Related papers: Dissipative work, Clausius inequality, and microsc…
For a two-level quantum mechanical system, we derive microscopically the exact expression for the fluctuation of microscopic work in a multi-step non-equilibrium process, and we rigorously prove that in an isothermal process, the…
Kawai, Parrondo, and Van den Broeck [Phys. Rev. Lett. 98, 080602 (2007)] have recently established a quantitative relationship between dissipated work and a microscopic, information-theoretic measure of irreversibility. We illustrate this…
Time-dependent density functional theory is extended to include dissipative systems evolving under a master equation, providing a Hamiltonian treatment for molecular electronics. For weak electric fields, the isothermal conductivity is…
Diffusive motion in an externally driven potential is considered. It is shown that the distribution of work required to drive the system from an initial equilibrium state to another is Gaussian for slow but finite driving. Our result is…
Clausius inequality has deep implications for reversibility and the arrow of time. Quantum theory is able to extend this result for closed systems by inspecting the trajectory of the density matrix on its manifold. Here we show that this…
The work content of non-equilibrium systems in relation to a heat bath is often analyzed in terms of expectation values of an underlying random work variable. However, we show that when optimizing the expectation value of the extracted…
We illustrate recent results concerning the validity of the work fluctuation theorem in open quantum systems [M. Campisi, P. Talkner, and P. H\"{a}nggi, Phys. Rev. Lett. {\bf 102}, 210401 (2009)], by applying them to a solvable model of an…
We study the statistics of work, dissipation, and entropy production of a quantum quasi-isothermal process, where the system remains close to the thermal equilibrium along the transformation. We derive a general analytic expression for the…
Previously derived expressions for the characteristic function of work performed on a quantum system by a classical external force are generalized to arbitrary initial states of the considered system and to Hamiltonians with degenerate…
Recently, the concept of minimal dissipation has been brought forward as a means to define work performed on open quantum systems [Phys. Rev. A 105, 052216 (2022)]. We discuss this concept from the point of view of projection operator…
Two recent topics on a formal thermodynamic analogy of intracellular diffusivity fluctuations observed experimentally in normal/anomalous diffusion are reported. Not only the analogs of the quantity of heat and work as well as the internal…
By generalizing the traditional concept of heat dQ and work dW to also include their time-dependent irreversible components d_{i}Q and d_{i}W allows us to express them in terms of the instantaneous internal temperature T(t) and pressure…
Recently, Kawai, Parrondo, and Van den Broeck have related dissipation to time-reversal asymmetry. We generalized the result by considering a protocol where the physical system is driven away from an initial thermal equilibrium state with…
In the context of driven diffusive systems, for thermodynamic transformations over a large but finite time window, we derive an expansion of the energy balance. In particular, we characterize the transformations which minimize the energy…
We develop a general theory describing the thermodynamical behavior of open quantum systems coupled to thermal baths beyond perturbation theory. Our approach is based on the exact time-local quantum master equation for the reduced open…
The decomposition of the energy of a compressible fluid parcel into slow (deterministic) and fast (stochastic) components is interpreted as a stochastic Hamiltonian interacting particle system (HIPS). It is shown that the McKean-Vlasov…
The study of thermodynamic fluctuations allows one to relate the free energy difference between two equilibrium states with the work done on a system through processes far from equilibrium. This finding plays a crucial role in the quantum…
The second law of thermodynamics is a fundamental law of Nature. It is almost universally associated with the Clausius inequality that lower bounds a change in entropy by the ratio of supplied heat and temperature. However, this result…
Dissipative adaptation is a general thermodynamic mechanism that explains self-organization in a broad class of driven classical many-body systems. It establishes how the most likely (adapted) states of a system subjected to a given drive…
Analytical work probability distributions for open classical systems are scarce; they can only be calculated in a few examples. In this work, I present a new method to derive such quantities for weakly driven processes in the overdamped…