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This article presents a new and efficient alternative to well established algorithms for molecular geometry optimization. The new approach exploits the approximate decoupling of molecular energetics in a curvilinear internal coordinate…

Materials Science · Physics 2007-05-23 Károly Németh , Matt Challacombe

We consider the optimal control of quantum systems interacting non-linearly with an electromagnetic field. We propose new monotonically convergent algorithms to solve the optimal equations. The monotonic behavior of the algorithm is ensured…

Quantum Physics · Physics 2015-05-13 M. Lapert , R. Tehini , G. Turinici , D. Sugny

Solving parabolic optimal control problems can be inherently challenging in the field of science and engineering, especially with constraints on the nonsmooth distributed control. Motivated by the extensive applicability of the alternating…

Optimization and Control · Mathematics 2026-03-03 Haiming Song , Jinda Yang , Yuran Yang , Jianhua Yuan

We propose a new design heuristic to tackle combinatorial optimisation problems, inspired by Hamiltonians for optimal state-transfer. The result is a rapid approximate optimisation algorithm. We provide numerical evidence of the success of…

Quantum Physics · Physics 2024-02-14 Robert J. Banks , Dan E. Browne , P. A. Warburton

We theoretically investigate the entangled states of an atomic ensemble that can be obtained via cavity-feedback, varying the atom-light coupling from weak to strong, and including a systematic treatment of decoherence. In the strong…

Quantum Physics · Physics 2015-07-28 Krzysztof Pawlowski , Jérôme Estève , Jakob Reichel , Alice Sinatra

This paper presents a particle-based optimization method designed for addressing minimization problems with equality constraints, particularly in cases where the loss function exhibits non-differentiability or non-convexity. The proposed…

Optimization and Control · Mathematics 2026-03-31 José A. Carrillo , Shi Jin , Haoyu Zhang , Yuhua Zhu

Alternating-Current Optimal Power Flow (AC-OPF) is an optimization problem critical for planning and operating the power grid. The problem is traditionally formulated using only continuous variables. Typically, control devices with…

Optimization and Control · Mathematics 2021-10-15 Timothy McNamara , Amritanshu Pandey , Aayushya Agarwal , Larry Pileggi

Methods for reconstructing the topology of complex networks from time-resolved observations of node dynamics are gaining relevance across scientific disciplines. Of biggest practical interest are methods that make no assumptions about…

This paper presents an algorithm to solve non-convex optimal control problems, where non-convexity can arise from nonlinear dynamics, and non-convex state and control constraints. This paper assumes that the state and control constraints…

Optimization and Control · Mathematics 2017-05-05 Yuanqi Mao , Michael Szmuk , Behcet Acikmese

To achieve accurate contour tracking of robotic manipulators with dynamic uncertainties, coupling and actuator faults, an adaptive non-singular terminal sliding mode control (ANTSMC) based on cross-coupling is proposed. Firstly, the…

Dynamical Systems · Mathematics 2021-10-19 Zhu Dachang , Du Baolin , Cui Aodong , Zhu Puchen

Optimal control theory is usually formulated as an indirect method requiring the solution of a two-point boundary value problem. Practically, the solution is obtained by iterative forward and backward propagation of quantum wavepackets.…

Quantum Physics · Physics 2020-10-09 Alejandro R. Ramos Ramos , Oliver Kühn

Finding the ground state of Ising spin glasses is notoriously difficult due to disorder and frustration. Often, this challenge is framed as a combinatorial optimization problem, for which a common strategy employs simulated annealing, a…

The system of an atom couples to two distinct optical cavities with phase decoherence is studied by making use of a dynamical algebraic method. We adopt the concurrence to characterize the entanglement between atom and cavities or between…

Quantum Physics · Physics 2015-06-26 Jing-Bo Xu , Shang-Bin Li

This paper proposes a provably convergent multiblock ADMM for nonconvex optimization with nonlinear dynamics constraints, overcoming the divergence issue in classical extensions. We consider a class of optimization problems that arise from…

Optimization and Control · Mathematics 2025-06-24 Bowen Li , Ya-xiang Yuan

The Alternating Direction Method of Multipliers (ADMM) has gained a lot of attention for solving large-scale and objective-separable constrained optimization. However, the two-block variable structure of the ADMM still limits the practical…

Optimization and Control · Mathematics 2020-03-24 Kresimir Mihic , Mingxi Zhu , Yinyu Ye

The Alternating Current Optimal Transmission Switching (ACOTS) problem incorporates line switching decisions into the AC Optimal Power Flow (ACOPF) framework, offering well-known benefits in reducing operational costs and enhancing system…

Optimization and Control · Mathematics 2025-06-09 Cheng Guo , Harsha Nagarajan , Merve Bodur

Selecting the best hyperparameters for a particular optimization instance, such as the learning rate and momentum, is an important but nonconvex problem. As a result, iterative optimization methods such as hypergradient descent lack global…

Machine Learning · Computer Science 2023-12-05 Xinyi Chen , Elad Hazan

The quasicontinuum method was originally introduced to bridge across length scales -- from atomistics to significantly larger continuum scales -- thus overcoming a key limitation of classical atomic-scale simulation techniques while solely…

Mesoscale and Nanoscale Physics · Physics 2021-06-30 Prateek Gupta , Michael Ortiz , Dennis M. Kochmann

Mathematical optimization is one of the cornerstones of modern engineering research and practice. Yet, throughout all application domains, mathematical optimization is, for the most part, considered to be a numerical discipline.…

Optimization and Control · Mathematics 2024-01-09 Adrian Hauswirth , Zhiyu He , Saverio Bolognani , Gabriela Hug , Florian Dörfler

An accurate description of strong correlation is quintessential for the exploration of emerging chemical phenomena. While near-term variational quantum algorithms provide a theoretically scalable framework for quantum chemical problems, the…

Quantum Physics · Physics 2025-10-20 Arpan Choudhury , Sonaldeep Halder , Rahul Maitra , Debashree Ghosh
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