Related papers: Flory theory for Polymers
The Flory theory for a single polymer chain is derived as the lowest order of a cumulant expansion. In this approach, the full original Flory free energy (including the logarithmic term), is recovered. %This term does not change the…
A Flory theory is constructed for a long polymer ring in a melt of unknotted and non-concatenated rings. The theory assumes that the ring forms an effective annealed branched object and computes its primitive path. It is shown that the…
Many water soluble polymers are chemically modified versions of insoluble base materials such as cellulose. A Flory-Huggins model is solved to determine the effects of heterogeneity in modification on the solubility of such polymers. It is…
We construct Hamiltonian Floer complexes associated to continuous, and even lower semi-continuous, time dependent exhaustion functions on geometrically bounded symplectic manifolds. We further construct functorial continuation maps…
The Flory-Huggins theory is a well-established lattice model that is commonly used to study the mixing of distinct chemical species. It can successfully predict phase separation phenomena in blends of incompatible materials. However, it is…
The wandering exponent $\nu$ for an isotropic polymer is predicted remarkably well by a simple argument due to Flory. By considering oriented polymers living in a one-parameter family of background tangent fields, we are able to relate the…
We consider the micellization of block copolymers in solution, employing self consistent field theory with an additional constraint that permits the examination of intermediate structures. From the information for an isolated micelle…
The interfacial structure formed in thermoreversible associating polymer solutions is studied within the density functional approach based on Flory's arguments of tree-like configurations of cluster associations. The unique characteristics…
The theory of multiphase polymer systems has a venerable tradition. The 'classical' theory of polymer demixing, the Flory-Huggins theory, was developed already in the forties of the last century. It is still the starting point for most…
A simple analytic theory for mixtures of hard spheres and larger polymers with excluded volume interactions is developed. The mixture is shown to exhibit extensive immiscibility. For large polymers with strong excluded volume interactions,…
Proteins, chain molecules of amino acids, behave in ways which are similar to each other yet quite distinct from standard compact polymers. We demonstrate that the Flory theorem, derived for polymer melts, holds for compact protein native…
An important goal of self-assembly is to achieve a preprogrammed structure with high fidelity. Here, we control the valence of DNA-functionalized emulsions to make linear and branched model polymers, or `colloidomers'. The distribution of…
A self consistent field theory for compressible polymer mixtures is developed by introducing elements of classical density functional theory into the framework of the Helfand theory. It is then applied to study free surfaces of binary (A,B)…
Polymer mixtures fractionate between phases depending on their molecular weight. Consequently, by varying solvent conditions, a polydisperse polymer sample can be separated between phases so as to achieve a particular molecular weight…
The present paper is mainly a survey of our work arXiv:0708.4221 and arXiv:0808.2440 but it also contains the announcement of some new results. Its main purpose is to present an accessible introduction to a technique allowing efficient…
We develop layered monoidal theories -- a generalisation of monoidal theories combining formal descriptions of a system at different levels of abstraction. Via their representation as string diagrams, monoidal theories provide a graphical…
Recent developments in off-lattice self-consistent field theories for inhomogeneous complex fluids are reviewed. Particular emphasis is given to the treatment of intermolecular interactions and compressibility, to the role of fluctuations,…
These are slightly informal lecture notes intended for graduate students about the standard local theory of holomorphic foliations and vector fields. Though the material presented here is well-known some of the proofs differs slightly from…
A perturbation theory modification of the Flory-Huggins polymer solution theory is presented. The proposed perturbation equation utilizes the results by Tukur et al [J. Chem. Phys. 110 (7), 3463, 1999] for hard-sphere binary mixture at…
We construct a stable infinity category with objects flow categories and morphisms flow bimodules; our construction has many flavors, related to a choice of bordism theory, and we discuss in particular framed bordism and the bordism theory…