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This work presents a systematic review of the feature-rich essential properties in graphene-related systems using the first-principles method. The geometric and electronic properties are greatly diversified by the number of layers, the…

Chemical Physics · Physics 2017-02-14 Ngoc Thanh Thuy Tran , Shih-Yang Lin , Chiun-Yan Lin , Ming-Fa Lin

Chemical adsorption of atomic hydrogen on a negatively charged single layer graphene sheet has been analyzed with ab-initio Density Functional Theory calculations. We have simulated both finite clusters and infinite periodic systems to…

Materials Science · Physics 2015-05-18 J. A. Verges , P. L. de Andres

The present manuscript summarizes the modern view on the problem of the graphene-metal interaction. Presently, the close-packed surfaces of d metals are used as templates for the preparation of highly-ordered graphene layers. Different…

Materials Science · Physics 2017-08-23 E. N. Voloshina , Yu. S. Dedkov

Quantum confinement endows two-dimensional (2D) layered materials with exceptional physics and novel properties compared to their bulk counterparts. Although certain two- and few-layer configurations of graphene have been realized and…

A model is proposed to study the electronic structure of slightly curved graphene sheets with an arbitrary number of pentagon-heptagon pairs and Stone-Wales defects based on a cosmological analogy. The disorder induced by curvature produces…

Strongly Correlated Electrons · Physics 2008-11-26 Alberto Cortijo , Maria A. H. Vozmediano

Defects play a key role in the electronic structure of graphene layers flat or curved. Topological defects in which an hexagon is replaced by an n-sided polygon generate long range interactions that make them different from vacancies or…

Strongly Correlated Electrons · Physics 2008-11-26 Alberto Cortijo , María A. H. Vozmediano

Chemisorption of hydrogen on graphene is studied using atomistic simulations with the second generation of reactive empirical bond order Brenner inter-atomic potential. The lowest energy adsorption sites and the most important metastable…

Mesoscale and Nanoscale Physics · Physics 2011-03-15 Abdiravuf A. Dzhurakhalov , Francois M. Peeters

Straining graphene results in the appearance of a pseudo-magnetic field which alters its local electronic properties. Applying a pressure difference between the two sides of the membrane causes it to bend/bulge resulting in a resistance…

Mesoscale and Nanoscale Physics · Physics 2017-08-03 S. P. Milovanovic , M. Z. Tadic , F. M. Peeters

Graphane is a two-dimensional system consisting of a single layer of fully saturated (sp$^3$ hybridization) carbon atoms. In an ideal graphane structure C-H bonds exhibit an alternating pattern (up and down with relation to the plane…

Materials Science · Physics 2009-10-23 Marcelo Z. S. Flores , Pedro A. S. Autreto , Sergio B. Legoas , Douglas S. Galvao

The recent discovery of graphene has sparked significant interest, which has so far been focused on the peculiar electronic structure of this material, in which charge carriers mimic massless relativistic particle. However, the structure of…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Jannik C. Meyer , A. K. Geim , M. I. Katsnelson , K. S. Novoselov , T. J. Booth , S. Roth

The electronic structure, bonding and magnetism in graphene containing vacancies are studied using density-functional methods. The single-vacancy graphene ground state is spin polarized and structurally flat. The unpolarized state is non…

Mesoscale and Nanoscale Physics · Physics 2008-07-11 M. W. C. Dharma-wardana , Marek Z. Zgierski

All-carbon heterostructures have been produced recently via focused ion beam patterning of single layer graphene. Amorphized graphene is similar to a graphene sheet in which some hexagons are replaced by a combination of pentagonal,…

Materials Science · Physics 2017-04-07 B Mortazavi , Z Fan , LFC Pereira , A Harju , T Rabczuk

Graphene is a new material that exhibits remarkable properties from both fundamental and applied issues. This is a 2D matter system whose physical and mechanical features have been approached by using tight binding model, first principle…

Strongly Correlated Electrons · Physics 2011-08-10 Lalla Btissam Drissi , El Hassan Saidi , Mosto Bousmina

Based on density functional calculations, optimized structures of graphite oxide are found for various coverage by oxygen and hydroxyl groups, as well as their ratio corresponding to the minimum of total energy. The model proposed describes…

Materials Science · Physics 2008-09-05 Danil W. Boukhvalov , Mikhail I. Katsnelson

Graphene research is currently one of the largest fields in condensed matter. Due to its unusual electronic spectrum with Dirac-like quasiparticles, and the fact that it is a unique example of a metallic membrane, graphene has properties…

Materials Science · Physics 2010-04-22 Antonio H. Castro Neto

Proximity effects resulting from depositing a graphene layer on a TMD substrate layer change the dynamics of the electronic states in graphene, inducing spin orbit coupling (SOC) and staggered potential effects. An effective Hamiltonian…

Mesoscale and Nanoscale Physics · Physics 2016-12-21 Abdulrhman M. Alsharari , Mahmoud M. Asmar , Sergio E. Ulloa

A great efficacy of molecular quantum chemistry applied to basic graphene problems has been recently demonstrated by the authors when studying the formation of peculiar composites between carbon nanotubes and graphene as well as considering…

Mesoscale and Nanoscale Physics · Physics 2011-02-07 Elena F Sheka , Nadezhda A Popova

Graphene is a sturdy and chemically inert material exhibiting an exposed two-dimensional electron gas of high mobility. These combined properties enable the design of graphene composites either based on covalent or non- covalent coupling of…

Mesoscale and Nanoscale Physics · Physics 2015-03-19 Adrien Allain , Zheng Han , Vincent Bouchiat

The understanding of the structural and thermal properties of membranes, low-dimensional flexible systems in a space of higher dimension, is pursued in many fields from string theory to chemistry and biology. The case of a two-dimensional…

Mesoscale and Nanoscale Physics · Physics 2013-02-08 Mikhail I. Katsnelson , Annalisa Fasolino

Graphene and its multilayers have attracted considerable interest owing to the fourfold spin and valley degeneracy of their charge carriers, which enables the formation of a rich variety of broken-symmetry states and raises the prospect of…

Mesoscale and Nanoscale Physics · Physics 2013-09-10 Benjamin E. Feldman , Andrei J. Levin , Benjamin Krauss , Dmitry Abanin , Bertrand. I. Halperin , Jurgen H. Smet , Amir Yacoby