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We predict the existence of a class of ultracold giant molecules formed from trapped ultracold Rydberg atoms and polar molecules. The interaction which leads to the formation of such molecules is the anisotropic charge-dipole interaction…

Atomic Physics · Physics 2015-05-18 Seth T. Rittenhouse , H. R. Sadeghpour

We examine the potential-energy curves and polarization of the dipole moments of two static polar molecules under the influence of an external dc electric field and their anisotropic dipole-dipole interaction. We model the molecules as…

Quantum Physics · Physics 2024-09-24 Felipe Isaule , Robert Bennett , Jörg B. Götte

Resonant energy transfer (RET), between equal parity 1s65s$^3\mathrm{S}_1$ and 1s66s$^3\mathrm{S}_1$ Rydberg levels in helium has been observed in low-temperature ($\sim80$ mK) collisions with ammonia molecules which undergo inversion…

Atomic Physics · Physics 2026-05-21 J. Zou , R. R. W. Wang , R. González-Férez , H. R. Sadeghpour , S. D. Hogan

We discuss laser dressed dipolar and Van der Waals interactions between atoms and polar molecules, so that a cold atomic gas with laser admixed Rydberg levels acts as a designed reservoir for both elastic and inelastic collisional…

Atomic Physics · Physics 2012-05-15 Bo Zhao , Alexander Glätzle , Guido Pupillo , Peter Zoller

We calculate pair potential curves for interacting Rydberg atoms in a constant electric field and use them to determine the effective $C_3$ dipole-dipole and $C_6$ van der Waals coefficients. We compare the $C_3$ and $C_6$ with experiments…

We investigate the non-adiabatic quantum dynamics of ultralong-range Rydberg molecules using a vibronically coupled two-channel treatment. The two channels are composed of coupled trilobite and butterfly electronic states, formed as a…

Atomic Physics · Physics 2026-03-17 Felix Giering , Rohan Srikumar , Peter Schmelcher

We propose a novel type of Rydberg dimer, consisting of a Rydberg-state atom bound to a distant positive ion. The molecule is formed through long-range electric-multipole interaction between the Rydberg atom and the point-like ion. We…

Atomic Physics · Physics 2021-05-14 A. Duspayev , X. Han , M. A. Viray , L. Ma , J. Zhao , G. Raithel

We report on the observation of interactions between ultracold Rydberg atoms and ions in a Paul trap. The rate of observed inelastic collisions, which manifest themselves as charge transfer between the Rydberg atoms and ions, exceeds that…

Atomic Physics · Physics 2019-07-03 N. V. Ewald , T. Feldker , H. Hirzler , H. Fürst , R. Gerritsma

Ultracold molecules provide opportunities for exploring quantum matter, chemical dynamics and information processing thanks to their rich interactions, which can be controlled by external fields. Magnetic fields tune interactions through…

A three-level atomic medium can be made transparent to a resonant probe field in the presence of a strong control field acting on an adjacent atomic transition to a long-lived state, which can be represented by a highly excited Rydberg…

Quantum Physics · Physics 2017-03-16 David Petrosyan

Oriented external electric fields are ubiquitous in chemistry; however, the effects of fields applied in different directions on molecular systems remain underexplored. A major challenge is that an applied field exerts a torque on a…

Chemical Physics · Physics 2026-05-12 Duc Anh Lai , Devin A. Matthews

The electric dipole moment of an electron (eEDM) is one of the sensitive probes of physics beyond the standard model. The possible existence of the eEDM gives rise to an experimentally observed energy shift, which is proportional to the…

Computational Physics · Physics 2017-01-18 A. Sunaga , M. Abe , M. Hada , B. P. Das

We present first steps toward understanding the ultracold scattering properties of polar molecules in strong electric field-seeking states. We have found that the elastic cross section displays a quasi-regular set of potential resonances as…

Atomic Physics · Physics 2009-11-11 Christopher Ticknor , John L. Bohn

Rydberg atoms and beams of ultracold polar molecules have become highly useful experimental tools in recent years. There is therefore a need for accessible calculations of interaction potentials between such particles and nearby surfaces…

Quantum Physics · Physics 2012-03-05 Simen Å. Ellingsen , Stefan Yoshi Buhmann , Stefan Scheel

We investigate properties of ultralong-range polyatomic molecules formed with a Rb Rydberg atom and several ground-state atoms whose distance from the Rydberg atom is of the order of n^2a_0, where n is the principle quantum number of the…

Atomic Physics · Physics 2007-05-23 Ivan C. H. Liu , Jan M. Rost

Molecular rotation spectra, generated by the coupling of the molecular electric-dipole moments to an external time-dependent electric field, are discussed in a few particular conditions which can be of some experimental interest. First, the…

Other Condensed Matter · Physics 2015-12-15 M. Apostol , L. C. Cune

In heavy atoms and ions, nuclear structure effects are significantly enhanced due to the overlap of the electron wave functions with the nucleus. This overlap rapidly increases with the nuclear charge $Z$. We study the energy level shifts…

Atomic Physics · Physics 2021-03-17 V. V. Flambaum , I. B. Samsonov , H. B. Tran Tan , A. V. Viatkina

Microscopic control over polar molecules with tunable interactions would enable realization of novel quantum phenomena. Using an applied electric field gradient, we demonstrate layer-resolved state preparation and imaging of ultracold…

We show that nuclear motion of Rydberg atoms can be induced by resonant dipole-dipole interactions that trigger the energy transfer between two energetically close Rydberg states. How and if the atoms move depends on their initial…

Atomic Physics · Physics 2009-11-13 C. Ates , A. Eisfeld , J. M. Rost

We demonstrate a multiphoton Rydberg dark resonance where a Lambda-system is coupled to a Rydberg state. This N-type level scheme combines the ability to slow and store light pulses associated with long lived ground state superpositions,…

Quantum Physics · Physics 2009-11-13 M. G. Bason , A. K. Mohapatra , K. J. Weatherill , C. S. Adams