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Related papers: Beyond the random phase approximation: Improved de…

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The status of different extensions of the Random Phase Approximation (RPA) is reviewed. The general framework is given within the Equation of Motion Method and the equivalent Green's function approach for the so-called Self-Consistent RPA…

Nuclear Theory · Physics 2021-08-25 P. Schuck , D. S. Delion , J. Dukelsky , M. Jemai , E. Litvinova , G. Roepke , M. Tohyama

We have calculated the correlation energy of the homogeneous electron gas (HEG) and the dissociation energy curves of molecules with covalent bonds from a novel implementation of the adiabatic connection fluctuation dissipation (ACFD)…

Strongly Correlated Electrons · Physics 2015-06-22 Nicola Colonna , Maria Hellgren , Stefano de Gironcoli

We present a detailed semiclassical study on the propagation of a pair of optical fields in resonant media with and without adiabatic approximation. In the case of near and on resonance excitation, we show detailed calculation, both…

Quantum Physics · Physics 2009-11-07 M. G. Payne , L. Deng , Chris Schmitt , Shannon Anderson

For revDSD double hybrids, the G\"orling-Levy second-order perturbation theory component is an Achilles' Heel when applied to systems with significant near-degeneracy ("static") correlation. We have explored its replacement by the direct…

Chemical Physics · Physics 2021-06-10 Golokesh Santra , Emmanouil Semidalas , Jan M. L. Martin

The particle-particle random phase approximation (pp-RPA) has been shown to be capable of describing double, Rydberg, and charge transfer excitations, for which the conventional time-dependent density functional theory (TDDFT) might not be…

Computational Physics · Physics 2017-04-26 Jianfeng Lu , Haizhao Yang

The relativistic mean field approach (RMF) is well known for describing accurately binding energies and nucleon distributions in atomic nuclei throughout the nuclear chart. The random phase approximation (RPA) built on top of the RMF is…

Nuclear Theory · Physics 2008-11-26 Nguyen Van Giai , Haozhao Liang , Jie Meng

The effects of the correlations in the ground state of $^{16}$O on the octupole and dipole excitations are studied using the extended random phase approximation (ERPA) derived from the time-dependent density-matrix theory. It is found that…

Nuclear Theory · Physics 2015-06-15 Mitsuru Tohyama

In non-self-consistent calculations of the total energy within the random-phase approximation (RPA) for electronic correlation, it is necessary to choose a single-particle Hamiltonian whose solutions are used to construct the electronic…

Materials Science · Physics 2016-01-28 Christopher E. Patrick , Kristian S. Thygesen

We investigate static correlation and delocalization errors in the self-consistent GW and random-phase approximation (RPA) by studying molecular dissociation of the H_2 and LiH molecules. Although both approximations contain topologically…

Strongly Correlated Electrons · Physics 2015-04-10 Maria Hellgren , Fabio Caruso , Daniel R. Rohr , Xinguo Ren , Angel Rubio , Matthias Scheffler , Patrick Rinke

We revisit the connection between equation-of-motion coupled cluster (EOM-CC) and random phase approximation (RPA) explored recently by Berkelbach [J. Chem. Phys. 149, 041103 (2018)] and unify various methodological aspects of these diverse…

Chemical Physics · Physics 2020-12-17 Varun Rishi , Ajith Perera , Rodney J. Bartlett

The iterative quasi-particle-random-phase approximation (QRPA) method we previously developed to accurately calculate properties of individual nuclear states is extended so that it can be applied for nuclei with odd numbers of neutrons and…

Nuclear Theory · Physics 2014-06-03 B. G. Carlsson , J. Toivanen

It is known that the adiabatic approximation in time-dependent density functional theory usually provides a good description of low-lying excitations of molecules. In the present work, the capability of the adiabatic nonempirical…

Materials Science · Physics 2009-11-13 Jianmin Tao , Sergei Tretiak , Jian-Xin Zhu

We recently introduced an efficient methodology to perform density-corrected Hartree-Fock density functional theory (DC(HF)-DFT) calculations and an extension to it we called "corrected" HF DFT (C(HF)-DFT). In this work, we take a further…

Chemical Physics · Physics 2023-11-10 Daniel Graf , Alex J. W. Thom

We develop a novel and powerful method of exactly calculating various transport characteristics of waves in one-dimensional random media with (or without) coherent absorption or amplification. Using the method, we compute the probability…

Disordered Systems and Neural Networks · Physics 2009-10-31 Kihong Kim

The direct ring coupled-cluster doubles (drCCD)-based random phase approximation (RPA) has provided an attractive framework for the development and application of RPA-related methods. However, a potential unphysical solution issue recently…

Chemical Physics · Physics 2025-08-18 Ruiheng Song , Xiliang Gong , Hong-Zhou Ye

We present an accurate local density-functional for electronic-structure calculations within the density functional theory (DFT). The functional is derived by analyzing the structure of the standard perturbative expansion of the correlation…

Materials Science · Physics 2024-11-28 Mario Benites , Angel Rosado , Efstratios Manousakis

Starting from the Random Phase Approximation (RPA), we generalize the schematic model of separable interaction defning subspaces of ph excitations with different coupling constants between them. This ansatz simplifies the RPA eigenvalue…

Atomic and Molecular Clusters · Physics 2016-08-24 D. I. Palade , V. Baran

The development and first applications of a new periodic energy decomposition analysis (pEDA) scheme for extended systems based on the Kohn-Sham approach to density functional theory are described. The pEDA decomposes the binding energy…

Chemical Physics · Physics 2015-05-19 Marc Raupach , Ralf Tonner

We construct a reference benchmark set for atomic and molecular random-phase-approximation (RPA) correlation energies in a density functional theory (DFT) framework at the complete basis set limit. This set is used to evaluate the accuracy…

Chemical Physics · Physics 2013-02-22 E. Fabiano , F. Della Sala

Time-dependent density-functional theory (TDDFT) treats dynamical exchange and correlation (xc) via a single-particle potential, Vxc(r,t), defined as a nonlocal functional of the density n(r',t'). The popular adiabatic local-density…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 C. A. Ullrich , I. V. Tokatly
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