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The spatial suppression of order parameter fluctuations in a critical media produces Critical Casimir forces acting on confining surfaces. This scenario is realized in a critical binary mixture near the demixing transition point that…

Statistical Mechanics · Physics 2014-10-03 Oleg A. Vasilyev

Mesoscopic particles immersed in a critical fluid experience long-range Casimir forces due to critical fluctuations. Using field theoretical methods, we investigate the Casimir interaction between two spherical particles and between a…

Condensed Matter · Physics 2009-10-28 E. Eisenriegler , U. Ritschel

Among the various kinds of effective forces in soft matter, the spatial range and the direction of the so-called critical Casimir force - which is generated by the enhanced thermal fluctuations close to a continuous phase transition - can…

Soft Condensed Matter · Physics 2011-02-14 Andrea Gambassi , S. Dietrich

We study theoretically and experimentally the solvent-mediated critical Casimir force acting on colloidal particles immersed in a binary liquid mixture of water and 2,6-lutidine and close to substrates which are chemically patterned with…

We study the normal and lateral effective critical Casimir forces acting on a spherical colloid immersed in a critical binary solvent and close to a chemically structured substrate with alternating adsorption preference. We calculate the…

Soft Condensed Matter · Physics 2009-12-17 M. Tröndle , S. Kondrat , A. Gambassi , L. Harnau , S. Dietrich

We study the critical Casimir interaction between two spherical colloids immersed in a binary liquid mixture close to its critical demixing point. The surface of each colloid prefers one species of the mixture with the exception of a…

Statistical Mechanics · Physics 2020-04-22 Nima Farahmand Bafi , Piotr Nowakowski , Siegfried Dietrich

We consider an ensemble of spherical colloidal particles immersed in a near-critical solvent such as a binary liquid mixture close to its critical demixing point. The emerging long-ranged fluctuations of the corresponding order parameter of…

Soft Condensed Matter · Physics 2015-06-03 T. F. Mohry , A. Maciołek , S. Dietrich

The critical Casimir effect provides a thermodynamic analogue of the well-known quantum mechanical Casimir effect. It acts between two surfaces immersed in a critical binary liquid mixture, and results from the confinement of concentration…

Soft Condensed Matter · Physics 2015-06-15 Van Duc Nguyen , Suzanne Faber , Zhibing Hu , Gerard H. Wegdam , Peter Schall

The effective interaction between two planar walls immersed in a fluid is investigated by use of Density Functional Theory in the super-critical region of the phase diagram. A hard core Yukawa model of fluid is studied with special…

Statistical Mechanics · Physics 2017-04-05 Pietro Anzini , Alberto Parola

If colloidal solute particles are suspended in a solvent close to its critical point, they act as cavities in a fluctuating medium and thereby restrict and modify the fluctuation spectrum in a way which depends on their relative…

Soft Condensed Matter · Physics 2018-11-14 Anna Maciolek , Siegfried Dietrich

Within mean field theory, we investigate the bridging transition between a pair of parallel cylindrical colloids immersed in a binary liquid mixture as a solvent which is close to its critical consolute point $T_c$. We determine the…

Soft Condensed Matter · Physics 2017-10-11 M. Labbé-Laurent , A. D. Law , S. Dietrich

Understanding the force between charged surfaces immersed in an electrolyte solution is a classic problem in soft matter and liquid-state theory. Recent experiments showed that the force decays exponentially but the characteristic decay…

Soft Condensed Matter · Physics 2018-09-26 Alpha A. Lee , Jean-Pierre Hansen , Olivier Bernard , Benjamin Rotenberg

Some time ago, Fisher and de Gennes pointed out that long-ranged correlations in a fluid close to its critical point Tc cause distinct forces between immersed colloidal particles which can even lead to flocculation [C. R. Acad. Sc. Paris B…

Statistical Mechanics · Physics 2007-05-23 F. Schlesener , A. Hanke , S. Dietrich

The confinement of long-ranged critical fluctuations in the vicinity of second-order phase transitions in fluids generates critical Casimir forces acting on confining surfaces or among particles immersed in a critical solvent. This is…

Statistical Mechanics · Physics 2015-06-17 O. A. Vasilyev , S. Dietrich

Colloids immersed in a critical or near-critical binary liquid mixture and close to a chemically patterned substrate are subject to normal and lateral critical Casimir forces of dominating strength. For a single colloid we calculate these…

Soft Condensed Matter · Physics 2010-08-18 M. Tröndle , S. Kondrat , A. Gambassi , L. Harnau , S. Dietrich

We present a numerical study of the effective potential $V_\mathrm{eff}$ between two hard-sphere colloids dispersed in a solvent of interacting particles, for several values of temperature and solvent density, approaching the solvent…

Soft Condensed Matter · Physics 2013-04-08 Nicoletta Gnan , Emanuela Zaccarelli , Piero Tartaglia , Francesco Sciortino

The Casimir effect arises when long-ranged fluctuations are geometrically confined between two surfaces, leading to a macroscopic force. Traditionally, these forces have been observed in quantum systems and near critical points in classical…

Soft Condensed Matter · Physics 2017-01-19 Justin C. Burton , Juan-José Liétor-Santos

In confined systems near a continuous phase transition the long-ranged fluctuations of the corresponding order parameter are subject to boundary conditions. These constraints result in so-called critical Casimir forces acting as effective…

Statistical Mechanics · Physics 2015-05-18 T. F. Mohry , A. Maciołek , S. Dietrich

We investigate the phase behaviour of mixtures of two populations of colloidal particles dispersed in a binary solvent system near its critical composition. The surfaces of particles are chemically modified to elicit a specific solvent…

Soft Condensed Matter · Physics 2026-02-16 T. E. Kodger , N. Farahmand Bafi , M. Labbé-Laurent , E. Steijlen , A. Maciolek , P. Schall

If two ore more bodies are immersed in a critical fluid critical fluctuations of the order parameter generate long ranged forces between these bodies. Due to the underlying mechanism these forces are close analogues of the well known…

Soft Condensed Matter · Physics 2009-10-30 M. Krech
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