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As an aid to the development of hydrogen separation membranes, we predict the temperature dependent phase diagrams using first principles calculations combined with thermodynamic principles. Our method models the phase diagram without…

Materials Science · Physics 2014-08-07 William Paul Huhn , Michael Widom , Michael C. Gao

We propose a dynamical mean field approach for calculating the electronic structure of strongly correlated materials from first principles. The scheme combines the GW method with dynamical mean field theory, which enables one to treat…

Strongly Correlated Electrons · Physics 2009-11-07 S. Biermann , F. Aryasetiawan , A. Georges

Using first-principles calculations, we analyze the structural properties of tungsten trioxide WO3 . Our calculations rely on density functional theory and the use of the B1-WC hybrid functional, which provides very good agreement with…

Materials Science · Physics 2016-12-28 Hanen Hamdi , Ekhard K. H. Salje , Philippe Ghosez , Eric Bousquet

Halide perovskites have been extensively studied as materials of interest for optoelectronic applications. There is a major emphasis on ways to tailor the stability, defect behavior, electronic band structure, and optical absorption in…

Materials Science · Physics 2023-09-29 Jiaqi Yang , Arun Mannodi-Kanakkithodi

Transition metal oxides belong to a genre of quantum materials essential for the exploration of theoretical methods for quantifying electronic correlation. Finding an efficient and accurate first principles method for the assertion of such…

Materials Science · Physics 2025-08-13 Suvadip Das

First principles electronic structure calculations, based upon density functional theory within the generalized gradient approximation and ultra-soft Vanderbilt pseudopotentials, have been used to simulate a liquid alloy of iron and sulfur…

Condensed Matter · Physics 2009-10-31 Dario Alfe` , Michael J. Gillan

Flexoelectricity, inherent in all materials, offers a promising alternative to piezoelectricity for nanoscale actuation and sensing. However, its widespread application faces significant challenges: differentiating flexoelectric effects…

Materials Science · Physics 2024-09-23 Daniel Moreno-Garcia , Kaitlin M. Howell , Luis Guillermo Villanueva

The principles of the thermoelectric phenomenon, including Seebeck effect, Peltier effect, and Thomson effect are discussed. The dependence of the thermoelectric devices on the figure of merit, Seebeck coefficient, electrical conductivity,…

Materials Science · Physics 2017-06-29 Ibrahim M Abdel-Motaleb , Syed M. Qadri

Experiments on rare-earth filled skutterudites demonstrate an intriguing array of thermodynamic, transport and superconducting properties, and bring to fore theoretical challenges posed by f-electron systems. First principle calculations…

Strongly Correlated Electrons · Physics 2019-09-11 Gheorghe Lucian Pascut , Michael Widom , Kristjan Haule , Khandker F. Quader

The structural, electronic, elastic and optical properties of tetragonal (P4mm) phase of Pb0.5Sn0.5TiO3 (PSTO) and Pb0.5Sn0.5Ti0.5(Zr0.5)O3 (PSTZO) are examined by first-principles calculations based on the density functional theory (DFT)…

Materials Science · Physics 2021-03-30 S. G. Kuma , M. M. Woldemariam

We perform all-electron path integral Monte Carlo (PIMC) and density functional theory molecular dynamics (DFT-MD) calculations to explore warm dense matter states of oxygen. Our simulations cover a wide density-temperature range of…

Plasma Physics · Physics 2016-01-22 K. P. Driver , F. Soubiran , Shuai Zhang , B. Militzer

This paper gives a short overview of the calculation of thermal properties of materials from first principles, using the Quasi-Harmonic Approximation (QHA). We first introduce some of the thermal properties of interest and describe how they…

Materials Science · Physics 2011-12-22 Stefano Baroni , Paolo Giannozzi , Eyvaz Isaev

Piezoelectricity usually accompanies with flexoelectricity in polar materials which is the linear response of polarization to a strain gradient. Therefore, it is hard to eliminate piezoelectric effect in determination of pure flexoelectric…

Materials Science · Physics 2021-03-08 Yingzhuo Lun , Hao Zhou , Di Yao , Xueyun Wang , Jiawang Hong

Spin fluctuations have a substantial influence on the electron and lattice behaviors in magnetic materials, which, however, is difficult to be tracked properly by prevalent first-principles methods. We propose a versatile self-adaptive…

Materials Science · Physics 2023-02-14 Zefeng Cai , Ke Wang , Yong Xu , Su-Huai Wei , Ben Xu

One of the central challenges in materials science is the design of functional and multifunctional materials, in which large responses are produced by applied fields and stresses. A rapidly developing paradigm for the rational design of…

Materials Science · Physics 2013-05-30 Anindya Roy , Joseph W. Bennett , Karin M. Rabe , David Vanderbilt

Using a combination of first-principles simulations, based on the density functional theory and Boltzmann's semiclassical theory, we have calculated the transport and thermoelectric properties of the half-metallic two dimensional electron…

Fabrication, handling and disposal of nuclear fuel materials require comprehensive knowledge of their surface morphology and reactivity. Due to unavoidable contact with air components (even at low partial pressures), UN samples contain…

Materials Science · Physics 2010-09-01 Yuri F. Zhukovskii , Dmitry Bocharov , Eugene Kotomin , Robert Evarestov , Andrey V. Bandura

First-principles calculations have been conducted to study the structural, vibrational and dielectric properties of {\beta}-Si3N4. Calculations of the zone-center optical-mode frequencies (including LO-TO splittings), Born effective charge…

Materials Science · Physics 2015-05-28 Yongqing Cai , Qingfeng Zeng , Litong Zhang , Laifei Cheng , Yongdong Xu

In this study, an efficient first-principles approach for calculating the thermodynamic properties of mixed metal oxides at high temperatures is demonstrated. More precisely, this procedure combines density functional theory and harmonic…

Materials Science · Physics 2023-05-12 Joakim Brorsson , Ivana Staničić , Jonatan Gastaldi , Tobias Mattison , Anders Hellman

The solubility and diffusivity of hydrogen in disordered Pd1-xCux alloys are investigated using a combination of first-principles calculations, a composition-dependent local cluster expansion (CDLCE) technique, and kinetic Monte Carlo…

Materials Science · Physics 2012-04-23 Lin Qin , Chao Jiang