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The band structures and optical properties of monoclinic HfO2 are investigated by the local density approximation (LDA)+U approach. With the on-site Coulomb interaction being introduced to 5d orbitals of Hf atom and 2p orbitals of O atom,…

Materials Science · Physics 2013-11-26 Jinping Li , Jiecai Han , Songhe Meng , Hantao Lu , Takami Tohyama

We studied the band gap of {\beta}-PtO2 using first-principles calculations based on density functional theory (DFT). The results are obtained within the framework of generalized gradient approximation (GGA), GGA+U, GW and the hybrid…

Strongly Correlated Electrons · Physics 2012-03-08 Yong Yang , Osamu Sugino , Takahisa Ohno

We perform first-principles calculations of electronic structure and optical properties for UO2 and PuO2 based on the density functional theory using the generalized gradient approximation (GGA)+\emph{U} scheme. The main features in…

Strongly Correlated Electrons · Physics 2010-05-07 Hongliang Shi , Mingfu Chu , Ping Zhang

We report density functional theory (DFT) band structure calculations on the transparent conducting oxides CuAlO2, CuGaO2, CuInO2 and CuCrO2. The use of the hybrid functional sX-LDA leads to considerably improved electronic properties…

Strongly Correlated Electrons · Physics 2013-04-10 Roland Gillen , John Robertson

The electronic band structures and optical properties of cubic, tetragonal, and monoclinic phases of HfO2 are calculated using the first-principles linear augmented plane-wave method, within the density functional theory and generalized…

The electronic band structure of cubic HfO2 is calculated using an it ab initio all-electron self--consistent linear augmented plane-wave method, within the framework of the local-density approximation and taking into account…

Hubbard-corrected density functional theory, denoted by DFT+U method, was developed to enable correct prediction of insulating properties for strongly-correlated electron systems. UO$_2$ is an example having O-$2p$, U-$6d$, and U-$5f$…

Strongly Correlated Electrons · Physics 2023-02-28 Mahmoud Payami

The so-called local density approximation plus the multi-orbital mean-field Hubbard model (LDA+U) has been implemented within the all-electron projector augmented-wave method (PAW), and then used to compute the insulating antiferromagnetic…

Strongly Correlated Electrons · Physics 2009-10-31 O. Bengone , M. Alouani , P. Bloechl , J. Hugel

The optical response functions and band structures of LiCoO$_2$ are studied at different levels of approximation, from density functional theory (DFT) in the generalized gradient approximation (GGA) to quasiparticle self-consistent QS$GW$…

The wurtzite (wz) structure of CdS is analyzed using density functional theory within the generalized gradient approximation (GGA) and Hubbard correction (GGA+U). The total energy convergence evaluation is carried out concerning energy…

Materials Science · Physics 2022-06-22 Ankan Biswas , S. R. Meher , Deepak K. Kaushik

We present first-principles many-body perturbation theory calculations of the quasiparticle electronic structure and of the optical response of HfO$_2$ polymorphs. We use the $GW$ approximation including core electrons by the projector…

Materials Science · Physics 2018-11-14 Benoît Sklénard , Alberto Dragoni , François Triozon , Valerio Olevano

We report on optical properties of various polymorphs of hafnia predicted within the framework of density functional theory. The full potential linearised augmented plane wave method was employed together with the Tran-Blaha modified…

Materials Science · Physics 2016-09-21 Pavel Ondračka , David Holec , David Nečas , Lenka Zajíčková

The electronic structure of the CuO monolayer is investigated taking into account the intra- and interatomic Coulomb interactions on copper and oxygen atoms. Local Coulomb interactions and covalence effects are treated exactly when…

Strongly Correlated Electrons · Physics 2025-03-28 I. A. Makarov , A. A. Slobodchikov , I. A. Nekrasov , Yu. S. Orlov , L. V. Begunovich , M. M. Korshunov , S. G. Ovchinnikov

Structural and optoelectronic properties of BaThO3 cubic perovskite are calculated using all electrons full potential linearized augmented plane wave (FP-LAPW) method. Wide and direct band gap, 5.7 eV, of the compound predicts that it can…

Materials Science · Physics 2015-03-17 G. Murtaza , Iftikhar Ahmad , B. Amin , J. Maqssod , A. Afaq , M. Maqbool , I. Khan , M. Zahid

The ground-state 4f fine-structure levels in the intrinsic optical transition gaps between the 2p and 5d orbitals of lanthanide sesquioxides (Ln2O3, Ln=La...Lu) were calculated by a two-way crossover search for the U parameters for DFT+U…

Strongly Correlated Electrons · Physics 2015-11-17 Bolong Huang

The dielectric function of the wide-gap optical material HfO2 is investigated by the local density approximation (LDA) +U approach. We focus on the origin of the shoulder-like structure near the edge of the band gap in the imaginary part of…

Materials Science · Physics 2016-01-06 Jinping Li , Songhe Meng , Liyuan Qin , Hantao Lu , Takami Tohyama

The role of electronic correlation effects for a realistic description of the electronic properties of LaAlO3/SrTiO3 heterostructures as covered by the on-site Coulomb repulsion within the GGA+U approach is investigated. Performing a…

Strongly Correlated Electrons · Physics 2017-01-30 I. I. Piyanzina , T. Kopp , Yu. V. Lysogorskiy , D. A. Tayurskii , V. Eyert

The ab initio computational method known as Hubbard-corrected density functional theory (DFT+$U$) captures well ground electronic structures of a set of solids that are poorly described by standard DFT alone. Since lattice dynamical…

Materials Science · Physics 2025-06-17 Wooil Yang , Sabyasachi Tiwari , Feliciano Giustino , Young-Woo Son

We propose a range-separated hybrid exchange-correlation functional to calculate solid-state material properties. The functional mixes Hartree-Fock exchange with the semilocal exchange of the meta-generalized gradient approximation…

Materials Science · Physics 2025-02-27 Subrata Jana , Abhishek Bhattacharjee , Suman Mahakal , Szymon Smiga , Prasanjit Samal

The electronic structure and properties of PuO$_{2}$ and Pu$_{2}$O$_{3}$ have been studied from first principles by the all-electron projector-augmented-wave (PAW) method. The local density approximation (LDA)+$U$ and the generalized…

Materials Science · Physics 2007-12-24 Bo Sun , Ping Zhang , Xian-Geng Zhao
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