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Water electrolysis performed in microsystems with a fast change of voltage polarity produces optically invisible nanobubbles containing H2 and O2 gases. In this form the gases are able to the reverse reaction of water formation. Here we…

Soft Condensed Matter · Physics 2017-01-20 A. V. Postnikov , I. V. Uvarov , M. V. Lokhanin , V. B. Svetovoy

Water electrolysis in a microsystem is observed and analyzed on a short-time scale ~10 us. Very unusual properties of the process are stressed. An extremely high current density is observed because the process is not limited by the…

Soft Condensed Matter · Physics 2013-07-18 Vitaly B. Svetovoy , Remco G. P. Sanders , Miko C. Elwenspoek

Microdischarges formed in bubbles immersed in liquids are of interest for materials synthesis and chemical conversion applications in the frame of plasma-driven electrochemistry. A key challenge associated with controlling such processes is…

Understanding how bubbles influence the efficiency of water electrolysis is crucial to achieve economically competitive hydrogen, generated by renewable energy sources, such as wind and solar power. Water electrolysis is typically performed…

Electrolytically generated gas bubbles can significantly hamper the overall electrolysis efficiency. Therefore it is crucial to understand their dynamics in order to optimise water electrolyzer systems. Here we demonstrate a distinct…

In water electrolysis, bubbles form on the electrode and interact through processes such as collision and coalescence. However, the impact of bubble coalescence a fundamental process governing electrolytic bubble behaviour-on electrolysis…

Chemical Physics · Physics 2024-11-06 Tao Wu , Bo Liu , Haohao Hao , Fang Yuan , Yu Zhang , Huanshu Tan , Qiang Yang

Spatially resolved electron energy-loss spectroscopy (EELS) in a scanning transmission electron microscope (STEM) has been used to investigate as fluidic phase in nanoubbles embedded in a metallic Pd90Pt10 matrix. Using the 1s->2p…

Materials Science · Physics 2016-08-14 D. Taverna , M. Kociak , O. Stéphan , A. Fabre , E. Finot , B. Décamps , C. Colliex

The effects of a pulsed low frequency electromagnetic field were investigated on photoluminescence of well characterized water and prepared under controlled conditions (container, atmospheric, electromagnetic, and acoustic environments).…

Chemical Physics · Physics 2016-08-16 Philippe Vallée , Jacques Lafait , Pascale Mentré , Marie-Odile Monod , Yolène Thomas

Bubbles are known to influence energy and mass transfer in gas evolving electrodes. However, we lack a detailed understanding on the intricate dependencies between bubble evolution processes and electrochemical phenomena. This review…

Soft Condensed Matter · Physics 2020-02-20 Andrea Angulo , Peter van der Linde , Han Gardeniers , Miguel Modestino , David Fernández Rivas

The evolution of electrogenerated gas bubbles during water electrolysis can significantly hamper the overall process efficiency. Promoting the departure of electrochemically generated bubbles during (water) electrolysis is therefore…

Enhancing the efficiency of water electrolysis, which can be severely impacted by the nucleation and growth of bubbles, is key in the energy transition. In this combined experimental and numerical study, in-situ bubble evolution and…

The formation, growth and detachment of gas bubbles on electrodes are omnipresent in electrolysis and other gas-producing chemical processes. To better understand their role in the mass transfer efficiency, we perform experiments involving…

A surprising phenomenon is presented: a bubble, produced from water electrolysis, is immobilized in the liquid (as if the Archimedes' buoyant force were annihilated). This is achieved using a nanoelectrode (1 nm to 1 $\mu$m of curvature…

Soft Condensed Matter · Physics 2017-02-07 Z Hammadi , L Lapena , R Morin , J Olives

We develop and implement numerically a phase field model for the growth and detachment of a gas bubble resting on an electrode and being filled with hydrogen produced by water electrolysis. The bubble is surrounded by a viscous liquid, has…

Soft Condensed Matter · Physics 2025-12-19 Carlos Uriarte , Marco A. Fontelos , Manuel Arrayás

A novel 3-electrode cell type is introduced to run parametrical studies of H$_2$ evolution in an alkaline electrolyte on porous electrodes. Electrochemical methods combined with a high-speed optical measurement system are applied…

A simple model of water nanoelectrolysis-defined as the nanolocalization at a single point of any electrolysis phenomenon-is presented. It is based on the electron tunneling assisted by the electric field through the thin film of water…

Chemical Physics · Physics 2019-04-25 Juan Olives , Zoubida Hammadi , Roger Morin , Laurent Lapena

The dynamics of hydrogen bubbles produced by water electrolysis in an acidic electrolyte are studied using electrochemical and optical methods. A defined cyclic modulation of the electric potential is applied at a microelectrode to produce…

Determining the nature of surface roughness and electrode pore structure on H2 bubble evolution rate and quantity, and bubble trapping under electrolytic conditions is important for quantifying useful gas production during total water…

Materials Science · Physics 2025-12-19 Matthew Ferguson , Alex Lonergan , Christopher Kent , Dara Fitzpatrick , Colm O'Dwyer

Recently, we demonstrated that the local heating of degassed water can generate water vapor microbubbles and induce a rapid flow around the bubble. Although flow generation involves the self-excited oscillation of bubbles at a local heating…

Fluid Dynamics · Physics 2024-05-21 Nao Hiroshige , Shunsuke Okai , Xuanwei Zhang , Samir Kumar , Kyoko Namura , Motofumi Suzuki

Direct numerical simulations are utilised to investigate mass transfer processes at gas-evolving electrodes that experience successive formation and detachment of bubbles. The gas-liquid interface is modeled employing an Immersed Boundary…

Fluid Dynamics · Physics 2023-10-23 Farzan Sepahi , Roberto Verzicco , Detlef Lohse , Dominik Krug
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