectation of value of some physical observable. The functional which maps the control…

Quantum Physics · Physics 2019-01-10 Martín Larocca , Pablo Poggi , Diego Wisniacki

Ultrafast electron diffraction and time-resolved serial crystallography are the basis of the ongoing revolution in capturing at the atomic level of detail the structural dynamics of molecules. However, most experiments employ the classical…

A class of optimal control problems governed by linear fractional diffusion equation with control constraint is considered. We first establish some results on the existence of strong solution to the state equation and the existence of…

Optimization and Control · Mathematics 2022-11-24 Bui Trong Kien , Bui Ngoc Muoi , Ching-Feng Wen , Jen-Chih Yao

We present a general multi-component density functional theory in which electrons and nuclei are treated completely quantum mechanically, without the use of a Born-Oppenheimer approximation. The two fundamental quantities in terms of which…

Materials Science · Physics 2007-05-23 Thomas Kreibich , Robert van Leeuwen , E. K. U. Gross

High-harmonic generation (HHG) is a nonlinear process in which a material sample is irradiated by intense laser pulses, causing the emission of high harmonics of the incident light. HHG has historically been explained by theories employing…

We develop a time-dependent theory to investigate electron dynamics and photoionization processes of diatomic molecules interacting with strong laser fields including electron-electron correlation effects. We combine the recently formulated…

Chemical Physics · Physics 2016-02-02 Henrik R. Larsson , Sebastian Bauch , Lasse Kragh Sørensen , Michael Bonitz

In this paper we study and solve an optimal control problem motivated by applications in quantum and classical physics. Although apparently simple, this optimal control problem is not easy to solve and we resort to various elaborated…

Optimization and Control · Mathematics 2025-07-18 Arnaud Lazarus , Emmanuel Trélat

We discuss time dependent quantum systems on bounded domains. Our work may be viewed as a framework for several models, including linear iterations involved in time dependent density functional theory (TDDFT), the Hartree-Fock model, or…

Dynamical Systems · Mathematics 2013-09-17 Joseph W. Jerome , Eric Polizzi

The approach of an ideal gas to equilibrium is simulated through a generalization of the Ehrenfest ball-and-box model. In the present model, the interior of each box is discretized, {\it i.e.}, balls/particles live in cells whose occupation…

Statistical Mechanics · Physics 2009-11-10 S. Prestipino

We derive a time-dependent density functional theory appropriate for calculating the near-edge X-ray absorption spectrum in molecules and condensed matter. The basic assumption is to increase the space of many-body wave functions from one…

Strongly Correlated Electrons · Physics 2015-06-16 G. F. Bertsch , A. Lee