Related papers: Physicochemical Effects in Aging Aqueous Laponite …
We use molecular dynamics simulations to study the behavior of supercooled water subject to different stimuli from a diluted azobenzene hydrophobic probe. When the molecular motor does not fold, it acts as a passive probe, modifying the…
We experimentally study the effects of salt concentration on the flowing dynamics of dense suspensions of micrometer-sized silica particles in microfluidic drums. In pure water, the particles are fully sedimented under their own weight, but…
The microscopic dynamics of spontaneously aged and rejuvenated glassy Laponite is investigated through X-ray photon correlation spectroscopy. Two different behaviours of the intensity autocorrelation functions are observed depending on the…
The influence of temperature on interfacial fluid slip, as measured by molecular-dynamics simulations of a Couette flow comprising a Lennard-Jones fluid and rigid crystalline walls, is examined as a function of the fluid-solid interaction…
Complex fluids exhibit time-dependent changes in viscosity that have been ascribed to both thixotropy and aging. However, there is no consensus for which phenomenon is the origin of which changes. A novel thixotropic model is defined that…
One of the challenges in the widespread use of biocomposites for engineering applications is the influence of environmental conditions on their mechanical properties, particularly for a combination of aging factors such as temperature,…
Understanding the correlation between structure and rheology in colloidal suspensions is important as these suspensions are crucial in industrial applications. Moreover, colloids exhibit a wide range of structures under confinement that…
We explore the origins of slow dynamics, aging and glassy rheology in soft and living matter. Non-diffusive slow dynamics and aging in materials characterised by crowding of the constituents can be explained in terms of structural…
We present a molecular dynamics study of the effects of confinement on the lubrication and flow properties of ionic liquids. We use a coarse-grained salt model description of ionic liquid as a lubricant confined between finite solid plates…
We study the aging of colloidal gels using light microscopy movies of depletion gels from the International Space Station. Under such microgravity conditions, we observe a slowdown in particle dynamics consistent with gel aging. Stronger…
We use state-of-the-art molecular dynamics simulations to study hydrodynamic effects on aging during kinetics of phase separation in a fluid mixture. The domain growth law shows a crossover from a diffusive regime to a viscous hydrodynamic…
Colloidal models with short-range attraction and long range repulsion (SALR) have been extensively studied using theoretical and simulations methods due to their rich and universal equilibrium phase behavior. Using Brownian Dynamics…
In the first paper of this series (Paper I) we computed time dependent simulations of multifluid shocks with chemistry and a transverse magnetic field frozen in the ions, using an adaptive moving grid. In this paper, we present new…
Shear localization in an aqueous clay suspension of Laponite is investigated through dynamic light scattering, which provides access both to the dynamics of the system (homodyne mode) and to the local velocity profile (heterodyne mode).…
The dynamics of the interaction of a system of two thin volatile liquid droplets resting on a soft viscoelastic solid substrate are investigated theoretically. The developed model fully considers the effect of evaporative cooling and the…
We observe non-monotonic aging and memory effects, two hallmarks of glassy dynamics, in two disordered mechanical systems: crumpled thin sheets and elastic foams. Under fixed compression, both systems exhibit monotonic non-exponential…
Effects of substrate temperature, substrate wettability and particles concentration are experimentally investigated for evaporation of a sessile water droplet containing colloidal particles. Time-varying droplet shapes and temperature of…
Using first-principles approaches we investigate local heating and the inelastic contribution to the current for various alkanethiols sandwiched between metal electrodes. In the absence of good heat dissipation into the bulk electrodes, we…
In a binary fluid mixture, the concentration gradient of a heavier molecular solute leads to a diffusive flux of solvent and solute to achieve thermodynamic equilibrium. If the solute concentration decreases with height, the system is…
Salt is a very common molecule in aqueous environments but the question of whether the interactions of monovalent ions Na^+ and Cl^- ,with the neutral heads of phospholipids are impactful enough to change the membrane rigidity is still a…