Related papers: The Possible Interstellar Anion CH2CN-: Spectrosco…
The dipole-bound excited state of the methylene nitrile anion (CH2CN-) has been suggested as a candidate carrier for a diffuse interstellar band (DIB) at 803.8 nm. Its corresponding radical has been detected in the interstellar medium…
The hypothesis that the cyanomethyl anion CH2CN- is responsible for the relatively narrow diffuse interstellar band (DIB) at 8037.8 +- 0.15 Angstroms is examined with reference to new observational data. The 0_0^0 absorption band arising…
It has long been suggested that CH2CN- might be a carrier of one of the many poorly characterized diffuse interstellar bands. In this paper, our aim is to study various forms of CH2CN in the interstellar medium. Aim of this paper is to…
Detecting anions in space has relied on a strong collaboration between theoretical and laboratory analyses to measure rotational spectra and spectroscopic constants to high accuracy. The advent of improved quantum chemical tools operating…
Cyanides, ranging from three carbon atoms to PAHs, and alkenyl compounds are abundant in the interstellar medium (ISM). Aminoacrylonitrile (3-Amino-2-propenenitrile, H$_{2}$N-CH=CH-CN), an alkenyl cyanide, thus represents a promising…
In the interstellar medium, the amide-type molecules play an important role in the formation of the prebiotic molecules in the hot molecular cores or high-mass star formation regions. The complex amide-related molecule cyanamide…
$C_2$ molecule is sometimes considered as a crucial component of carriers of some diffuse interstellar bands. Using UV data achieved by spectrometer STIS fed with HST we detected interstellar $C_2$ lines for few reddened target stars. We…
We report on the detection with the Infrared Space Observatory (ISO) of a molecular band at 57.5 microns (174 cm^{-1}) in carbon-rich evolved stars and in Sgr B2. Taking into account the chemistry of these objects the most likelihood…
To clarify the authenticity of a recently proposed identification of H2CCC (linear-C3H2) as a diffuse interstellar band carrier, we searched for the rotational transition of H2CCC at a frequency of 103 GHz toward HD 183143 using a 45-m…
The cyano radical (CN), one of the first detected interstellar molecular species, is a key molecule in many astrochemical chains. Particularly, it is detected towards molecular cores, the birth places of the stars, and it is known that it…
C-cyanomethanimine (HNCHCN), existing in the two $Z$ and $E$ isomeric forms, is a key prebiotic molecule, but, so far, only the $E$ isomer has been detected toward the massive star-forming region. Sagittarius B2(N) using transitions in the…
We report the first detection in the interstellar medium of $N$-cyanomethanimine (H$_2$CNCN), the stable dimer of HCN of highest energy, and the most complex organic molecule identified in space containing the prebiotically relevant NCN…
C$_3$P$^-$ is analogous to the known interstellar anion C$_3$N$^-$ with phosphorus replacing the nitrogen in a simple step down the periodic table. In this work, it is shown that C$_3$P$^-$ is likely to possess a dipole-bound excited state.…
We report the first detection of the molecule cyanomethyl, CH$_2$CN, in a protoplanetary disk. Until now, CH$_2$CN had only been observed at earlier evolutionary stages, in the giant molecular clouds TMC-1 and Sgr 2, and the prestellar core…
This work aims to spectroscopically characterize and provide for the first time direct experimental frequencies of the ground vibrational state and two excited states of the simplest alkynyl thiocyanate (HCCSCN) for astrophysical use. Both…
While it is now well established that large carbon chain species and radiative electron attachment (REA) are key ingredients triggering interstellar anion chemistry, the role played by smaller molecular anions, for which REA appears to be…
We report the first laboratory and interstellar detection of the alpha-cyano vinyl radical (H2CCCN). This species was produced in the laboratory by an electric discharge of a gas mixture of vinyl cyanide, CH2CHCN, and Ne, and its rotational…
It is thought that dicyanopolyynes could be potentially abundant interstellar molecules, although their lack of dipole moment makes it impossible to detect them through radioastronomical techniques. Recently, the simplest member of this…
Potential vibrational modes associated with diffuse interstellar bands (DIBs) could be discerned by examining energy differences between correlated DIBs. Consequently, $\approx 10^3$ higher correlated DIB pairs ($r-\sigma_r \ge 0.8$, $\ge…
It has been shown that rotational lines observed in the Horsehead nebula PDR are probably not caused by l-C3H+, as was originally suggested. In the search for viable alternative candidate carriers, quartic force fields are employed here to…