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We report a three-dimensional numerical implementation of multiconfiguration time-dependent Hartree-Fock (MCTDHF) based on a multi-resolution Cartesian grid, with no need to assume any symmetry of molecular structure. We successfully…

Computational Physics · Physics 2016-03-23 Ryohto Sawada , Takeshi Sato , Kenichi L. Ishikawa

Multielectron tunneling ionization creates ionic coherence crucial for lasing and driving electron motion in molecules. While tunneling is well understood as a single active electron process, less emphasis has been placed on theoretical…

Quantum Physics · Physics 2026-04-23 Chi-Hong Yuen

Systematic investigations of the electric dipole (E1) modes of excitation are performed using the canonical-basis time-dependent Hartree-Fock-Bogoliubov (Cb-TDHFB) theory. The Cb-TDHFB is able to describe dynamical pairing correlations in…

Nuclear Theory · Physics 2014-08-12 Shuichiro Ebata , Takashi Nakatsukasa , Tsunenori Inakura

Theoretical approaches to the photoionization of few-electron atoms are discussed. These include nonequilibrium Greens functions and wave function based approaches. In particular, the Multiconfiguration Time-Dependent Hartree-Fock method is…

Atomic Physics · Physics 2015-05-14 M. Bonitz , D. Hochstuhl , S. Bauch , K. Balzer

The evaluation of exact (Hartree--Fock, HF) exchange operator is a crucial ingredient for the accurate description of electronic structure in periodic systems through ab initio and hybrid density functional approaches. An efficient…

Chemical Physics · Physics 2020-10-28 Xiao Wang , Cannada A. Lewis , Edward F. Valeev

Silicon quantum computing has the potential to revolutionize technology with capabilities to solve real-life problems that are computationally complex or even intractable for modern computers [1] by offering sufficient high quality qubits…

Mesoscale and Nanoscale Physics · Physics 2024-09-24 Dylan H. Liang , MengKe Feng , Philip Y. Mai , Jesus D. Cifuentes , Andrew S. Dzurak , Andre Saraiva

Time-dependent Hartree--Fock (TDHF) method has been applied to various low-energy nuclear reactions, such as fusion, fission, and multinucleon transfer reactions. In this Mini Review, we summarize recent attempts to bridge a microscopic…

Nuclear Theory · Physics 2020-03-16 Kouhei Washiyama , Kazuyuki Sekizawa

We theoretically investigate an electric-field-driven system of charged spheres as a primitive model of concentrated electrolytes under an applied electric field. First, we provide a unified formulation for the stochastic charge and density…

Soft Condensed Matter · Physics 2025-01-15 Hiroshi Frusawa

We discuss two problems which are particularly challenging for approximations in time-dependent density functional theory (TDDFT) to capture: momentum-distributions in ionization processes, and memory-dependence in real-time dynamics. We…

Materials Science · Physics 2010-03-22 Arun K. Rajam , Paul Hessler , Christian Gaun , Neepa T. Maitra

The evolution of Bose-Einstein condensates is amply described by the time-dependent Gross-Pitaevskii mean-field theory which assumes all bosons to reside in a single time-dependent one-particle state throughout the propagation process. In…

Other Condensed Matter · Physics 2008-03-18 Ofir E. Alon , Alexej I. Streltsov , Lorenz S. Cederbaum

We develop a time-dependent variational Monte Carlo (t-VMC) method for quantum dynamics of strongly correlated electrons. The t-VMC method has been recently applied to bosonic systems and quantum spin systems. Here, we propose a…

Strongly Correlated Electrons · Physics 2015-12-22 Kota Ido , Takahiro Ohgoe , Masatoshi Imada

Ab initio modeling of dynamic structure factors (DSF) and related density response properties in the warm dense matter (WDM) regime is a challenging computational task. The DSF, convolved with a probing X-ray beam and instrument function,…

We present the theory, implementation, and benchmarking of a real-time time-dependent density functional theory (RT-TDDFT) module within the RMG code, designed to simulate the electronic response of molecular systems to external…

Simulating electron-ion dynamics using time-dependent density functional theory within an Ehrenfest dynamics scheme can be done in two ways that are in principle exact and identical: propagating time-dependent electronic Kohn-Sham equations…

Chemical Physics · Physics 2021-07-01 Lionel Lacombe , Neepa T. Maitra

We introduce a microscopic approach for calculating the excitation energies of systems formed during heavy-ion collisions. The method is based on time-dependent Hartree-Fock (TDHF) theory and allows the study of the excitation energy as a…

Nuclear Theory · Physics 2009-10-29 A. S. Umar , V. E. Oberacker , J. A. Maruhn , P. -G. Reinhard

The time-dependent Schrodinger equation (TDSE) is usually treated in real space in the textbook. However, it makes the numerical simulations of strong-field processes difficult due to the wide dispersion and fast oscillation of the electron…

Atomic Physics · Physics 2020-01-20 Yan Xu , Xue-Bin Bian

We investigate the accuracy and efficiency of the semiclassical Frozen Gaussian method in describing electron dynamics in real time. Model systems of two soft-Coulomb-interacting electrons are used to study correlated dynamics under…

Chemical Physics · Physics 2015-05-30 Peter Elliott , Neepa T. Maitra

The development of a novel exact two-component (X2C) scheme with the inclusion of the picture-change correction for the fluctuation potential, the X2Ccorr scheme, is reported, hereby establishing a hierarchy of X2C schemes with systematic…

Chemical Physics · Physics 2026-03-02 Xubo Wang , Sen Wang , Yixuan Wu , Lan Cheng

We propose an efficient algorithm for the recently published electron/hole-transfer Dynamical-weighted State-averaged Constrained CASSCF (eDSC/hDSC) method studying charge transfer states and D$_1$-D$_0$ crossings for systems with odd…

Computational Physics · Physics 2024-09-24 Tian Qiu , Joseph E. Subotnik

Attosecond dynamics in strong-field tunnel ionization are encoded in intricate holographic patterns in the photoelectron momentum distributions (PMDs). These patterns show the interference between two or more superposed quantum electron…