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The description of excited state dynamics in multichromophoric systems constitutes both a theoretical and experimental challenge in modern physical chemistry. An experimental protocol which can systematically characterize both coherent and…

Quantum Physics · Physics 2011-10-31 Joel Yuen-Zhou , Jacob J. Krich , Masoud Mohseni , Alán Aspuru-Guzik

Quantum synchronisation has recently been proposed as a mechanism for electronic excitation energy transfer in light-harvesting complexes, yet its robustness in driven-dissipative settings remains under active investigation. Here, we…

Biological Physics · Physics 2026-01-30 Wenhao Xu

We study direct energy transfer by multipolar or exchange interactions between diffusive excited donor and diffusive unexcited acceptors. Extending over the case of long-range transfer of an excitation energy a non-perturbative approach by…

Statistical Mechanics · Physics 2010-04-07 G. Oshanin , M. Tachiya

It is demonstrated that the properties of light stored in a four-level atomic system can be modified by an additional control interaction present during the storage stage. By choosing the pulse area of this interaction one can in particular…

Quantum Physics · Physics 2009-11-07 A. Raczynski , J. Zaremba , S. Zielinska-Kaniasty

Is it possible to infer the time evolving quantum state of a multichromophoric system from a sequence of two-dimensional electronic spectra (2D-ES) as a function of waiting time? Here we provide a positive answer for a tractable model…

Quantum Physics · Physics 2015-05-27 Joel Yuen-Zhou , Alán Aspuru-Guzik

There are two types of two-photon transitions in molecular aggregates, that is, non-local excitations of two monomers and local double excitations to some higher excited intra-monomer electronic state. As a consequence of the inter-monomer…

Quantum Physics · Physics 2015-06-04 Yun-an Yan , Oliver Kühn

We theoretically study pump-photon-energy-dependent pathways of a photoinduced dimer-Mott-insulator-to-metal transition, on the basis of numerical solutions to the time-dependent Schr\"odinger equation for the exact many-body wave function…

Strongly Correlated Electrons · Physics 2015-05-28 Kenji Yonemitsu , Satoshi Miyashita , Nobuya Maeshima

Optical control is achieved on the excited state energy transfer between spatially separated donor and acceptor molecules, both coupled to the same optical mode of a cavity. The energy transfer occurs through the formed hybrid polaritons…

We study theoretically the optical response of a nanohybrid comprising a symmetric quantum dimer emitter coupled to a metal nanoparticle (MNP). The interactions between the exitonic transitions in the dimer and the plasmons in the MNP lead…

Mesoscale and Nanoscale Physics · Physics 2015-11-11 Bintoro S. Nugroho , Victor A. Malyshev , Jasper Knoester

From studying the time evolution of the single electron density matrix within a density functional tight-binding formalism we study in a fully atomistic picture the electronic excitation transfer between two photosynthetic pigments in real…

Chemical Physics · Physics 2015-02-03 María Belén Oviedo , Cristián G. Sánchez

We consider directed polymers in 1+1 spatial dimension under action of an external repulsive potential along a line. Using the exact mapping onto imaginary time evolution of free fermions we find that for sufficiently strong potential the…

Statistical Mechanics · Physics 2024-05-22 James S. Pallister , Samuel H. Pickering , Dimitri M. Gangardt , Alexander G. Abanov

The low-energy dynamical optical response of dimerized and undimerized spin liquid states in a one-dimensional charge transfer Mott insulator is theoretically studied. An exact analysis is given for the low-energy asymptotic behavior using…

Strongly Correlated Electrons · Physics 2009-10-23 Hosho Katsura , Masahiro Sato , Takashi Furuta , Naoto Nagaosa

Energy transfer between quantum systems can either be achieved through an effective unitary interaction or through the generation of entanglement. This observation defines two types of energy exchange: unitary and correlation energy. Here…

We investigate the power dissipated by an electronic current flowing through a quantum point contact in a two-dimensional electron gas. Based on the Landauer-B\"uttiker approach to quantum transport, we evaluate the power that is dissipated…

Mesoscale and Nanoscale Physics · Physics 2022-03-30 Carmen Blaas-Anselmi , Félix Helluin , Rodolfo A. Jalabert , Guillaume Weick , Dietmar Weinmann

We demonstrate for the first time coherent control of bond making, a milestone on the way to coherent control of photo-induced bimolecular chemical reactions. In strong-field multiphoton femtosecond photoassociation experiments, we find the…

Electron transfer (ET) in molecular donor-acceptor dye systems is crucial for charge transport in organic semiconductors. Classically, ET rates should decrease with increasing donor-acceptor distance while the microscopic mechanism is more…

We introduce a protocol for dynamical dispersion engineering in an atomic chain consisting of an ordered array of multi-level atoms with subwavelength lattice constant. This chain supports dark states that are protected from dissipation in…

Quantum Physics · Physics 2022-04-15 R. Gutiérrez-Jáuregui , A. Asenjo-Garcia

Electronic excitation energy transfer along a molecular wire depends on the relative orientation of the electronic transition dipole moments of neighboring chromophores. In porphycenes this orientation is changed upon double proton transfer…

Chemical Physics · Physics 2010-10-28 Mahmoud K. Abdel-Latif , Oliver Kuehn

In this paper we consider the essential electronic excited states in parallel chains of semiconducting polymers that are currently being explored for photovoltaic and light-emitting diode applications. In particular, we focus upon various…

Materials Science · Physics 2009-11-11 Eric R. Bittner , John Glenn Santos Ramon , Stoyan Karabunarliev

The induction of dc electronic transport in rigid and flexible trans-polyacetylene oligomers according to the $\omega$ vs. $2\omega$ coherent control scenario is investigated using a quantum-classical mean field approximation. The approach…

Quantum Physics · Physics 2009-11-13 Ignacio Franco , Moshe Shapiro , Paul Brumer