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We analyze the density functional theory (DFT) description of weak interactions by employing diffusion and reptation quantum Monte Carlo (QMC) calculations, for a set of benzene-molecule complexes. While the binding energies depend…

Materials Science · Physics 2015-05-14 Yosuke Kanai , Jeffrey C. Grossman

We briefly review a theory for the cuprates that has been recently proposed based on the movement and interaction of holes in antiferromagnetic (AF) backgrounds. A robust peak in the hole density of states (DOS) is crucial to produce a…

Condensed Matter · Physics 2009-10-28 E. Dagotto , A. Nazarenko , A. Moreo , S. Haas

We study the accuracy of Kohn-Sham density functional theory (DFT) for warm- and hot-dense matter (WDM and HDM). Specifically, considering a wide range of systems, we perform accurate ab initio molecular dynamics simulations with…

Computational Physics · Physics 2024-11-21 Phanish Suryanarayana , Arpit Bhardwaj , Xin Jing , Shashikant Kumar , John E. Pask

An analysis of the different approaches used within the van Hove BCS model for the high temperature superconductors has been done. How far the employment of an asymptotic expression for the density of states underestimates the thermodynamic…

Condensed Matter · Physics 2007-05-23 D. Quesada , A. Rubio-Ponce , R. Pena , R. Baquero , C. Trallero-Giner

Self-consistent theory of electron localization in disordered systems is generalized for the case of interacting electrons. We propose and critically compare a number of possible self-consistency schemes which take into account the lowest…

Condensed Matter · Physics 2008-02-03 E. Z. Kuchinskii , M. V. Sadovskii , V. G. Suvorov

The thermodynamic approach to density functional theory (DFT) is used to derive a versatile theoretical framework for the treatment of finite-temperature (and in the limit, zero temperature) Bose-Einstein condensates (BECs). The simplest…

Quantum Gases · Physics 2015-05-20 Nathan Argaman , Y. B. Band

We investigate the condensate density and the condensate fraction of conduction electrons in weak-coupling superconductors by using the BCS theory and the concept of off-diagonal-long-range-order. We discuss the analytical formula of the…

Quantum Gases · Physics 2010-03-22 Luca Salasnich

Long-range charge transfer excited states are notoriously badly underestimated in time-dependent density functional theory (TDDFT). We resolve how {\it exact} TDDFT captures charge transfer between open-shell species: in particular the role…

Chemical Physics · Physics 2009-11-11 Neepa T. Maitra

Neither BCS theory nor London theory contain any charge asymmetry. However it is an experimental fact that a rotating superconductor always exhibits a magnetic field parallel, never antiparallel, to its angular velocity. This and several…

Superconductivity · Physics 2009-11-10 J. E. Hirsch

We report measurements of the resistance of silicon MOSFETs as a function of temperature in high parallel magnetic fields where the 2D system of electrons has been shown to be fully spin-polarized. A magnetic field suppresses the metallic…

Strongly Correlated Electrons · Physics 2009-10-31 K. M. Mertes , Hairong Zheng , S. A. Vitkalov , M. P. Sarachik , T. M. Klapwijk

Quantum--Mechanical methods that are both computationally fast and accurate are not yet available for electronic excitations having charge transfer character. In this work, we present a significant step forward towards this goal for those…

Chemical Physics · Physics 2015-06-12 Michele Pavanello , Troy Van Voorhis , Lucas Visscher , Johannes Neugebauer

Static correlation error(SCE) inevitably emerges when a dissociation of a covalent bond is described with a conventional denstiy-functional theory (DFT) for electrons. SCE gives rise to a serious overshoot in the potential energy at the…

Computational Physics · Physics 2020-08-10 Hideaki Takahashi

A hybrid Kohn-Sham Density Functional Theory (KS-DFT) and 1-electron Reduced Density Matrix Functional Theory (1-RDMFT) has recently been developed to describe strongly correlated systems at mean-field computational cost. This approach…

Computational Physics · Physics 2025-04-14 Daniel Gibney , Jan-Niklas Boyn

In traditional finite-temperature Kohn-Sham density functional theory (KSDFT), the well-known orbitals wall restricts the use of first-principles molecular dynamics methods at extremely high temperatures. However, stochastic density…

Plasma Physics · Physics 2024-01-30 Tao Chen , Qianrui Liu , Yu Liu , Liang Sun , Mohan Chen

One of the most promising techniques used for studying the electronic properties of materials is based on Density Functional Theory (DFT) approach and its extensions. DFT has been widely applied in traditional solid state physics problems…

Materials Science · Physics 2013-06-03 Nicola Varini , Davide Ceresoli , Layla Martin-Samos , Ivan Girotto , Carlo Cavazzoni

We study interaction corrections to the thermoelectric transport coefficient $\alpha$ and the thermopower $S$ in the two-dimensional disordered electron gas with long-range Coulomb interactions. To this end, we analyze the heat…

Mesoscale and Nanoscale Physics · Physics 2024-11-05 Zahidul Islam Jitu , Georg Schwiete

The exact universal functional of integer charge leads to an extension to fractional charge asymptotically when it is applied to a system made of asymptotically separated densities. The extended functional is asymptotically local and is…

Chemical Physics · Physics 2024-12-17 Jing Kong

Heterogeneous interfaces are central to many energy-related applications in the nanoscale. From the first-principles electronic structure perspective, one of the outstanding problems is accurately and efficiently calculating how the…

Materials Science · Physics 2023-08-29 Zhen-Fei Liu

A new reference state for density functional theory, termed the independent atom ansatz, is introduced in this work. This ansatz allows for the exact representation of electron density in terms of non-interacting, atom-localized orbitals.…

Chemical Physics · Physics 2024-05-03 Alexander V. Mironenko

We present a finite-temperature density functional theory investigation of the nonequilibrium transient electronic structure of warm dense Li, Al, Cu, and Au created by laser excitation. Photons excite electrons either from the inner shell…

Atomic Physics · Physics 2021-02-26 Hengyu Zhang , Shen Zhang , Dongdong Kang , Jiayu Dai , M. Bonitz