Related papers: Hexagonal patterns in a simplified model for block…
Using exact enumeration methods and Monte Carlo simulations we study the phase diagram relative to the conformational transitions of a two dimensional diblock copolymer. The polymer is made of two homogeneous strands of monomers of…
Very few works exist to date on development of a consistent energy-based coupling of atomistic and continuum models of materials in more than one dimension. The difficulty in constructing such a coupling consists in defining a coupled…
In this work, we study the effective behavior of a two-dimensional variational model within finite crystal plasticity for high-contrast bilayered composites. Precisely, we consider materials arranged into periodically alternating thin…
The ability to tune the microstructures formed by block copolymers using accessible physical approaches provides control for practical material applications. A common strategy involves the addition of homopolymers, which can induce…
Long range order and symmetry in heterogeneous materials architected on crystal lattices lead to elastic and inelastic anisotropies and thus limit mechanical functionalities in particular crystallographic directions. Here, we present a…
We study a two-dimensional ternary inhibitory system derived as a sharp-interface limit of the Nakazawa-Ohta density functional theory of triblock copolymers. This free energy functional combines an interface energy favoring micro-domain…
A justification of heterogeneous membrane models as zero-thickness limits of a cylindral three-dimensional heterogeneous nonlinear hyperelastic body is proposed in the spirit of Le Dret & Raoult. Specific characterizations of the 2D elastic…
The microphase separated morphology of a melt of a specific class of comb-coil diblock copolymers, consisting of an AB comb block and a linear homopolymer A block, is analyzed in the weak segregation limit. On increasing the length of the…
We describe the asymptotic behaviour of the minimal inhomogeneous two-capacity of small sets in the plane with respect to a fixed open set $\Omega$. This problem is governed by two small parameters: $\varepsilon$, the size of the inclusion…
We study the conformational properties of complex polymer macromolecules, consisting in general of $n$ subsequently connected chains (blocks) of different lengths and distinct chemical structure. Depending on the solvent conditions, the…
We consider the phase behavior of two-dimensional ($2D$)system of particles with an isotropic core-softened potential introduced in our previous publications. As one can expect from the qualitative consideration for the three dimensional…
We investigate ground state configurations of atomic systems in two dimensions interacting via short range pair potentials. As the number of particles tends to infinity, we show that low-energy configurations converge to a macroscopic…
We numerically investigate local defectiveness control of self-assembled diblock copolymer patterns through appropriate substrate design. We use a nonlocal Cahn-Hilliard (CH) equation for the phase separation dynamics of diblock copolymers.…
We prove strong crystallization results in two dimensions for an energy that arises in the theory of block copolymers. The energy is defined on sets of points and their weights, or equivalently on the set of atomic measures. It consists of…
A cascade of phase transitions from square to hexagonal lattice is studied in 2D system of particles interacting via core-softened potential. Due to the presence of two length-scales of repulsion, different local configurations with four,…
In this paper we review some recent results, obtained jointly with Stu Whittington, for a mathematical model describing a copolymer in an emulsion. The copolymer consists of hydrophobic and hydrophilic monomers, concatenated randomly with…
Classical atomistic simulations based on interatomic potentials resolve lattice instabilities, defect nucleation, and microstructure evolution with high fidelity, but their accessible system sizes remain far below those required for…
We consider a class of models motivated by previous numerical studies of wrinkling in highly stretched, thin rectangular elastomer sheets. The model used is characterized by a finite-strain hyperelastic membrane energy perturbed by small…
We study the ternary Ohta-Kawasaki free energy that has been used to model triblock copolymer systems. Its one-dimensional global minimizers are conjectured to have cyclic patterns. However, some physical experiments and computer…
We study a two-dimensional fluid of particles interacting through a spherically-symmetric and marginally soft two-body repulsion. This model can exist in three different crystal phases, one of them with square symmetry and the other two…