Related papers: A radical route to interstellar propylene formatio…
We report the first detection in the interstellar medium of $N$-cyanomethanimine (H$_2$CNCN), the stable dimer of HCN of highest energy, and the most complex organic molecule identified in space containing the prebiotically relevant NCN…
Aims. We investigate the dominant formation mechanism of H2CO and CH3OH in the Horsehead PDR and its associated dense core. Methods. We performed deep integrations of several H2CO and CH3OH lines at two positions in the Horsehead, namely…
Aims: To investigate the chemical relations between complex organics based on their spatial distributions and excitation conditions in the low-mass young stellar objects IRAS 16293-2422 A and B. Methods: Interferometric observations with…
Uranus and Neptune have atmospheres dominated by molecular hydrogen and helium. In the upper troposphere, methane is the third main molecule and condenses, yielding a vertical gradient in CH4. This condensable species being heavier than H2…
A gas-phase formation route is proposed for the recently detected propargylimine molecule. In analogy to other imines, such as cyanomethanimine, the addition of a reactive radical (C$_2$H in the present case) to methanimine (CH$_2$NH})…
Alcohols and aldehydes represent two key classes of interstellar complex organic molecules (COMs). This work seeks to better understand their possible chemical connections, with a focus on such molecules in the sources of the star-forming…
Methanol (CH$_{3}$OH) ice is abundant in space and is a key feedstock for seeding chemical complexity in interstellar and circumstellar environments. Despite its ubiquity, gas-phase methanol has only been detected in one disk around a…
The past decade has led to significant improvements in our understanding of the physical structure of the molecular cores of cold dark clouds. Observational efforts, in combination with improved knowledge of cloud structure, now provide…
We report the detection of complex molecules (HCOOCH_3, HCOOH and CH_3CN), signposts of a "hot core" like region, toward the low mass, Class 0 source NGC1333-IRAS4A. This is the second low mass protostar where such complex molecules have…
The dense molecular clump P1 in the infrared dark cloud (IRDC) complex G28.34+0.06 harbors a massive protostellar cluster at its extreme youth. Our previous Submillimeter Array (SMA) observations revealed several jet-like CO outflows…
Complex organic molecules (COMs) can be produced by energetic processing of interstellar ice mantles accreted on top of dust grains. Two COMs with proposed energetic ice formation pathways are formamide and acetaldehyde. Both have been…
Recent observations indicate that organic molecules are prevalent towards starless and prestellar cores. Deuteration of these molecules has not been well-studied during the starless phase. Published observations of singly-deuterated…
Freeze-out of the gas phase elements onto cold grains in dense interstellar and circumstellar media builds up ice mantles consisting of molecules that are mostly formed in situ (H2O, NH3, CO2, CO, CH3OH, and more). This review summarizes…
Massive star formation exhibits an extremely rich chemistry. However, not much evolutionary details are known yet, especially at high spatial resolution. Therefore, we synthesize previously published Submillimeter Array…
We investigate the presence of COMs in strongly UV-irradiated interstellar molecular gas. We have carried out a complete millimetre line survey using the IRAM30m telescope towards the edge of the Orion Bar photodissociation region (PDR),…
Methyl isocyanate (CH3NCO) is one of the important complex organic molecules detected on the comet 67P/Churyumov-Gerasimenko by Rosetta's Philae lander. It was also detected in hot cores around high-mass protostars along with a recent…
Amines, in particular primary amines (R-NH$_2$) are closely related to the primordial synthesis of amino acids since they share the same structural backbone. However, only limited number of amines has been identified in the ISM which…
N-methylformamide, CH3NHCHO, may be an important molecule for interstellar pre-biotic chemistry because it contains a peptide bond. The rotational spectrum of the most stable trans conformer of CH3NHCHO is complicated by strong…
Complex organic molecules (COMs) are widely detected in protostellar and protoplanetary systems, where they are thought to have been inherited in large part from earlier evolutionary phases. The chemistry of COMs in these earlier phases,…
In the currently-accepted model for star formation out of the interstellar gas in galaxies, the basic construction material is assumed to be large clouds of atomic hydrogen (HI). These clouds are thought to form higher-density complexes of…