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A model-potential approach to calculating positron-molecule binding energies and annihilation rates is developed. Unlike existing ab initio calculations, which have mostly been applied to strongly polar molecules, the present methodology…

Atomic Physics · Physics 2018-12-31 A. R. Swann , G. F. Gribakin

A new relativistic method for calculation of positron binding to atoms is presented. The method combines a configuration interaction treatment of the valence electron and the positron with a many-body perturbation theory description of…

Atomic Physics · Physics 2009-10-31 V. A. Dzuba , V. V. Flambaum , G. F. Gribakin , C. Harabati

A model-potential approach has been developed to study positron interactions with molecules. Binding energies and annihilation rates are calculated for positron bound states with a range of alkane molecules, including rings and isomers. The…

Atomic Physics · Physics 2019-09-17 A. R. Swann , G. F. Gribakin

We determine the binding energy of the negative positronium ion in the limits of one spatial dimension and of infinitely many dimensions. The numerical result for the one-dimensional ground state energy seems to be a rational number,…

High Energy Physics - Phenomenology · Physics 2012-01-30 Nikita Blinov , Andrzej Czarnecki

Positrons bind to molecules leading to vibrational excitation and spectacularly enhanced annihilation. Whilst positron binding energies have been measured via resonant annihilation spectra for $\sim$90 molecules in the past two decades, an…

Atomic Physics · Physics 2023-03-23 J. Hofierka , B. Cunningham , C. M. Rawlins , C. H. Patterson , D. G. Green

A method is proposed for detecting positron-atom bound states by observing enhanced positron annihilation due to electronic Feshbach resonances at electron-volt energies. The method is applicable to a range of open-shell transition metal…

Atomic Physics · Physics 2010-12-10 V. A. Dzuba , V. V. Flambaum , G. F. Gribakin

The model-potential approach previously developed by the authors to study positron interactions with molecules is used to calculate the positron binding energy for $n$-alkanes (C$_n$H$_{2n+2}$) and the corresponding cycloalkanes…

Atomic Physics · Physics 2020-11-13 A. R. Swann , G. F. Gribakin

Measured and calculated positron binding energies are presented for a range of hydrocarbons with up to six carbon atoms (viz., methane, acetylene, ethylene, ethane, propane, butane, and hexane) and their chlorinated counterparts. Both…

Atomic Physics · Physics 2021-07-27 A. R. Swann , G. F. Gribakin , J. R. Danielson , S. Ghosh , M. R. Natisin , C. M. Surko

The binding energies of the excited states of positronium are calculated using the two body Dirac equations of constraint formalism. The results from nonperturbative evaluation are compared to those from perturbative evaluation. The…

High Energy Physics - Phenomenology · Physics 2026-04-14 Robert W. Johnson

Positron binding to silver and gold atoms was studied using a fully {\it ab initio} relativistic method, which combines the configuration interaction method with many-body perturbation theory. It was found that the silver atom forms a bound…

Atomic Physics · Physics 2009-11-06 V. A. Dzuba , V. V. Flambaum , C. Harabati

A model for positron binding to polar molecules is considered by combining the dipole potential outside the molecule with a strongly repulsive core of a given radius. Using existing experimental data on binding energies leads to…

Atomic Physics · Physics 2015-09-24 G. F. Gribakin , A. R. Swann

Annihilation spectra are presented for aromatic and heterocyclic ring molecules resolved as a function of incident positron energy using a trap-based positron beam. Comparisons with the vibrational mode spectra yield positron-molecule…

Positron binding in parabenzoquinone is studied using \textit{ab initio} many-body theory. The effects of electron-positron correlations including polarization, virtual positronium formation and positron-hole repulsion, as well as those of…

Chemical Physics · Physics 2025-02-17 S. K. Gregg , J. Hofierka , B. Cunningham , D. G. Green

Positron binding energies in the negative ions H$^-$, F$^-$, Cl$^-$ and Br$^-$, and the closed-shell atoms Be, Mg, Zn and Ca, are calculated via a many-body theory approach developed by the authors [J.~Hofierka \emph{et al.} Nature~{\bf…

Atomic Physics · Physics 2023-11-23 J. Hofierka , B. Cunningham , C. M. Rawlins , C. H. Patterson , D. G. Green

An effective theory of the excited states of positronium is derived and some of its consequences are explored. At large physical separation, the binding of the electron and positron is assumed to be described completely by QED, whereas all…

High Energy Physics - Phenomenology · Physics 2022-06-07 David M. Jacobs

The aim of this work is to identify the mechanisms responsible for very large rates and other peculiarities observed in low-energy positron annihilation on molecules. The two mechanisms considered are: (i) Direct annihilation of the…

Atomic Physics · Physics 2009-10-31 G. F. Gribakin

Positronium annihilation amplitudes that are computed by assuming a factorization approximation with on-shell intermediate leptons, do not exhibit good analytical behavior. We propose an ansatz which allows to include binding energy…

High Energy Physics - Phenomenology · Physics 2007-05-23 G. Lopez Castro , J. Pestieau , C. Smith

A many-body theory approach developed by the authors [Phys. Rev. A 70, 032720 (2004)] is applied to positron bound states and annihilation rates in atomic systems. Within the formalism, full account of virtual positronium (Ps) formation is…

Atomic Physics · Physics 2014-11-20 J. A. Ludlow , G. F. Gribakin

We consider a gas of N weakly interacting bosons in the ground state. Such gases exhibit Bose-Einstein condensation. The binding energy is defined as the energy it takes to remove one particle from the gas. In this article, we prove an…

Mathematical Physics · Physics 2024-05-09 Lea Boßmann , Nikolai Leopold , David Mitrouskas , Sören Petrat

We demonstrate that the model of zero-range potentials can be successfully employed for the description of attached electrons in atomic and molecular anions, for example, negatively charged carbon clusters. To illustrate the capability of…

Atomic and Molecular Clusters · Physics 2023-01-13 Arkadiy S. Baltenkov , Igor Woiciechowski
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