Related papers: Is acetylene essential for carbon dust formation?
The formation of dust with temperature-dependent non-grey opacity is considered in a series of self-consistent model atmospheres at different phases of an O-rich Mira variable of mass 1.2 $M_\odot$. Photometric and interferometric…
The abundance of polycyclic aromatic hydrocarbons (PAHs) in low- and high-metallicity galaxies has been widely discussed since the time when detailed infrared data for extragalactic objects were first obtained. On the scales of entire…
To study the chemical evolution during the formation of molecular clouds, we model three types of clouds with different density structures: collapsing spherical, collapsing ellipsoidal, and static spherical profiles. The collapsing models…
Depending on whom you ask, PAHs are either the smallest dust particles or the largest gas-phase molecules in space. Whether referred to as gas or dust, these PAHs can contain up to 20% of the total cosmic carbon abundance and as such also…
[Abridged] Fullerenes have been recently detected in various circumstellar and interstellar environments, raising the question of their formation pathway. It has been proposed that they can form by the photo-chemical processing of large…
Carbon dioxide (CO$_2$) is one of the most important interstellar molecules. While it is considered that it forms on the surface of interstellar dust grains, the exact contribution of different chemical mechanisms is still poorly…
Substellar atmospheres are observed to be irregularly variable for which the formation of dust clouds is the most promising candidate explanation. The atmospheric gas is convectively unstable and, last but not least, colliding convective…
The nature and evolution of hydrocarbonaceous grains within interstellar and circumstellar media is still far from resolved, perhaps owing to the rather complex nature of their seemingly simple binary atomic compositions. This work explores…
The chemical pathways linking the small organic molecules commonly observed in molecular clouds to the large, complex, polycyclic species long-suspected to be carriers of the ubiquitous unidentified infrared emission bands remain unclear.…
While dust is a major player in galaxy evolution, its relationship with gas and stellar radiation in the early universe is still not well understood. We combine 3D-HST emission line fluxes with far-UV through far-IR photometry in a sample…
[Abridged] Ethylene oxide and its isomer acetaldehyde are important complex organic molecules because of their potential role in the formation of amino acids. Despite the fact that acetaldehyde is ubiquitous in the interstellar medium,…
In this work the optical properties of amorphous carbon (amC) dust condensed around carbon(C)-stars are constrained by comparing the observations for the Large Magellanic Cloud C-stars from the Two Micron All Sky Survey (2MASS) and from the…
The most usual tracer of molecular gas is line emission from CO. However, the reliability of that tracer has long been questioned in environments different from the Milky Way. We study the relationship between H2 and CO abundances using a…
Brown dwarfs and giant gas planets are substellar objects whose spectral appearance is determined by the chemical composition of the gas and the solids/liquids in the atmosphere. Atmospheres of substellar objects possess two major scale…
Emission from polycyclic aromatic hydrocarbons (PAHs), a commonly used indicator of star formation activity in galaxies, also has the potential to serve as an effective empirical tracer of molecular gas. We use a sample of 19 nearby…
Interstellar molecules are thought to build up in the shielded environment of molecular clouds or in the envelope of evolved stars. This follows many sequential reaction steps of atoms and simple molecules in the gas phase and/or on (icy)…
The formation of CO2 in quiescent regions of molecular clouds is not yet fully understood, despite CO2 having an abundance of around 10-34 % H2O. We present a study of the formation of CO2 via the non-energetic route CO + OH on non-porous…
Oxygen ($O_2$) is one of the most important elements required to sustain life. The concentration of $O_2$ on Earth has been accumulated over millions of years and has a direct connection with that of $CO_2$. Further, $CO_2$ plays an…
The presence of carbon-chain molecules in the interstellar medium (ISM) has been known since the early 1970s and $>130$ such species have been identified to date, making up $\sim 43$% of the total of detected ISM molecules. They are…
Carbon is one of the most abundant metals in the universe because of its synthesis in the fundamental triple alpha reaction. The knowledge of carbon abundances in different environments is one key ingredient to our understanding of stellar…